Ternary Organic Solar Cells with Coumarin7 as the Donor Exhibiting Greater Than 10% Power Conversion Efficiency and a High Fill Factor of 75%

2017 ◽  
Vol 9 (35) ◽  
pp. 29907-29916 ◽  
Author(s):  
Xin-Wei Chen ◽  
Si-Lu Tao ◽  
Cong Fan ◽  
Dong-Cheng Chen ◽  
Ling Zhou ◽  
...  
2013 ◽  
Vol 378 ◽  
pp. 125-130
Author(s):  
Murtaza Imran

In contrast to the solar cells based on inorganic semiconductors, organic solar cells degrade during illumination. Therefore, the influence of the illumination time on the efficiencies of an organic solar cell is investigated which reveals that under steady-state illumination at 1 sun (100 mW/cm2) the efficiency of the solar cell with the structure of ITO/CuPc/C60/BCP/Ag degrade significantly over few hours. There are three efficiencies that are of interest; Fill Factor (FF), Power Conversion Efficiency (PCE), and Quantum Yield (QY). Fill factor decreased less than power conversion efficiency and quantum yield, indicating that the degradation in those efficiencies is caused by photon-induced damage to the molecules that did not lead to an increase in internal resistance.


RSC Advances ◽  
2015 ◽  
Vol 5 (3) ◽  
pp. 2155-2158 ◽  
Author(s):  
Luting Ling ◽  
Qiang Zhang ◽  
Lin Zhu ◽  
Cai-Feng Wang ◽  
Su Chen

A new interfacial synthesis of colloidal SnSe quantum dots (QDs) was realized from common precursors at a mild condition. SnSe QD-sensitized solar cells were fabricated to show an improved power conversion efficiency with a high fill factor of 0.71.


2020 ◽  
Vol 11 (16) ◽  
pp. 2883-2888 ◽  
Author(s):  
Liuyuan Lan ◽  
Xiang Deng ◽  
Jie Zhang ◽  
Jingdong Luo ◽  
Alex K.-Y. Jen

Mitsunobu post-functionalization was utilized to construct a new efficient dopant-free side-chain hole transporting polymer for inverted perovskite solar cells, exhibiting a power conversion efficiency of 17.75% and a high fill factor over 81%.


2019 ◽  
Vol 16 (3) ◽  
pp. 236-243 ◽  
Author(s):  
Hui Zhang ◽  
Yibing Ma ◽  
Youyi Sun ◽  
Jialei Liu ◽  
Yaqing Liu ◽  
...  

In this review, small-molecule donors for application in organic solar cells reported in the last three years are highlighted. Especially, the effect of donor molecular structure on power conversion efficiency of organic solar cells is reported in detail. Furthermore, the mechanism is proposed and discussed for explaining the relationship between structure and power conversion efficiency. These results and discussions draw some rules for rational donor molecular design, which is very important for further improving the power conversion efficiency of organic solar cells based on the small-molecule donor.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Zhenrong Jia ◽  
Shucheng Qin ◽  
Lei Meng ◽  
Qing Ma ◽  
Indunil Angunawela ◽  
...  

AbstractTandem organic solar cells are based on the device structure monolithically connecting two solar cells to broaden overall absorption spectrum and utilize the photon energy more efficiently. Herein, we demonstrate a simple strategy of inserting a double bond between the central core and end groups of the small molecule acceptor Y6 to extend its conjugation length and absorption range. As a result, a new narrow bandgap acceptor BTPV-4F was synthesized with an optical bandgap of 1.21 eV. The single-junction devices based on BTPV-4F as acceptor achieved a power conversion efficiency of over 13.4% with a high short-circuit current density of 28.9 mA cm−2. With adopting BTPV-4F as the rear cell acceptor material, the resulting tandem devices reached a high power conversion efficiency of over 16.4% with good photostability. The results indicate that BTPV-4F is an efficient infrared-absorbing narrow bandgap acceptor and has great potential to be applied into tandem organic solar cells.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
S. Wageh ◽  
Mahfoudh Raïssi ◽  
Thomas Berthelot ◽  
Matthieu Laurent ◽  
Didier Rousseau ◽  
...  

AbstractPoly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) mixed with single-wall nanotubes (SWNTs) (10:1) and doped with (0.1 M) perchloric acid (HClO4) in a solution-processed film, working as an excellent thin transparent conducting film (TCF) in organic solar cells, was investigated. This new electrode structure can be an outstanding substitute for conventional indium tin oxide (ITO) for applications in flexible solar cells due to the potential of attaining high transparency with enhanced conductivity, good flexibility, and good durability via a low-cost process over a large area. In addition, solution-processed vanadium oxide (VOx) doped with a small amount of PEDOT-PSS(PH1000) can be applied as a hole transport layer (HTL) for achieving high efficiency and stability. From these viewpoints, we investigate the benefit of using printed SWNTs-PEDOT-PSS doped with HClO4 as a transparent conducting electrode in a flexible organic solar cell. Additionally, we applied a VOx-PEDOT-PSS thin film as a hole transporting layer and a blend of PTB7 (polythieno[3,4-b] thiophene/benzodithiophene): PC71BM (phenyl-C71-butyric acid methyl ester) as an active layer in devices. Zinc oxide (ZnO) nanoparticles were applied as an electron transport layer and Ag was used as the top electrode. The proposed solar cell structure showed an enhancement in short-circuit current, power conversion efficiency, and stability relative to a conventional cell based on ITO. This result suggests a great carrier injection throughout the interfacial layer, high conductivity and transparency, as well as firm adherence for the new electrode.


Author(s):  
Minkyu Kyeong ◽  
Jinho Lee ◽  
Matyas Daboczi ◽  
Katherine Stewart ◽  
Huifeng Yao ◽  
...  

Functionalized polyethyleneimines that are compatible with non-fullerene acceptors have been developed by protecting the reactive amine groups, leading to non-fullerene solar cells with high power conversion efficiency and enhanced thermal stability.


1981 ◽  
Vol 59 (6) ◽  
pp. 727-732 ◽  
Author(s):  
Rafik O. Loutfy ◽  
Cheng-Kuo Hsiao

The effect of temperature on the photovoltaic properties of indium/metal-free phthalocyanine Schottky barrier solar cells was investigated in the range 260–350 K. In general, the short circuit photocurrent, Jsc, and fill factor, ff, increased with increasing temperature (in contrast to inorganic photocells). The device series resistance and open circuit photovoltage, Voc, decreased (similar to inorganic photocells) as temperature was raised. An increase in the overall power conversion efficiency, η, has been observed with increase of temperature. In the case of x-H2Pc, the power conversion efficiency increased by 2.5 times due to a temperature rise of 60 °C above ambient. Thus, for operation at temperatures above ambient, organic solar cells may offer a significant advantage over inorganic cells.Analysis of the variation of the photovoltage with temperature showed that the decrease in Voc is mainly due to variation injunction impedance, which is controlled by thermionic current at high temperature and ionized impurity at low temperature.


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