Flexible Building Blocks ofN,N‘-Bis(picolinoyl)hydrazine for Hydrogen-Bonding Directed Cocrystallization:  Structural Diversity, Concomitant Polymorphs, and Synthon Prediction

2006 ◽  
Vol 6 (8) ◽  
pp. 1867-1875 ◽  
Author(s):  
Miao Du ◽  
Zhi-Hui Zhang ◽  
Xiu-Guang Wang ◽  
Hui-Fang Wu ◽  
Qian Wang
Keyword(s):  
Hydrogen Bonding ◽  
Structural Diversity ◽  
Building Blocks

scholarly journals 1,3-Diketone Calix[4]arene Derivatives—A New Type of Versatile Ligands for Metal Complexes and Nanoparticles

Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1214
Author(s):  
Sergey N. Podyachev ◽  
Rustem R. Zairov ◽  
Asiya R. Mustafina
Keyword(s):  
Structural Diversity ◽  
Building Blocks ◽  
Structural Features ◽  
Structure Property ◽  
One Pot ◽  
Arene Ligands ◽  
Structure Property Relationships ◽  
New Type ◽  
Synthetic Routes ◽  
Magnetic Resonance Imaging Mri

The present review is aimed at highlighting outlooks for cyclophanic 1,3-diketones as a new type of versatile ligands and building blocks of the nanomaterial for sensing and bioimaging. Thus, the main synthetic routes for achieving the structural diversity of cyclophanic 1,3-diketones are discussed. The structural diversity is demonstrated by variation of both cyclophanic backbones (calix[4]arene, calix[4]resorcinarene and thiacalix[4]arene) and embedding of different substituents onto lower or upper macrocyclic rims. The structural features of the cyclophanic 1,3-diketones are correlated with their ability to form lanthanide complexes exhibiting both lanthanide-centered luminescence and magnetic relaxivity parameters convenient for contrast effect in magnetic resonance imaging (MRI). The revealed structure–property relationships and the applicability of facile one-pot transformation of the complexes to hydrophilic nanoparticles demonstrates the advantages of 1,3-diketone calix[4]arene ligands and their complexes in developing of nanomaterials for sensing and bioimaging.

scholarly journals Straightforward Preparation of Supramolecular Janus Nanorods by Hydrogen Bonding of End-Functionalized Polymers

2020 ◽  
Author(s):  
Shuaiyuan Han ◽  
Sandrine Pensec ◽  
Cédric Lorthioir ◽  
Jacques Jestin ◽  
Jean-Michel Guigner ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Self Assembly ◽  
Functional Materials ◽  
Phase Segregation ◽  
Building Blocks ◽  
Functionalized Polymers ◽  
Nanometer Range ◽  
One Dimensional ◽  
Oil In Water ◽  
First Time

Janus cylinders are one-dimensional colloids that have two faces with different compositions and functionalities and are useful as building blocks for advanced functional materials. Such anisotropic objects are difficult to prepare with nanometric dimensions. Here we describe a robust and versatile strategy to form micrometer long Janus nanorods with diameters in the 10-nanometer range, by self-assembly in water of end-functionalized polymers. For the first time, the Janus topology is not a result of the phase segregation of incompatible polymer arms, but is driven by the interactions between unsymmetrical and complementary hydrogen bonded stickers. It is therefore independent of the actual polymers used and works even for compatible polymers. To illustrate their applicative potential, we show that these Janus nanorods can efficiently stabilize oil-in-water emulsions.

Functional phosphorus-based π-conjugated systems: Structural diversity without multistep synthesis

2007 ◽  
Vol 79 (2) ◽  
pp. 201-212 ◽  
Author(s):  
Muriel Hissler ◽  
Christophe Lescop ◽  
Régis Réau
Keyword(s):  
Structural Diversity ◽  
Building Blocks ◽  
Transition Metal Ions ◽  
Organic Light Emitting Diodes ◽  
Supramolecular Organization ◽  
Chemical Transformations ◽  
Light Emitting ◽  
Conjugated Systems ◽  
Multistep Synthesis ◽  
Organic Light

The synthesis and properties of linear π-conjugated systems incorporating phosphole rings are described. Their supramolecular organization in the solid state can be controlled either by chemical modifications or coordination to transition metals of the phosphorus atom. Furthermore, chemical transformations of the phosphole ring allow organizing these P-chromophores in 3D assemblies exhibiting σ-π conjugation or in organometallic ferrocene-like derivatives. Phosphole-pyridine-containing π-conjugated chromophores act as P,N-chelates toward transition-metal ions, giving rise to mono- and di-nuclear complexes. The specific properties of these complexes make them valuable materials for organic light-emitting diodes (OLEDs) and interesting building blocks for the tailoring of π-conjugated systems.

2-Pyridyl Tosylate Derivatives-Building Blocks for Structural Diversity via Transition Metal Catalysis

2010 ◽  
Vol 50 (5-6) ◽  
pp. 558-567 ◽  
Author(s):  
Anders T. Lindhardt ◽  
Thomas M. Gøgsig ◽  
Delphine Gauthier ◽  
Daniel Lupp ◽  
Mette Louise Hallager Mantel ◽  
...  
Keyword(s):  
Transition Metal ◽  
Structural Diversity ◽  
Building Blocks ◽  
Transition Metal Catalysis ◽  
Metal Catalysis

Unusual Two-Dimensional Nickel(II) Complexes Based on [Ni(dien)]2+ and [M(CN)4]2− Building Blocks (M = Ni, Pd and Pt)− Synthesis, Structural Diversity and Magnetic Properties

2004 ◽  
Vol 2004 (9) ◽  
pp. 1886-1893 ◽  
Author(s):  
Iñaki Muga ◽  
Juan M. Gutiérrez-Zorrilla ◽  
Pablo Vitoria ◽  
Pascual Román ◽  
Luis Lezama ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Structural Diversity ◽  
Building Blocks ◽  
Two Dimensional

Hydrothermal Synthesis and Structure Characterization of a Bi-Capped Keggin Heteropoly Molybdovanadated Derivative

2014 ◽  
Vol 1004-1005 ◽  
pp. 542-545
Author(s):  
Ya Bing Liu ◽  
Li Guang Xiao
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Building Blocks ◽  
Crystal Structure Analysis ◽  
Structure Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Hydrogen Bonding Interactions ◽  
Supramolecular Networks

A new bi-capped Keggin heteropoly molybdovanadated derivative, [Co (en)3]2[SiMo8V6O42]∙6H2O (1) (en = ethylendiamine) has been hydrothermally synthesized and structurally characterized by the elemental analysis, IR, XPS and single crystal X-ray diffraction. The crystal structure analysis reveals that compound 1 consists of [Co (en)3]2+transition metal coordination fragment and the [SiMo8V6O42]4-building blocks, which are linked together via hydrogen-bonding interactions to form a new 3-D supramolecular networks.

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