scholarly journals Characterization of Electrospray Drop Size Distributions by Mobility-Classified Mass Spectrometry: Implications for Ion Clustering in Solution and Ion Formation Pathways

Author(s):  
Christian Lübbert ◽  
Wolfgang Peukert
Fluids ◽  
2022 ◽  
Vol 7 (1) ◽  
pp. 29
Author(s):  
Miguel Panão

In particle engineering, spray drying is an essential technique that depends on producing sprays, ideally made of equal-sized droplets. Ultrasonic sprays appear to be the best option to achieve it, and Faraday waves are the background mechanism of ultrasonic atomization. The characterization of sprays in this atomization strategy is commonly related to the relation between characteristic drop sizes and the capillary length produced by the forcing frequency of wavy patterns on thin liquid films. However, although this atomization approach is practical when the intended outcome is to produce sprays with droplets of the same size, drop sizes are diverse in real applications. Therefore, adequate characterization of drop size is paramount to establishing the relations between empirical approaches proposed in the literature and the outcome of ultrasonic atomization in actual operating conditions. In this sense, this work explores new approaches to spray characterization applied to ultrasonic sprays produced with different solvents. The first two introduced are the role of redundancy in drop size measurements to avoid resolution limitation in the measurement technique and compare using regular versus variable bin widths when building the histograms of drop size. Another spray characterization tool is the Drop Size Diversity to understand the limitations of characterizing ultrasonic sprays solely based on representative diameters or moments of drop size distributions. The results of ultrasonic spray characterization obtained emphasize: the lack of universality in the relation between a characteristic diameter and the capillary length associated with Faraday waves; the variability on drop size induced by both liquid properties and flow rate on the atomization outcome, namely, lower capillary lengths produce smaller droplets but less efficiently; the higher sensibility of the polydispersion and heterogeneity degrees in Drop Size Diversity when using variable bin widths to build the histograms of drop size; the higher drop size diversity for lower flow rates expressed by the presence of multiple clusters of droplets with similar characteristics leading to multimodal drop size distributions; and the gamma and log-normal mathematical probability functions are the ones that best describe the organization of drop size data in ultrasonic sprays.


2011 ◽  
Vol 105 (4) ◽  
pp. 656-662 ◽  
Author(s):  
Jewe Schröder ◽  
Stefan Kraus ◽  
Bruna Bertolla Rocha ◽  
Volker Gaukel ◽  
Heike P. Schuchmann

2019 ◽  
Vol 33 (26) ◽  
pp. 3391-3406 ◽  
Author(s):  
Marvin Lüpke ◽  
Michael Leuchner ◽  
Delphis Levia ◽  
Kazuki Nanko ◽  
Shin'ichi Iida ◽  
...  

AIChE Journal ◽  
1971 ◽  
Vol 17 (3) ◽  
pp. 575-584 ◽  
Author(s):  
K. Y. Kim ◽  
W. R. Marshall

2015 ◽  
Vol 17 (1) ◽  
pp. 53-72 ◽  
Author(s):  
Katja Friedrich ◽  
Evan A. Kalina ◽  
Joshua Aikins ◽  
Matthias Steiner ◽  
David Gochis ◽  
...  

Abstract Drop size distributions observed by four Particle Size Velocity (PARSIVEL) disdrometers during the 2013 Great Colorado Flood are used to diagnose rain characteristics during intensive rainfall episodes. The analysis focuses on 30 h of intense rainfall in the vicinity of Boulder, Colorado, from 2200 UTC 11 September to 0400 UTC 13 September 2013. Rainfall rates R, median volume diameters D0, reflectivity Z, drop size distributions (DSDs), and gamma DSD parameters were derived and compared between the foothills and adjacent plains locations. Rainfall throughout the entire event was characterized by a large number of small- to medium-sized raindrops (diameters smaller than 1.5 mm) resulting in small values of Z (<40 dBZ), differential reflectivity Zdr (<1.3 dB), specific differential phase Kdp (<1° km−1), and D0 (<1 mm). In addition, high liquid water content was present throughout the entire event. Raindrops observed in the plains were generally larger than those in the foothills. DSDs observed in the foothills were characterized by a large concentration of small-sized drops (d < 1 mm). Heavy rainfall rates with slightly larger drops were observed during the first intense rainfall episode (0000–0800 UTC 12 September) and were associated with areas of enhanced low-level convergence and vertical velocity according to the wind fields derived from the Variational Doppler Radar Analysis System. The disdrometer-derived Z–R relationships reflect how unusual the DSDs were during the 2013 Great Colorado Flood. As a result, Z–R relations commonly used by the operational NEXRAD strongly underestimated rainfall rates by up to 43%.


2005 ◽  
Vol 44 (7) ◽  
pp. 1146-1151 ◽  
Author(s):  
Axel Seifert

Abstract The relation between the slope and shape parameters of the raindrop size distribution parameterized by a gamma distribution is examined. The comparison of results of a simple rain shaft model with an empirical relation based on disdrometer measurements at the surface shows very good agreement, but a more detailed discussion reveals some difficulties—for example, deviations from the gamma shape and the overestimation of collisional breakup.


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