scholarly journals Three body photodissociation of the water molecule and its implications for prebiotic oxygen production

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yao Chang ◽  
Yong Yu ◽  
Feng An ◽  
Zijie Luo ◽  
Donghui Quan ◽  
...  

AbstractThe provenance of oxygen on the Earth and other planets in the Solar System is a fundamental issue. It has been widely accepted that the only prebiotic pathway to produce oxygen in the Earth’s primitive atmosphere was via vacuum ultraviolet (VUV) photodissociation of CO2 and subsequent two O atom recombination. Here, we provide experimental evidence of three-body dissociation (TBD) of H2O to produce O atoms in both 1D and 3P states upon VUV excitation using a tunable VUV free electron laser. Experimental results show that the TBD is the dominant pathway in the VUV H2O photochemistry at wavelengths between 90 and 107.4 nm. The relative abundance of water in the interstellar space with its exposure to the intense VUV radiation suggests that the TBD of H2O and subsequent O atom recombination should be an important prebiotic O2-production, which may need to be incorporated into interstellar photochemical models.

2021 ◽  
Author(s):  
Yao Chang ◽  
Yong Yu ◽  
Feng An ◽  
Zijie Luo ◽  
Donghui Quan ◽  
...  

Abstract The provenance of oxygen on the Earth and other Solar planetary bodies is a fundamental issue. It has been widely accepted that the only prebiotic pathway to produce oxygen in the Earth’s primitive atmosphere was via vacuum ultraviolet (VUV) photodissociation of CO2 and subsequent two O atom recombination. Here, we provide experimental evidence of three-body dissociation (TBD) of H2O to produce O atoms in both 1D and 3P states upon vacuum ultraviolet (VUV) excitation using the newly developed tunable VUV free electron laser. Experimental results show that the TBD is the dominant pathway in the VUV H2O photochemistry at wavelengths between 90 and 107.4 nm. The relative abundance of water in the interstellar space with its exposure to intense VUV radiation suggests that the TBD of H2O and subsequent O atoms recombination should be an important prebiotic O2-production, which may need to be incorporated into interstellar photochemical models.


1972 ◽  
Vol 45 ◽  
pp. 329-334 ◽  
Author(s):  
V. S. Safronov

The theory of planetary accumulation leads quite definitely to the conclusion that the formation of Oort's cometary cloud is the result of ejection of bodies to the outermost parts of the solar system due to encounters with the giant planets during their growth. Uranus and Neptune could have grown to their present dimensions only if the initial mass of solid material in their zones were substantially larger than that of these planets. The relative velocities of the bodies were increased through perturbations by the planetary embryos, and on reaching the escape velocity they would start to be ejected. Our concept of this process differs from that suggested by Öpik by the assumption that Jupiter and Saturn accreted hydrogen, not in solid but in gaseous state, and by the introduction of a more effective mechanism for the interaction with several embryos. In their final stages the embryos ejected amounts of mass an order of magnitude higher than the amounts accreted. Most of the mass was ejected into interstellar space by Jupiter, but the cometary cloud was created mainly by Neptune. The mass of the cloud is estimated to be about three times that of the Earth.


2011 ◽  
Vol 20 (01) ◽  
pp. 17-22 ◽  
Author(s):  
I. B. KHRIPLOVICH

We consider the capture of galactic dark matter by the solar system, due to the gravitational three-body interaction of the Sun, a planet, and a dark matter particle. Simple estimates are presented for the capture cross-section, as well as for the density and velocity distributions of captured dark matter particles close to the Earth.


2017 ◽  
Vol 14 (09) ◽  
pp. 1750117 ◽  
Author(s):  
Emmanuele Battista ◽  
Giampiero Esposito ◽  
Luciano Di Fiore ◽  
Simone Dell’Agnello ◽  
Jules Simo ◽  
...  

