The Microstructure of Shock-Synthesized Diamond

Author(s):  
Lucien F. Trueb

A new type of synthetic industrial diamond formed by an explosive shock process has been recently developed by the Du Pont Company. This material consists of a mixture of two basically different forms, as shown in Figure 1: relatively flat and compact aggregates of acicular crystallites, and single crystals in the form of irregular polyhedra with straight edges.Figure 2 is a high magnification micrograph typical for the fibrous aggregates; it shows that they are composed of bundles of crystallites 0.05-0.3 μ long and 0.02 μ. wide. The selected area diffraction diagram (insert in Figure 2) consists of a weak polycrystalline ring pattern and a strong texture pattern with arc reflections. The latter results from crystals having preferred orientation, which shows that in a given particle most fibrils have a similar orientation.

1989 ◽  
Vol 54 (11) ◽  
pp. 2951-2961 ◽  
Author(s):  
Miloslav Karel ◽  
Jaroslav Nývlt

Measured growth and dissolution rates of single crystals and tablets were used to calculate the overall linear rates of growth and dissolution of CuSO4.5 H2O crystals. The growth rate for the tablet is by 20% higher than that calculated for the single crystal. It has been concluded that this difference is due to a preferred orientation of crystal faces on the tablet surface. Calculated diffusion coefficients and thicknesses of the diffusion and hydrodynamic layers in the vicinity of the growing or dissolving crystal are in good agreement with published values.


In the ordinary type of Wöhler machine used for testing materials in fatigue under reversed bending stresses, the load system is stationary in space, and variation of the stress system with respect to the test piece is obtained by rotating the test piece. It is, of course, essential to the success of the test that the system of displacements caused by the application of the load system to the test piece should remain stationary in space; but, since the test piece rotates, this requirement can only be fulfilled if the material of the test piece is isotropic. Thus, if an attempt were made to test a single crystal in a Wöhler machine it might be anticipated that either actual elastic antisotropy or the virtual anisotropy due to restricted slip movement would cause the deformation to vary with the orientation of the stress system relative to the axes of the crystal and that "whipping" of the specimen would occur. Three such attempts have indeed been made: but in spite of great care exercised in setting up the specimens and in applying the loads, only in one case, in which the orientation of the crystal was such as to provide effective symmetry about the axis of the specimen, was the test successful. A new type of testing machine recently developed at the N. P. L. for testing specimens in fatigue under systems of combined bending and torsional stresses, differs in principle from the Wöhler machine in that the variation of stress is produced by actual variation of load. In this machine both me test piece and the orientation of the stress system remain stationary, only the magnitude of the stresses being varied. The deformation of the test piece is therefore only that due to one type of stress system fixed in relation to the orientation of the test piece and varying only in magnitude. Moreover, the construction of the machine is such that the strain of the test piece is not required to be of the same type as the stress system applied, e. g ., the application of pure bending moment does not restrict the test piece to pure bending strain and the test piece remains free to twist also if necessary. These conditions render this type of machine perfectly suitable for test on single crystals. Accordingly, tests have been carried out in this machine on three single crystals of aluminium; the first was tested under reversed flexural stresses, the second under reversed torsional stresses and the third under a combination of reversed flexural and reversed torsional stresses.


1987 ◽  
Vol 99 ◽  
Author(s):  
Hoydoo You ◽  
J. D. Axe ◽  
X. B. Kan ◽  
S. C. Moss ◽  
J. Z. Liu ◽  
...  

ABSTRACTSingle crystals of YBa2Cu3O7-y were studied by transmission Laue photography and monochromatic diffraction techniques, using the Cornell High Energy Synchrotron Source and a rotating anode x-ray source. A new type of twinning, with two orthorhombic domains rotated exactly 90 degree about the c axis, was observed in one sample and the conventional (110) type twinning in another sample with nominally identical growth conditions. A high resolution diffraction study of the sample with the conventional (110) twinning shows that measured orthorhombicity (proportional to oxygen ordering parameter) varies from one domain to another.


