Two Anthracene-Based Ir(III) Complexes [Ir(pbt)2(aip)]Cl and [Ir(pbt)2(aipm)]Cl: Relationship between Substituent Group and Photo-oxidation Activity as Well as Photo-oxidation-Induced Luminescence

2020 ◽  
Vol 59 (23) ◽  
pp. 17071-17076
Author(s):  
Qin-Zhen Yuan ◽  
Qianwenhao Fan ◽  
Hang Lv ◽  
Wen-Wen Chen ◽  
Xue-Xiao Yang ◽  
...  
Keyword(s):  
Oxidation Activity ◽  
Photo Oxidation ◽  
Substituent Group

scholarly journals Non‐Sacrificial Water Photo‐Oxidation Activity of Lamellar Calcium Niobate Induced by Exfoliation

2014 ◽  
Vol 1 (7) ◽  
pp. 1400131 ◽  
Author(s):  
Takayoshi Oshima ◽  
Osamu Ishitani ◽  
Kazuhiko Maeda
Keyword(s):  
Oxidation Activity ◽  
Photo Oxidation ◽  
Calcium Niobate

Preparation and enhanced photocatalytic oxidation activity of surface-modified CdS nanoparticles with high photostability

1999 ◽  
Vol 14 (5) ◽  
pp. 2092-2095 ◽  
Author(s):  
M. Y. Han ◽  
W. Huang ◽  
C. H. Quek ◽  
L. M. Gan ◽  
C. H. Chew ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Surface Modification ◽  
Photocatalytic Oxidation ◽  
Uv Light ◽  
Cds Nanoparticles ◽  
Oxidation Activity ◽  
Chemical Surface ◽  
Photo Oxidation ◽  
Chemical Surface Modification ◽  
Surface Modified

Highly photostable CdS nanoparticles modified with an alkyl group were prepared by an improved microemulsion technique using hexanethiol as cosurfactant. The surface-modified CdS nanoparticles catalyzed the photo-oxidation of 4-chlorophenol via continuously bubbling oxygen under uv light. The photocatalytic oxidation activity of the CdS nanoparticles was enhanced due to the formation of their compact CdS cores with strong chemical surface modification by heat treatment.

Improving photo-oxidation activity of water by introducing Ti3+ in self-ordered TiO2 nanotube arrays treated with Ar/NH3

2019 ◽  
Vol 414 ◽  
pp. 242-249 ◽  
Author(s):  
Yin Xu ◽  
Rasin Ahmed ◽  
David Klein ◽  
Sebastien Cap ◽  
Keren Freedy ◽  
...  
Keyword(s):  
Tio2 Nanotube Arrays ◽  
Tio2 Nanotube ◽  
Nanotube Arrays ◽  
Oxidation Activity ◽  
Photo Oxidation

Peroxisome proliferation: Organelles or activity as an endpoint?

1993 ◽  
Vol 51 ◽  
pp. 396-397
Author(s):  
Catherine A. Taylor ◽  
Bruce M. Jarnot
Keyword(s):  
Acid Oxidation ◽  
Peroxisome Proliferation ◽  
Post Dose ◽  
Oxidation Activity ◽  
Wasting Syndrome ◽  
Perfluorodecanoic Acid ◽  
Hypolipidemic Agent ◽  
Commercially Important ◽  
Acyl Coa Oxidase ◽  
Mitochondrial Disruption

Peroxisome induction can be expressed as an increase in peroxisome area (proliferation) or as an increase in peroxisomal fatty acid oxidation (activity). This study compares proliferation and activity as endpoints for hepatic peroxisome induction by perfluorodecanoic acid (PFDA). Fluorocarboxylic acids such as PFDA represent a class of compounds possessing commercially important surfactant properties. A single 50 mg/Kg ip. dose of PFDA produces a characteristic “wasting syndrome” in male F-344 rats. Symptoms include hypophagia, weight loss, hepatomegaly, and delayed lethality. Hepatic studies reveal changes similar to those seen with the hypolipidemic agent clofibrate. These include mitochondrial disruption, endoplasmic reticulum and peroxisome proliferation, and increased peroxisomal acyl-CoA oxidase activity.Male Fisher-344 rats received a single ip. dose of 2, 20, or 50mg/Kg PFDA dissolved in 1:1 propylene glycol/water and were sacrificed 8 days post-dose. All control rats received an equal volume of vehicle ip. Animals were provided food and water ad libitum, except pair-fed controls which received the same restrictive food intake consumed by their weight-paired dosed partners (50mg/Kg PFDA group) to simulate the hypophagia associated with PFDA.