Recent work in the literature has advocated using the Earth–Moon–planetoid Lagrangian points as observables, in order to test general relativity and effective field theories of gravity in the solar system. However, since the three-body problem of classical celestial mechanics is just an approximation of a much more complicated setting, where all celestial bodies in the solar system are subject to their mutual gravitational interactions, while solar radiation pressure and other sources of nongravitational perturbations also affect the dynamics, it is conceptually desirable to improve the current understanding of solar system dynamics in general relativity, as a first step towards a more accurate theoretical study of orbital motion in the weak-gravity regime. For this purpose, starting from the Einstein equations in the de Donder–Lanczos gauge, this paper arrives first at the Levi-Civita Lagrangian for the geodesic motion of planets, showing in detail under which conditions the effects of internal structure and finite extension get canceled in general relativity to first post-Newtonian order. The resulting nonlinear ordinary differential equations for the motion of planets and satellites are solved for the Earth’s orbit about the Sun, written down in detail for the Sun–Earth–Moon system, and investigated for the case of planar motion of a body immersed in the gravitational field produced by the other bodies (e.g. planets with their satellites). At this stage, we prove an exact property, according to which the fourth-order time derivative of the original system leads to a linear system of ordinary differential equations. This opens an interesting perspective on forthcoming research on planetary motions in general relativity within the solar system, although the resulting equations remain a challenge for numerical and qualitative studies. Last, the evaluation of quantum corrections to location of collinear and noncollinear Lagrangian points for the planar restricted three-body problem is revisited, and a new set of theoretical values of such corrections for the Earth–Moon–planetoid system is displayed and discussed. On the side of classical values, the general relativity corrections to Newtonian values for collinear and noncollinear Lagrangian points of the Sun–Earth–planetoid system are also obtained. A direction for future research will be the analysis of planetary motions within the relativistic celestial mechanics set up by Blanchet, Damour, Soffel and Xu.


1962 ◽  
Vol 14 ◽  
pp. 149-155 ◽  
Author(s):  
E. L. Ruskol

The difference between average densities of the Moon and Earth was interpreted in the preceding report by Professor H. Urey as indicating a difference in their chemical composition. Therefore, Urey assumes the Moon's formation to have taken place far away from the Earth, under conditions differing substantially from the conditions of Earth's formation. In such a case, the Earth should have captured the Moon. As is admitted by Professor Urey himself, such a capture is a very improbable event. In addition, an assumption that the “lunar” dimensions were representative of protoplanetary bodies in the entire solar system encounters great difficulties.


1962 ◽  
Vol 14 ◽  
pp. 133-148 ◽  
Author(s):  
Harold C. Urey

During the last 10 years, the writer has presented evidence indicating that the Moon was captured by the Earth and that the large collisions with its surface occurred within a surprisingly short period of time. These observations have been a continuous preoccupation during the past years and some explanation that seemed physically possible and reasonably probable has been sought.


2007 ◽  
Vol 72 (8) ◽  
pp. 1122-1138 ◽  
Author(s):  
Milan Uhlár ◽  
Ivan Černušák

The complex NO+·H2S, which is assumed to be an intermediate in acid rain formation, exhibits thermodynamic stability of ∆Hº300 = -76 kJ mol-1, or ∆Gº300 = -47 kJ mol-1. Its further transformation via H-transfer is associated with rather high barriers. One of the conceivable routes to lower the energy of the transition state is the action of additional solvent molecule(s) that can mediate proton transfer. We have studied several NO+·H2S structures with one or two additional water molecule(s) and have found stable structures (local minima), intermediates and saddle points for the three-body NO+·H2S·H2O and four-body NO+·H2S·(H2O)2 clusters. The hydrogen bonds network in the four-body cluster plays a crucial role in its conversion to thionitrous acid.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Sune G. Nielsen ◽  
David V. Bekaert ◽  
Maureen Auro

AbstractIsotopic measurements of lunar and terrestrial rocks have revealed that, unlike any other body in the solar system, the Moon is indistinguishable from the Earth for nearly every isotopic system. This observation, however, contradicts predictions by the standard model for the origin of the Moon, the canonical giant impact. Here we show that the vanadium isotopic composition of the Moon is offset from that of the bulk silicate Earth by 0.18 ± 0.04 parts per thousand towards the chondritic value. This offset most likely results from isotope fractionation on proto-Earth during the main stage of terrestrial core formation (pre-giant impact), followed by a canonical giant impact where ~80% of the Moon originates from the impactor of chondritic composition. Our data refute the possibility of post-giant impact equilibration between the Earth and Moon, and implies that the impactor and proto-Earth mainly accreted from a common isotopic reservoir in the inner solar system.


2021 ◽  
Vol 34 (1) ◽  
pp. 51-60
Author(s):  
Gang Li ◽  
Chong Wang ◽  
Hui-jun Zheng ◽  
Tian-tong Wang ◽  
Hua Xie ◽  
...  

2004 ◽  
Vol 12 (1) ◽  
pp. 111-119
Author(s):  
SIEGFRIED J. BAUER

Planet Earth is unique in our solar system as an abode of life. In contrast to its planetary neighbours, the presence of liquid water, a benign atmospheric environment, a solid surface and an internal structure providing a protective magnetic field make it a suitable habitat for man. While natural forces have shaped the Earth over millennia, man through his technological prowess may become a threat to this oasis of life in the solar system.


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