2005 ◽  
Vol 60 (4) ◽  
pp. 431-436 ◽  
Author(s):  
Stefan Jörgens ◽  
Albrecht Mewis

Colourless single crystals of KBaPS4 (a = 11.587(2), b = 6.700(1), c = 10.118(2) Å ), and pale orange ones of KBaPSe4 (a = 11.972(2), b = 6.973(1), c = 10.388(2) Å ) were obtained by reactions of Ba3(PS4)2 and Ba3(PSe4)2, respectively, with KCl (790 °C; 30 h). The isotypic compounds crystallize with a slightly modified TlEuPS4 type structure (Pnma, Z = 4); that is, the characteristic units are distorted discrete PX4 tetrahedra (X: S, Se) interconnected by K+ and Ba2+. However, due to the strong distortion of the trigonal X6 prisms along [001] the coordination numbers increase from 8 to 9 for the barium atoms and from 8 to 11 for the potassium atoms. Orange crystals of Ba3PO4PSe4 (a= 6.779(1), b =7.108(1), c =12.727(3)Å ; α = 82.45(3)°, β =78.88(3)°, γ =81.34(3)°) resulted as a by-product of the synthesis of Ba3(PSe4)2. The compound crystallizes in a new type of structure (P1̅; Z = 2) and is the first chalcogenophosphate with discrete PO4 and PSe4 tetrahedra. The coordination polyhedra of the barium atoms are formed by both chalcogen atoms


2006 ◽  
Vol 980 ◽  
Author(s):  
Yukichi Umakoshi ◽  
Takashi Nakajima ◽  
Hiroyuki Y. Yasuda

AbstractNew type pseudoelasticity in Fe3Al with the D03 structure was examined using the single crystals. The pseudoelasticity occurred due to a reversible motion of 1/4<111> superpartials dragging the nearest-neighbor anti-phase boundaries. The chemical composition and microstructure of Fe3Al alloys strongly influenced the shape recovery ratio and Fe-23.0at%Al alloy with fine domain structure was the most favorable for the appearance of the pseudoelasticity. The recovery ratio of Fe-23.0at%Al exceeded 80 % in the wide temperature range from -50 to 200 oC.


1989 ◽  
Vol 173 ◽  
Author(s):  
Z. Yoshida ◽  
T. Sugimoto ◽  
Y. Misaki

ABSTRACTThe electron-donating [n]radialenes (n=3,4,5) were prepared with the aim of developing both new type of organic (super)conductors and unprecedented organic/molecular ferromagnets. The charge-transfer (CT) complexes of 1,3-dithiole[4]radialene with TCNQ and of 1,3-benzodithiole-[4]radialene with TCNQF4 and DDQ showed comparatively high electrical conductivities in compressed pellets. The single crystals of PF6 and CIO4 salts of 1,3-benzodithiole[4]radialene radical cation revealed temperature change of electrical conductivity characteristic of a semiconductor. The magnetic properties of the bis(trifluoroacetate)salt of thioxanthene[3]-radialene dication and of the CT complexes of 1,3-benzodithiole[5]-radialene with DDQ, TCNQF4, and hexacyanohexamethylenecyclopropane, were also investigated from the ESR and/or magnetic susceptibility measurements.


1992 ◽  
Vol 47 (7) ◽  
pp. 937-941 ◽  
Author(s):  
Kurt O. Klepp

Transparent single crystals of Na4Ga2S5 were obtained from a melt of Na2S, Ga and S. Na4Ga2S5 is monoclinic, space group P21/c with a = 7.967(1), b = 6.133(2), c = 19.852(9) Å, β = 91.61(2)°, Ζ = 4. Its crystal structure was refined to a conventional R of 0.033 for 1150 observed reflections.The structure of Na4Ga2S5 is of a new type. It is characterized by infinite ribbon like thiogallate anions, -, which are built up by GaS4-tetrahedra (mean Ga-S bond length 2.28 A) sharing apices and edges. The four crystallographically independent alkali cations are coordinated to six sulphur atoms in distorted octahedral configurations.


Author(s):  
Lucien F. Trueb

The microstructure of early shock-synthesized diamond was discussed in a previous report; this paper is concerned with the characterization of improved material which is now available from E. I. du Pont de Nemours & Company in various size ranges suitable for lapping and polishing.This new type of synthetic industrial diamond is produced by shocking dense graphite-metal mixtures at high explosive pressures. It consists of two types of particles which are shown in Figure 1; polycrystalline aggregates which are rounded and have a mottled surface, and single crystals or fragments thereof which have straight edges and flat surfaces. Figure 2 shows the two types of particles in transmission; they both partly consist of the hexagonal modification of diamond. Single crystals have either a cubic or a hexagonal habit and they often contain large numbers of stacking faults. Polycrystalline particles consist of densely aggregated bundles of acicular crystallites having an average width of 150 A and a length varying between 0.05 and 0.3 p.; a strong preferred orientation is invariably present (Figure 3).


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