Water-Stable Metal–Organic Framework with Three Hydrogen-Bond Acceptors: Versatile Theoretical and Experimental Insights into Adsorption Ability and Thermo-Hydrolytic Stability

Zn(ii)-based MOF for detecting FOX-7 like explosives is designed via hydrogen-bond-intensified host–guest interactions. The crystalline MOF achieves 0.14 ppm detection limit and a highest fluorescence quenching constant of 3.22 × 104 M−1.

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Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework

Nature Communications ◽

10.1038/s41467-020-16897-z ◽

2020 ◽

Vol 11 (1) ◽

Cited By ~ 1

Author(s):

Julia Oktawiec ◽

Henry Z. H. Jiang ◽

Jenny G. Vitillo ◽

Douglas A. Reed ◽

Lucy E. Darago ◽

...

Keyword(s):

Hydrogen Bond ◽

Metal Organic Framework ◽

Negative Cooperativity ◽

O2 Adsorption ◽

Redox Active ◽

Active Metal ◽

Metal Organic ◽

Redox Active Metal ◽

Organic Framework

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Coordinative Reduction of Metal Nodes Enhances the Hydrolytic Stability of a Paddlewheel Metal–Organic Framework

Journal of the American Chemical Society ◽

10.1021/jacs.9b02114 ◽

2019 ◽

Vol 141 (19) ◽

pp. 7853-7864 ◽

Cited By ~ 18

Author(s):

Dahae Song ◽

Jinhee Bae ◽

Hoon Ji ◽

Min-Bum Kim ◽

Youn-Sang Bae ◽

...

Keyword(s):

Metal Organic Framework ◽

Hydrolytic Stability ◽

Metal Organic ◽

Organic Framework

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A Copper(II)-Paddlewheel Metal–Organic Framework with Exceptional Hydrolytic Stability and Selective Adsorption and Detection Ability of Aniline in Water

ACS Applied Materials & Interfaces ◽

10.1021/acsami.7b07920 ◽

2017 ◽

Vol 9 (32) ◽

pp. 27027-27035 ◽

Cited By ~ 49

Author(s):

Ya Chen ◽

Bin Wang ◽

Xiaoqing Wang ◽

Lin-Hua Xie ◽

Jinping Li ◽

...

Keyword(s):

Selective Adsorption ◽

Metal Organic Framework ◽

Hydrolytic Stability ◽

Detection Ability ◽

Metal Organic ◽

Organic Framework

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Influence of Hydrogen Bond Donating Sites in UiO‐66 Metal‐Organic Framework for Highly Regioselective Methanolysis of Epoxides

ChemCatChem ◽

10.1002/cctc.201902219 ◽

2020 ◽

Vol 12 (6) ◽

pp. 1789-1798 ◽

Cited By ~ 1

Author(s):

Aniruddha Das ◽

Nagaraj Anbu ◽

Mostakim Sk ◽

Amarajothi Dhakshinamoorthy ◽

Shyam Biswas

Keyword(s):

Hydrogen Bond ◽

Metal Organic Framework ◽

Metal Organic ◽

Organic Framework

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Simultaneous implementation of resistive switching and rectifying effects in a metal-organic framework with switched hydrogen bond pathway

Science Advances ◽

10.1126/sciadv.aaw4515 ◽

2019 ◽

Vol 5 (8) ◽

pp. eaaw4515 ◽

Cited By ~ 24

Author(s):

Zizhu Yao ◽

Liang Pan ◽

Lizhen Liu ◽

Jindan Zhang ◽

Quanjie Lin ◽

...

Keyword(s):

Hydrogen Bond ◽

Resistive Switching ◽

Metal Organic Framework ◽

Random Access ◽

Resistive Random Access Memory ◽

Information Storage ◽

X Ray Diffraction ◽

Metal Organic ◽

Simultaneous Implementation ◽

Organic Framework

Resistive random-access memory (RRAM) has evolved as one of the most promising candidates for the next-generation memory, but bistability for information storage, simultaneous implementation of resistive switching and rectification effects, and a better understanding of switching mechanism are still challenging in this field. Herein, we report a RRAM device based on a chiral metal-organic framework (MOF) FJU-23-H2O with switched hydrogen bond pathway within its channels, exhibiting an ultralow set voltage (~0.2 V), a high ON/OFF ratio (~105), and a high rectification ratio (~105). It is not only the first MOF with voltage-gated proton conduction but also the first single material showing both rectifying and resistive switching effects. By single-crystal x-ray diffraction analyses, the mechanism of the resistive switching has been demonstrated.

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