Predicting sodification of calcium-saturated soil columns on leaching with sodic waters

SummaryDepth accumulation of exchangeable Na+ was measured in Ca-saturated sandy loam soil columns (length 50 cm; diameter 5 cm) after percolating 500, 1000, 1500 and 2000 ml of 013 M Na+, as NaCl, NaHCO3, Na2SO4 and Na2CO3 solutions. The values of exchangeable sodium percentage (ESP) increased gradually with the increase in the volumes of the solution percolated. Two conceptual layer models, based on whether solutions were added to the topmost soil layer in one lot (M-I) or in splits equal to the saturation deficit (M-II), were used to predict the depth distribution of ESP of soil. The chemical processes considered in the models were the formation of ion pairs and the exchange equilibria of Na+ and Ca2+. The predicted values of ESP were considerably higher for model M-II than model M-I. The consideration of ion-pair formation and the accompanying anion had only negligible effect on the predicted ESP. The model M-II over-predicted the experimental ESP throughout the soil columns, whereas the model M-I under-predicted it for the upper layer(s) and over-predicted for the lower layers. On the basis of average ESP of the whole columns, the less realistic model M-I predicted experimental results better than model M-II. This was attributed to the presence of mobile and immobile zones for the flowing solutions.