Simple Determination of Herbicides in Rice Paddy Water by Immunoassay

Author(s):  
Shiro Miyake ◽  
Yasuo Ishii ◽  
Yuki Yamaguchi ◽  
Katsuya Ohde ◽  
Minoru Motoki ◽  
...  
Keyword(s):  
2014 ◽  
Vol 97 (4) ◽  
pp. 987-994 ◽  
Author(s):  
Mateus B Pereira ◽  
Janice F Facco ◽  
Gabriela M Zemolin ◽  
Manoel L Martins ◽  
Osmar D Prestes ◽  
...  

Abstract Pollution of water sources by pesticides is a result of intensive use of these compounds, and the establishment of analytical methods for monitoring programs is very important. This paper presents a method for the determination of multiclass pesticide residues in rice paddy water based on SPE and GC/MS/MS. The validation results were satisfactory. All compounds showed adequate linearity (r2 ≥ 0.99), and analysis by GC/MS/MS with a triple quadrupole mass spectrometer gave high selectivity and sensitivity. With the proposed SPE step an LOD of 0.06 μg/L was achieved. Recoveries from blank samples spiked at 0.2, 04, and 0.8 μg/L were between 70 and 120% with RSD <20% for most analyzed compounds, despite their different chemical nature, indicating good accuracy and precision. The proposed method is efficient for pesticide residue determination, including some metabolites, and gave good performance when applied to real samples.


1989 ◽  
Vol 72 (5) ◽  
pp. 845-847
Author(s):  
Keith W Beauchamp ◽  
Dave D W Liu ◽  
Edward J Kikta

Abstract A procedure for the determination of carbofuran and its metabolites (carbamate and phenolic) in rice paddy water is described. Water samples are concentrated on a C-18 solid phase extraction (SPE) column and eluted with methanol-water. The eluate is analyzed by reverse-phase liquid chromatography (LC) and measured by a wavelength programmable ultraviolet (UV) detector. The limit of detection for the method is 0.4 μg/L. Recovery studies were carried out at levels ranging from 1 to 15 μg/L in both rice paddy water and distilled water; recoveries ranged from 85.9 to 112.9%.


2016 ◽  
Vol 13 (8) ◽  
pp. 2429-2440 ◽  
Author(s):  
Lei Zhao ◽  
Christopher W. N Anderson ◽  
Guangle Qiu ◽  
Bo Meng ◽  
Dingyong Wang ◽  
...  

Abstract. Rice paddy plantation is the dominant agricultural land use throughout Asia. Rice paddy fields have been identified as important sites for methylmercury (MeHg) production in the terrestrial ecosystem and a primary pathway of MeHg exposure to humans in mercury (Hg) mining areas. We compared the source and distribution of Hg species in different compartments of the rice paddy during a complete rice-growing season at two different typical Hg-contaminated mining sites in Guizhou province, China: an abandoned site with a high Hg concentration in soil but a low concentration in the atmosphere and a current-day artisanal site with a low concentration in soil but a high concentration in the atmosphere. Our results showed that the flux of new Hg to the ecosystem from irrigation and atmospheric deposition was insignificant relative to the pool of old Hg in soil; the dominant source of MeHg to paddy soil is in situ methylation of inorganic Hg (IHg). Elevated MeHg concentrations and the high proportion of Hg as MeHg in paddy water and the surface soil layer at the artisanal site demonstrated active Hg methylation at this site only. We propose that the in situ production of MeHg in paddy water and surface soil is dependent on elevated Hg in the atmosphere and the consequential deposition of new Hg into a low-pH anoxic geochemical system. The absence of depth-dependent variability in the MeHg concentration in soil cores collected from the abandoned Hg mining site, consistent with the low concentration of Hg in the atmosphere and high pH of the paddy water and irrigation water, suggested that net production of MeHg at this site was limited. We propose that the concentration of Hg in ambient air is an indicator for the risk of MeHg accumulation in paddy rice.


Author(s):  
Renato Zanella ◽  
Martha B. ◽  
Sandra C. ◽  
Caroline do A. Friggi ◽  
Osmar D. ◽  
...  

