scholarly journals Epoxidation of Linseed Oil by Performic Acid Produced In Situ

2021 ◽  
Author(s):  
Rosa Turco ◽  
Riccardo Tesser ◽  
Vincenzo Russo ◽  
Tommaso Cogliano ◽  
Martino Di Serio ◽  
...  
Keyword(s):  
Linseed Oil ◽  
Performic Acid

Sustainable Aldehyde Oxidations in Continuous Flow Using in Situ-Generated Performic Acid

2021 ◽  
Vol 9 (16) ◽  
pp. 5519-5525
Author(s):  
Michael Prieschl ◽  
Sándor B. Ötvös ◽  
C. Oliver Kappe
Keyword(s):  
Continuous Flow ◽  
Performic Acid

Application of Epoxy Resin for Improvement of the Banana Stem-Acoustic Panel

2021 ◽  
Vol 15 ◽  
Author(s):  
Mohd Azril Riduan ◽  
Mohd Jumain Jalil ◽  
Intan Suhada Azmi ◽  
Afifudin Habulat ◽  
Danial Nuruddin Azlan Raofuddin ◽  
...  
Keyword(s):  
Oleic Acid ◽  
Kinetic Modelling ◽  
Low Cost ◽  
Cost Effective ◽  
Performic Acid ◽  
High Yield ◽  
Renewable Materials ◽  
Runge Kutta Method ◽  
To Come

Background: Greener epoxidation by using vegetable oil to create an eco-friendly epoxide is being studied because it is a more cost-effective and environmentally friendly commodity that is safer than non-renewable materials. The aim of this research is to come up with low-cost solutions for banana trunk acoustic panels with kinetic modelling of epoxy-based palm oil. Method: In this study, the epoxidation of palm oleic acid was carried out by in situ performic acid to produce epoxidized palm oleic acid. Results: Banana trunk acoustic panel was successfully innovated based on the performance when the epoxy was applied. Lastly, a mathematical model was developed by using the numerical integration of the 4th order Runge-Kutta method, and the results showed that there is a good agreement between the simulation and experimental data, which validates the kinetic model. Conclusion: Overall, the peracid mechanism was effective in producing a high yield of epoxy from palm oleic acid that is useful for the improvement of acoustic panels based on the banana trunk.

scholarly journals Preparation and Characterization of Epoxidised and Acrylated Styrene/Isoprene/Styrene (SIS) Triblock Block Copolymer Based Nanocomposites

2013 ◽  
Vol 28 ◽  
pp. 84-88 ◽  
Author(s):  
Santosh Khanal ◽  
Alina Shakya ◽  
Goerg H. Michler ◽  
Boulos Youssef ◽  
Jean M. Saiter ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Chemical Society ◽  
Performic Acid ◽  
Casting Method ◽  
Immiscible Polymers ◽  
Transmission Electron ◽  
Boehmite Nanoparticles ◽  
Solution Casting Method

In this work, a commercially available Styrene-Isoprene-Styrene (SIS)triblock copolymer was modified into epoxidised version (ESIS)using performic acid generated in situ from hydrogen peroxide and formic acid. The epoxidised sample was further acrylated to prepare acrylated version (ASIS). The nanocomposites of each sample (SIS, ESIS and ASIS) were prepared using boehmite nanoparticles as filler by solution casting method. The polymers were characterized by Fourier Transform Infrared (FTIR) spectroscopy and transmission electron microscopy (TEM). TEM investigations revealed that that the epoxidation of the diene block enhanced the dispersion of the nanofiller in the polymer matrix while the segregation of the nanoparticles towards the interface of the immiscible polymers was observed in the acrylated block copolymer based nanocomposite. DOI: http://dx.doi.org/10.3126/jncs.v28i0.8112 Journal of Nepal Chemical Society Vol. 28, 2011 Page: 84-88 Uploaded Date: May 24, 2013

scholarly journals Studies of the In-Situ Epoxidation of Rubber (Hevea Brasiliensis)Seed Oil by Performic Acid

2019 ◽  
Vol 1378 ◽  
pp. 022025
Author(s):  
O.R. Obanla ◽  
J.D. Udonne ◽  
O.O. Ajani ◽  
M.E. Ojewumi ◽  
O.J. Omodara ◽  
...  
Keyword(s):  
Hevea Brasiliensis ◽  
Seed Oil ◽  
Performic Acid ◽  
In Situ Epoxidation

In situ surface treatment of nanocrystalline MFe2O4 (M=Co, Mg, Mn, Ni) spinel ferrites using linseed oil