Treatment of wastewater from oil manufacturing plant by yeasts

1996 ◽  
Vol 34 (11) ◽  
pp. 51-58 ◽  
Author(s):  
K. Chigusa ◽  
T. Hasegawa ◽  
N. Yamamoto ◽  
Y. Watanabe
Keyword(s):  
Pilot Plant ◽  
Removal Rate ◽  
Oil Removal ◽  
Oxidation Activity ◽  
Single Strain ◽  
Manufacturing Plants ◽  
Yeast Strains ◽  
Hexane Extracts ◽  
One Year ◽  
Raw Wastewater

Nine strains of yeasts capable of decomposing oil were isolated in order to directly treat wastewater from oil manufacturing plants with no pretreatment. The oil decomposing ability of these yeast strains was evaluated in terms of lipase activity and β-oxidation activity. Since the mixture of the isolated yeasts was superior to any single strain in the oil removal rate, a pilot plant utilizing the mixed strains was operated at the soybean oil factory. Following a one year pilot plant operation, it was found that 10,000 mgℓ−1 of hexane extracts in the raw wastewater could be reduced by yeast treatment to a concentration of about 100 mgℓ−1. This concentration was further treated by the activated sludge process to 2 mgℓ−1. The dominant yeasts in the pilot plant were found to form mycelial or pseudomycelial pellets and have low fermenting ability.

Polymer oxidation catalyst containing acidic functional groups

1981 ◽  
Vol 46 (5) ◽  
pp. 1237-1247
Author(s):  
Zdeněk Prokop ◽  
Karel Setínek
Keyword(s):  
Functional Groups ◽  
Elevated Temperatures ◽  
Redox Properties ◽  
Oxidation Catalyst ◽  
Carbon Clusters ◽  
Oxidation Activity ◽  
Redox Sites ◽  
Styrene Divinylbenzene ◽  
Proportional Decrease ◽  
Polymer Oxidation

The catalyst containing redox sites in addition to acid functional groups was prepared by sulphonation of a macroporous chloromethylated styrene-divinylbenzene copolymer with concentrated sulphuric acid at elevated temperatures. Its activity was tested for the oxidation of 2-propanol by molecular oxygen at 120 °C and was found to be comparable to that of the iridium on carbon catalyst.Neutralisation of acid functional groups by alkali metal led to proportional decrease in the oxidation activity. The results of EPR spectroscopic study of these catalysts show that the redox properties of the polymer are caused by carbon clusters which are capable of electron exchange.

Nanoscale Structural and Chemical Segregation in Pt50Ru50 Electrocatalysts

2001 ◽  
Vol 7 (S2) ◽  
pp. 1112-1113
Author(s):  
Rhonda M. Stroud ◽  
Jeffrey W. Long ◽  
Karen E. Swider-Lyons ◽  
Debra R. Rolison
Keyword(s):  
Methanol Oxidation ◽  
Structural Heterogeneity ◽  
Oxidation Activity ◽  
Bimetallic Alloy ◽  
Transmission Electron ◽  
Chemical Segregation ◽  
High Fraction ◽  
Argon Mixture ◽  
Microscopy Techniques ◽  
Electron Energy Loss

To address how the chemical and structural heterogeneity of Pt50Ru50 nanoparticles affects methanol oxidation activity, we have employed an arsenal of transmission electron microscopy techniques (conventional bright field-imaging, selected area diffraction, atomic-resolution lattice imaging, electron-energy loss spectroscopy, and energy-dispersive x-ray spectroscopy) to characterize 2.5-nm particles in differing oxidation and hydration states. Our studies demonstrate that electrocatalysts containing a high fraction of Ru-rich hydrous oxide, as apposed to the anhydrous PtRu bimetallic alloy, have as much as 250x higher methanol oxidation activityThe nominally 2.5-nm Pt50Ru50 particles were studied in as-received, reduced and reoxidized forms. The reducing treatment consisted of 2 h at 100 °C in flowing 10% PL/argon mixture. For re-oxidation, the reduced particles were heated for 20 h at 100 °C in an H2O-saturated oxygen atmosphere. The particles were suspended in methanol, and pipetted onto holey-carboncoated Cu grids for TEM studies.

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