scholarly journals A crystalline supramolecular polymer with self-healing capability at room temperature

2013 ◽  
Vol 45 (9) ◽  
pp. 955-961 ◽  
Author(s):  
Nobuhiro Oya ◽  
Tabito Ikezaki ◽  
Naoko Yoshie
Keyword(s):  
Room Temperature ◽  
Supramolecular Polymer ◽  
Self Healing

scholarly journals Tough Supramolecular Polymer Networks with Extreme Stretchability and Fast Room-Temperature Self-Healing

2017 ◽  
Vol 29 (22) ◽  
pp. 1605325 ◽  
Author(s):  
Ji Liu ◽  
Cindy Soo Yun Tan ◽  
Ziyi Yu ◽  
Nan Li ◽  
Chris Abell ◽  
...  
Keyword(s):  
Room Temperature ◽  
Polymer Networks ◽  
Supramolecular Polymer ◽  
Self Healing

Autonomous self-healing polyisoprene elastomers with high modulus and good toughness based on the synergy of dynamic ionic crosslinks and highly disordered crystals

2020 ◽  
Vol 11 (41) ◽  
pp. 6549-6558
Author(s):  
Yohei Miwa ◽  
Mayu Yamada ◽  
Yu Shinke ◽  
Shoichi Kutsumizu
Keyword(s):  
Mechanical Properties ◽  
Room Temperature ◽  
Self Healing ◽  
High Modulus ◽  
Disordered Crystals ◽  
Ionic Crosslinks

We designed a novel polyisoprene elastomer with high mechanical properties and autonomous self-healing capability at room temperature facilitated by the coexistence of dynamic ionic crosslinks and crystalline components that slowly reassembled.

scholarly journals Research on Thermal Stability and Properties of Ca3ZrSi2O9 as Potential T/EBC Materials

Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 583
Author(s):  
Yangyang Pan ◽  
Bo Liang ◽  
Yaran Niu ◽  
Dijuan Han ◽  
Dongdong Liu ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Thermal Stability ◽  
Fracture Toughness ◽  
Room Temperature ◽  
Coefficient Of Thermal Expansion ◽  
Atmospheric Plasma ◽  
Thermal Barrier ◽  
Mechanical And Thermal Properties ◽  
Self Healing ◽  
Barrier Coating

In this study, a new coating material for thermal barrier coating (TBC) or environment barrier coating (EBC) application, Ca3ZrSi2O9 (CZSO), was synthesized and prepared by atmospheric plasma spray (APS) technology. The evolution of the phases and microstructures of the coatings with different thermal-aged were characterized by XRD, XRF, EDS and SEM, respectively. The thermal stability was measured by TG-DTA and DSC. The mechanical and thermal properties, including Vickers hardness (HV), fracture toughness (KIC), thermal conductivity () and coefficient of thermal expansion (CTE) were focused on. It was found that the as-sprayed CZSO coating contained amorphous phase. Crystalline transformation happened at 900–960 ∘C and no mass changes took place from room temperature (RT) to 1300 ∘C. The phenomena of microcrack self-healing and composition uniformity were observed during thermal aging. The of coating was very low at about 0.57–0.80 Wm−1K−1 in 200–1200 ∘C. The combined properties indicated that the CZSO coating might be a potential T/EBC material.

Stretchable dual cross-linked silicon elastomer with superhydrophobic surface and fast triple self-healing ability at room temperature

Soft Matter ◽  
2021 ◽  
Author(s):  
Yuxing Shan ◽  
shuai liang ◽  
Xiangkai Mao ◽  
Jie Lu ◽  
Lili Liu ◽  
...  
Keyword(s):  
Superhydrophobic Surface ◽  
Room Temperature ◽  
Superhydrophobic Surfaces ◽  
Self Healing ◽  
Wearable Electronics ◽  
Actual Application ◽  
Potential Applications

Abstract. Stretchable elastomers with superhydrophobic surfaces have potential applications in wearable electronics. However, various types of damage inevitably occur on these elastomers in actual application, resulting in deterioration of the...

scholarly journals Recyclable Self-Healing Polyurethane Cross-Linked by Alkyl Diselenide with Enhanced Mechanical Properties

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 773 ◽  
Author(s):  
Yuqing Qian ◽  
Xiaowei An ◽  
Xiaofei Huang ◽  
Xiangqiang Pan ◽  
Jian Zhu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Room Temperature ◽  
Amide Bond ◽  
Self Healing ◽  
Healing Efficiency ◽  
Polyurethane Networks ◽  
Combined Action ◽  
Cross Linker ◽  
Dynamic Structures ◽  
External Interventions

Dynamic structures containing polymers can behave as thermosets at room temperature while maintaining good mechanical properties, showing good reprocessability, repairability, and recyclability. In this work, alkyl diselenide is effectively used as a dynamic cross-linker for the design of self-healing poly(urea–urethane) elastomers, which show quantitative healing efficiency at room temperature, without the need for any catalysts or external interventions. Due to the combined action of the urea bond and amide bond, the material has better mechanical properties. We also compared the self-healing effect of alkyl diselenide-based polyurethanes and alkyl disulfide-based polyurethanes. The alkyl diselenide has been incorporated into polyurethane networks using a para-substituted amine diphenyl alkyl diselenide. The resulting materials not only exhibit faster self-healing properties than the corresponding disulfide-based materials, but also show the ability to be processed at temperatures as low as 60 °C.

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