2013 ◽  
Vol 287 ◽  
pp. 490-498 ◽  
Author(s):  
Daniel Gherca ◽  
Nicoleta Cornei ◽  
Olivier Mentré ◽  
Houria Kabbour ◽  
Sylvie Daviero-Minaud ◽  
...  
Keyword(s):  
Surface Treatment ◽  
Linseed Oil ◽  
Spinel Ferrites

scholarly journals Optimization on Epoxidation of Palm Olein by Using Performic Acid

2010 ◽  
Vol 7 (4) ◽  
pp. 1440-1448 ◽  
Author(s):  
Darfizzi Derawi ◽  
Jumat Salimon
Keyword(s):  
Palm Olein ◽  
Oxygen Carrier ◽  
Oxirane Oxygen ◽  
Performic Acid ◽  
H Nmr ◽  
Oxygen Donor ◽  
Infra Red ◽  
Stirring Effect ◽  
C Nmr

The epoxidation process of palm olein (POo) was carried out by usingin situgenerated performic acid (HCOOOH) to produce epoxidized palm olein (EPO). HCOOOH was produced by mixing of formic acid (HCOOH) as oxygen carrier and hydrogen peroxide (H2O2) as oxygen donor in various ratio of POo: HCOOH: H2O2. The effect of HCOOH and H2O2concentration, temperature, stirring effect and reaction time were studied. The presence of oxirane ring of EPO was characterised by fourier transformation infra-red (FTIR), proton and carbon nuclear magnetic resonance (1H-NMR and (13C-NMR) spectra. The results showed that an optimum oxirane oxygen content (OOC) value was obtained by using mol ratio of 1: 5: 2 at 150 minutes.

scholarly journals Technological Parameters of Epoxidation of Sesame Oil with Performic Acid

2018 ◽  
Vol 20 (3) ◽  
pp. 53-59 ◽  
Author(s):  
Marlena Musik ◽  
Eugeniusz Milchert ◽  
Kornelia Malarczyk-Matusiak
Keyword(s):  
Hydrogen Peroxide ◽  
Oxygen Content ◽  
Oxirane Oxygen ◽  
Sesame Oil ◽  
Performic Acid ◽  
Optimal Conditions ◽  
Technological Parameters ◽  
Independent Parameters ◽  
Relative Conversion

Abstract The course of epoxidation of sesame oil (SO) with performic acid formed „in situ” by the reaction of 30 wt% hydrogen peroxide and formic acid in the presence of sulfuric acid(VI) as a catalyst was studied. The most advantageous of the technological independent parameters of epoxidation are as follows: temperature 80°C, H2O2/ C=C 3.5:1, HCOOH/C=C 0.8:1, amount of catalyst as H2SO4/(H2O2+HCOOH) 1 wt%, stirring speed at least 700 rpm, reaction time 6 h. The iodine number (IN), epoxy number (EN), a relative conversion to oxirane (RCO) and oxirane oxygen content (EOe) were determined every hour during the reaction. Under optimal conditions the sesame oil conversion amounted to 90.7%, the selectivity of transformation to epoxidized sesame oil was equal to 93.2%, EN = 0.34 mol/100 g, IN = 0.04 mol/100 g oil (10.2 g/100 g oil), a relative conversion to oxirane RCO = 84.6%, and oxirane oxygen content of EOe = 5.5%.

scholarly journals Surfactant-Assisted Selective Oxidation of Aromatic Amines to Nitro Compounds by in Situ-Formed Performic Acid

ACS Omega ◽  
2019 ◽  
Vol 4 (5) ◽  
pp. 9453-9457 ◽  
Author(s):  
Krishnan Ravi ◽  
Balasaheb D. Bankar ◽  
Sana Jindani ◽  
Ankush V. Biradar
Keyword(s):  
Selective Oxidation ◽  
Aromatic Amines ◽  
Nitro Compounds ◽  
Performic Acid ◽  
Surfactant Assisted

Fabrication and characterization of in situ graphene oxide reinforced high-performance shape memory polymeric nanocomposites from vegetable oil

RSC Advances ◽  
2016 ◽  
Vol 6 (33) ◽  
pp. 27648-27658 ◽  
Author(s):  
Rakesh Das ◽  
Sovan Lal Banerjee ◽  
P. P. Kundu
Keyword(s):  
Graphene Oxide ◽  
High Performance ◽  
Linseed Oil ◽  
Polymeric Nanocomposites ◽  
Modified Graphene Oxide ◽  
Fabrication And Characterization ◽  
Surface Modified ◽  
Modified Graphene

Polymeric nanocomposites have been fabricated via in situ cationic polymerization of linseed oil in the presence of surface-modified graphene oxide (SGO).

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