The De Long Trough: defining the mineralogical signature of the East Siberian Ice Sheet

The Arctic's glacial history has classically been interpreted from marine records in terms of the fluctuations of the Eurasian and North American ice sheets. However, the existence, size, and timing of the East Siberian Ice Sheet (ESIS) remains highly uncertain. A recently discovered glacially scoured cross-shelf trough extending to the edge of the continental shelf north of the De Long Islands has provided additional evidence that glacial ice existed on parts of the East Siberian Sea (ESS) during previous glacial periods (MIS 6 and 4). This study concentrates on defining the mineralogical signature and dynamics of the ESIS. Sediment materials from the East Siberian shelf and slope were collected during the 2014 SWERUS-C3 expedition. The cores studied are 20-GC1 from the East Siberian shelf, 23-GC1 and 24-GC1 from the De Long Trough (DLT), and 29-GC1 from the southern Lomonosov Ridge (LR). Heavy mineral assemblages were used to identify prominent parent rocks in hinterland and other sediment source areas. The parent rocks areas include major eastern Siberian geological provinces such as the Omolon massif, the Chukotka Fold Belt, the Verkhoyansk Fold Belt, and possibly the Okhotsk–Chukotka Volcanic Belt. The primary riverine sources for the ESS sediments are the Indigirka and Kolyma rivers, which material then was glacially eroded and re-deposited in the DLT. The higher abundances of hornblendes in the heavy mineral assemblages may indicate ESS paleovalley of the Indigirka river as a major pathway of sediments, while the Kolyma river paleovalley pathway relates to a higher share of pyroxenes and epidote. Mineralogical signature in the DLT diamicts, consisting predominantly of amphiboles and pyroxenes with minor content of garnet and epidote, show clear delivery from the eastern sector of the ESIS. Although the physical properties of the DLT basal diamict closely resemble a pervasive diamict unit recovered across the southern LR, their source material is slightly different according to their heavy mineral content. Assemblages with elevated amphibole and garnet content, along with higher titanite and ilmenite content from core 29-GC1 from the southern LR emphasise the Verkhoyansk Fold Belt as a possible source. This suggests that glacial ice not only grew out from the East Siberian shelf, but also from the New Siberian Islands and westerly sources due to the dynamics in the ice flow and deposition. An increase in the iron oxides in the sediments overlying the diamicts relates to the deglaciation cycle of the ESIS when the central plateau, or at least the shoreline and river discharge region, were possibly free from ice, and the reworking as well as enrichment of iron oxides was possible. This indicates sea-ice rather than iceberg transport for the present distal shelf sediments.

Occurrence of Volatile and Semi-Volatile Organic Pollutants in the Russian Arctic Atmosphere: The International Siberian Shelf Study Expedition (ISSS-2020)

Environmental issues in the Arctic region are of primary importance due to the fragility of the Arctic ecosystem. Mainly persistent organic compounds are monitored in the region by nine stationary laboratories. Information on the volatile (VOC) and semi volatile (SVOC) organic priority pollutants is very limited, especially for the Russian Arctic. Air samples from 16 sites along the Russian Arctic coast from the White Sea to the East Siberian Sea were collected on sorption tubes packed with Tenax, Carbograph, and Carboxen sorbents with different selectivity for a wide range of VOCs and SVOCs in 2020 within the framework of the International Siberian Shelf Study Expedition on the research vessel Akademik Keldysh. Thermal desorption gas chromatography–high-resolution mass spectrometry with Orbitrap was used for the analysis. Eighty-six VOCs and SVOCs were detected in the air samples at ng/m3 levels. The number of quantified compounds varied from 26 to 66 per sample. Benzoic acid was the major constituent, followed by BTEX, phenol, chloroform, bis(2-ethylhexyl) phthalate, and carbon tetrachloride. The study allowed for obtaining the first ever data on the presence of 138 priority pollutants in the air of Russian Arctic, whereas the thorough assessment of their possible sources will be the aim of a next investigation.

