Electrical properties of carbon dioxide hydrate: Implications for monitoring CO 2 in the gas hydrate stability zone

Author(s):  
Laura A. Stern ◽  
Steven Constable ◽  
Ryan Lu ◽  
Wyatt L. Du Frane ◽  
Jeffery J. Roberts
2021 ◽  
Author(s):  
Hariharan Ramachandran ◽  
Andreia Plaza-Faverola ◽  
Hugh Daigle ◽  
Stefan Buenz

<p>Evidences of subsurface fluid flow-driven fractures (from seismic interpretation) are quite common at Vestnesa Ridge (around 79ºN in the Arctic Ocean), W-Svalbard margin. Ultimately, the fractured systems have led to the formation of pockmarks on the seafloor. At present day, the eastern segment of the ridge has active pockmarks with continuous methane seep observations in sonar data. The pockmarks in the western segment are considered inactive or to seep at a rate that is harder to identify. The ridge is at ~1200m water depth with the base of the gas hydrate stability zone (GHSZ) at ~200m below the seafloor. Considerable free gas zone is present below the hydrates. Besides the obvious concern of amount and rates of historic methane seeping into the ocean biosphere and its associated effects, significant gaps exist in the ability to model the processes of flow of methane through this faulted and fractured region. Our aim is to highlight the interactions between physical flow, geomechanics and geological control processes that govern the rates and timing of methane seepage.</p><p>For this purpose, we performed numerical fluid flow simulations. We integrate fundamental mass and component conservation equations with a phase equilibrium approach accounting for hydrate phase boundary effects to simulate the transport of gas from the base of the GHSZ through rock matrix and interconnected fractures until the seafloor. The relation between effective stress and fluid pressure is considered and fractures are activated once the effective stress exceeds the tensile limit. We use field data (seismic, oedometer tests on calypso cores, pore fluid pressure and temperature) to constrain the range of validity of various flow and geomechanical parameters in the simulation (such as vertical stress, porosity, permeability, saturations).</p><p>Preliminary results indicate fluid overpressure greater than 1.5 MPa is required to initiate fractures at the base of the gas hydrate stability zone for the investigated system. Focused fluid flow occurs through the narrow fracture networks and the gas reaches the seafloor within 1 day. The surrounding regions near the fracture network exhibit slower seepage towards the seafloor, but over a wider area. Advective flux through the less fractured surrounding regions, reaches the seafloor within 15 years and a diffusive flux reaches within 1200 years. These times are controlled by the permeability of the sediments and are retarded further due to considerable hydrate/carbonate formation during vertical migration. Next course of action includes constraining the methane availability at the base of the GHSZ and estimating its impact on seepage behavior.</p>


Geosciences ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 188 ◽  
Author(s):  
Evgeny Chuvilin ◽  
Valentina Ekimova ◽  
Boris Bukhanov ◽  
Sergey Grebenkin ◽  
Natalia Shakhova ◽  
...  

Destabilization of intrapermafrost gas hydrate is one possible reason for methane emission on the Arctic shelf. The formation of these intrapermafrost gas hydrates could occur almost simultaneously with the permafrost sediments due to the occurrence of a hydrate stability zone after sea regression and the subsequent deep cooling and freezing of sediments. The top of the gas hydrate stability zone could exist not only at depths of 200–250 m, but also higher due to local pressure increase in gas-saturated horizons during freezing. Formed at a shallow depth, intrapermafrost gas hydrates could later be preserved and transform into a metastable (relict) state. Under the conditions of submarine permafrost degradation, exactly relict hydrates located above the modern gas hydrate stability zone will, first of all, be involved in the decomposition process caused by negative temperature rising, permafrost thawing, and sediment salinity increasing. That’s why special experiments were conducted on the interaction of frozen sandy sediments containing relict methane hydrates with salt solutions of different concentrations at negative temperatures to assess the conditions of intrapermafrost gas hydrates dissociation. Experiments showed that the migration of salts into frozen hydrate-containing sediments activates the decomposition of pore gas hydrates and increase the methane emission. These results allowed for an understanding of the mechanism of massive methane release from bottom sediments of the East Siberian Arctic shelf.


Geosciences ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 484
Author(s):  
Anatoly Gavrilov ◽  
Valentina Malakhova ◽  
Elena Pizhankova ◽  
Alexandra Popova

By using thermal mathematical modeling for the time range of 200,000 years ago, the authors have been studying the role the glaciation, covered the De Long Islands and partly the Anjou Islands at the end of Middle Neopleistocene, played in the formation of permafrost and gas hydrates stability zone. For the modeling purpose, we used actual geological borehole cross-sections from the New Siberia Island. The modeling was conducted at geothermal flux densities of 50, 60, and 75 mW/m2 for glacial and extraglacial conditions. Based on the modeling results, the glaciated area is characterized by permafrost thickness of 150–200 m lower than under extraglacial conditions. The lower boundary of the gas hydrate stability zone in the glacial area at 50–60 mW/m2 is located 300 m higher than the same under extraglacial conditions. At 75 mW/m2 in the area of 20–40 m isobaths, open taliks are formed, and the gas hydrate stability zone was destroyed in the middle of the Holocene. The specified conditions and events were being formed in the course of the historical development of the glacial area with a predominance of the marine conditions peculiar to it from the middle of the Middle Neopleistocene.


Energies ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 3403 ◽  
Author(s):  
Burwicz ◽  
Rüpke

Marine sediments of the Blake Ridge province exhibit clearly defined geophysical indications for the presence of gas hydrates and a free gas phase. Despite being one of the world’s best-studied gas hydrate provinces and having been drilled during Ocean Drilling Program (ODP) Leg 164, discrepancies between previous model predictions and reported chemical profiles as well as hydrate concentrations result in uncertainty regarding methane sources and a possible co-existence between hydrates and free gas near the base of the gas hydrate stability zone (GHSZ). Here, by using a new multi-phase finite element (FE) numerical model, we investigate different scenarios of gas hydrate formation from both single and mixed methane sources (in-situ biogenic formation and a deep methane flux). Moreover, we explore the evolution of the GHSZ base for the past 10 Myr using reconstructed sedimentation rates and non-steady-state P-T solutions. We conclude that (1) the present-day base of the GHSZ predicted by our model is located at the depth of ~450 mbsf, thereby resolving a previously reported inconsistency between the location of the BSR at ODP Site 997 and the theoretical base of the GHSZ in the Blake Ridge region, (2) a single in-situ methane source results in a good fit between the simulated and measured geochemical profiles including the anaerobic oxidation of methane (AOM) zone, and (3) previously suggested 4 vol.%–7 vol.% gas hydrate concentrations would require a deep methane flux of ~170 mM (corresponds to the mass of methane flux of 1.6 × 10−11 kg s−1 m−2) in addition to methane generated in-situ by organic carbon (POC) degradation at the cost of deteriorating the fit between observed and modelled geochemical profiles.


2020 ◽  
Vol 38 (4) ◽  
pp. 1188-1200
Author(s):  
Jiapeng Jin ◽  
Xiujuan Wang ◽  
Min He ◽  
Jie Li ◽  
Chengzhi Yan ◽  
...  

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