2014 ◽  
Vol 44 (8) ◽  
pp. 1392-1397 ◽  
Author(s):  
Geovane Boschmann Reimche ◽  
Sérgio Luiz de Oliveira Machado ◽  
Renato Zanella ◽  
Michele Câmara de Vicari ◽  
Fernando Piccinini ◽  
...  

The aim of this study was to assess the effect of concentrations of imazethapyr, imazapic, and bispyribac-sodium herbicides on zooplankton community (Cladocer, Copepod and Rotifer) in rice paddy fields. The decrease of half-life dissipation (DT50) of the herbicides under study in water was: imazethapyr, imazapic, and bispyribac-sodium with an average of 3.75, 3.73 and 1.91 days, respectively. The mixture of imazethapyr with imazapic caused change in the analyzed zooplankton, with an increase in the densities of Cladocer and adult Copepod groups, while bispyribac-sodium caused a reduction of density in Copepod group, both adults and nauplii, in the initial samples. Among the groups, Rotifer was slightly sensitive to the herbicides.


2018 ◽  
Vol 23 (4) ◽  
pp. 536-539
Author(s):  
Muhammad Athar Khan ◽  
Muhammad Zahid Latif ◽  
Syed Amir Gilani ◽  
Ifrah Bukhari

Leptospirosis is a global zoonotic infectious disease having alarming public health concerns. Generally this is an occupation related disease and the victims belong to animal slaughtering, owners of pet shops, farm workers, handlers of meat, sewerage and agriculture workers. Leptospirosis affect multiple organs in human body and may lead to myocarditis, renal failure, respiratory distress and hypotension. This disease is an emerging infectious problem in many developing countries like Pakistan. A total of 250 subjects were selected from five different rice growing districts of Punjab, Pakistan after the approval of institutional ethical review board (IERB), 250 subjects were selected for this comparative cross sectional study. Multiple stage probability technique was used for sampling. In the first stage one union council was selected from each district randomly. In the second stage, 25 subjects involved in rice cultivation from the last 10 years wereselected from each union council. Similarly 25 subjects who never worked in the rice paddy field were also randomly selected from each union council as controls. The serum sample of each subject was tested against each of the five antigens against the serovars. A total of 250 subjects were included in the study. Out of these, 125 subjects were exposed to the rice paddy water where as 125 were not exposed to rice paddy water. The cumulative seropositivity among the exposed is (83.2%) as compared to (42%) among the non exposed to rice paddy field water. The calculated cumulative odds ratio is 6.7 which represent a strong association of the risk for the development of disease among the exposed than the non exposed subjects. Leptospirosis is a public health zoonotic disease which is widely present in tropical and sub tropical areas. This study concludes that there is a strong association of rice cultivation with Leptospirosis. It is recommended that rice cultivators should protect their body parts with gloves or boots as prevention is the most appropriate way to control any disease.


Author(s):  
Abdur Rahim

This study aims to determine the impact of the Pandan Duri dam on changes in the Crop Index (IP) and changes in the productivity level of rice paddy farming in West Sakra District, East Lombok Regency. The method in this research is descriptive, data collection is done by survey technique. Determination of the number of samples as many as 30 people is done by sampling quota and taking farmers in each village is done by proportional random sampling and determining the village as a sample is done by purposive sampling. The results showed that: 1) The total planting index (IP) of lowland rice before the Pandan Duri dam in West Sakra District was 1.39 and after 2.12. This means that the existence of the Pandan Duri dam can have an impact on the difference in the Crop Index (IP) of lowland rice farming in Sakra District and, 2) The average productivity of rice before the Pandan Duri dam in West Sakra District was 49,682 Kw/Ha while after the Pandan Duri dam was 57,267 Kw/Ha and there was a significant difference at the alpha 5% (0,05) level.or in the other word, that the existence of Pandan Duri development has real/significant impact on the productivity of lowland rice farming in West Sakra District, East Lombok Regency


1978 ◽  
Vol 13 (2) ◽  
pp. 131-148 ◽  
Author(s):  
J. N. Seiber ◽  
M. P. Catahan ◽  
C. R. Barril

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