CDOM Optical Properties and DOC Content in the Largest Mixing Zones of the Siberian Shelf Seas

Notable changes in the Arctic ecosystem driven by increased atmospheric temperature and ice cover reduction were observed in the last decades. Ongoing environmental shifts affect freshwater discharge to the Arctic Ocean, and alter Arctic land-ocean fluxes. The monitoring of DOC distribution and CDOM optical properties is of great interest both from the point of view of validation of remote sensing models, and for studying organic carbon transformation and dynamics. In this study we report the DOC concentrations and CDOM optical characteristics in the mixing zones of the Ob, Yenisei, Khatanga, Lena, Kolyma, and Indigirka rivers. Water sampling was performed in August–October 2015 and 2017. The DOC was determined by high-temperature combustion, and absorption coefficients and spectroscopic indices were calculated using the seawater absorbance obtained with spectrophotometric measurements. Kara and Laptev mixing zones were characterized by conservative DOC behavior, while the East Siberian sea waters showed nonconservative DOC distribution. Dominant DOM sources are discussed. The absorption coefficient aCDOM (350) in the East Siberian Sea was two-fold lower compared to Kara and Laptev seawaters. For the first time we report the DOC content in the Khatanga River of 802.6 µM based on the DOC in the Khatanga estuary.

Permafrost and Gas Hydrate Stability Zone of the Glacial Part of the East-Siberian Shelf

By using thermal mathematical modeling for the time range of 200,000 years ago, the authors have been studying the role the glaciation, covered the De Long Islands and partly the Anjou Islands at the end of Middle Neopleistocene, played in the formation of permafrost and gas hydrates stability zone. For the modeling purpose, we used actual geological borehole cross-sections from the New Siberia Island. The modeling was conducted at geothermal flux densities of 50, 60, and 75 mW/m2 for glacial and extraglacial conditions. Based on the modeling results, the glaciated area is characterized by permafrost thickness of 150–200 m lower than under extraglacial conditions. The lower boundary of the gas hydrate stability zone in the glacial area at 50–60 mW/m2 is located 300 m higher than the same under extraglacial conditions. At 75 mW/m2 in the area of 20–40 m isobaths, open taliks are formed, and the gas hydrate stability zone was destroyed in the middle of the Holocene. The specified conditions and events were being formed in the course of the historical development of the glacial area with a predominance of the marine conditions peculiar to it from the middle of the Middle Neopleistocene.

Fauna associated with shallow-water methane seeps in the Laptev Sea

Background Methane seeps support unique benthic ecosystems in the deep sea existing due to chemosynthetic organic matter. In contrast, in shallow waters there is little or no effect of methane seeps on macrofauna. In the present study we focused on the recently described methane discharge area at the northern Laptev Sea shelf. The aim of this work was to describe the shallow-water methane seep macrofauna and to understand whether there are differences in macrobenthic community structure between the methane seep and background areas. Methods Samples of macrofauna were taken during three expeditions of RV Akademik Mstislav Keldysh in 2015, 2017 and 2018 using 0.1 m2 grabs and the Sigsbee trawl. 21 grabs and two trawls in total were taken at two methane seep sites named Oden and C15, located at depths of 60–70 m. For control, three 0.1 m2 grabs were taken in area without methane seepage. Results The abundance of macrofauna was higher at methane seep stations compared to non-seep sites. Cluster analysis revealed five station groups corresponding to control area, Oden site and C15 site (the latter represented by three groups). Taxa responsible for differences among the station groups were mostly widespread Arctic species that were more abundant in samples from methane seep sites. However, high densities of symbiotrophic siboglinids Oligobrachia sp. were found exclusively at methane seep stations. In addition, several species possibly new to science were found at several methane seep stations, including the gastropod Frigidalvania sp. and the polychaete Ophryotrocha sp. The fauna at control stations was represented only by well-known and widespread Arctic taxa. Higher habitat heterogeneity of the C15 site compared to Oden was indicated by the higher number of station groups revealed by cluster analysis and higher species richness in C15 trawl sample. The development of the described communities at the shallow-water methane seeps can be related to pronounced oligotrophic environment on the northern Siberian shelf.