scholarly journals Potential mechanisms involving the immobilization of Cd, As and Cr during swine manure composting

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Hao-Nan Guo ◽  
Li-Xia Wang ◽  
Hong-Tao Liu

Abstract This study aims to investigate the relationship between key physicochemical parameters related to composting process and bioavailability of Cd, As and Cr during swine manure composting through regulating different initial carbon to nitrogen (C/N) ratios (15:1, 20:1, 25:1) and bulking agent types (straw, green waste). Results showed that higher initial C/N ratio of 20:1 or 25:1 and straw as bulking agent were optimal to reduce the bioavailability of Cd, As and Cr (62.4%, 20.6% and 32.2% reduction, respectively). Redundancy analysis implied that the bioavailability of Cd was significantly associated with total phosphorus and total nitrogen, deducing the formation of phosphate precipitation and biosorption might participated in the reaction process, while that of As and Cr were mainly influenced by organic matter (OM), cation exchange capacity (CEC) and OM, CEC, electric conductivity, respectively. A total of 48.5%, 64.6% and 62.2% of Cd, As and Cr redistribution information could be explained by the above parameters. Further correlation analysis revealed that bioavailable As and Cr were negatively correlated with humic acid to fulvic acid ratio. In summary, this study confirms that the mechanisms of phosphate precipitation, biosorption and humification played critical role in reducing Cd, As and Cr bioavailability during swine manure composting.

Author(s):  
Z. Abdulhamid ◽  
E.B. Agbaji ◽  
C.E. Gimba ◽  
A.S. Agbaji

Physico-chemical properties and heavy metals content of soils were determined from seven farms in Minna, central Nigeria. Conventional analytical methods were employed to determine the physico-chemical properties and the heavy metals were analysed by atomic absorption spectrometry. The result showed that pH values ranged from 6.64 - 7.70 indicating slight acidity to slight alkalinity of the soils. The total organic carbon values ranged from 0.95-2.25 % resulting in the presence of organic matter (1.63-3.87). The electrical conductivity values ranged from 17-37 μS/cm. The cation exchange capacity of the soil samples ranged from 3.68-5.15 cmol/kg. The heavy metals levels were in the following range: Cd (0.00018-0.00134 mg/g), Cu (0.0069-0.0476 mg/g), Fe (1.942-2.2059 mg/g), Mn (0.1825-0.3696 mg/g), Ni (0.0065-0.0069 mg/g) and Zn (0.0157-0.2252 mg/g). The concentration of the metals in the soil samples varied according to the following trend: Fe>Mn>Zn> Cu>Ni>Cd. The average concentration of all the metals in each farm also gave the trend Farm B>Farm G>Farm E>Farm C>Farm F>Farm D>Farm A. The findings indicate the presence of heavy metals in all the farms but only Fe was above the FAO/WHO standards.


1992 ◽  
Vol 119 (1) ◽  
pp. 79-82 ◽  
Author(s):  
E. P. Papanicolaou ◽  
C. G. Apostolakis ◽  
V. Skarlou ◽  
C. Nobeli ◽  
P. Kritidis

SummaryThe relationship between values of 85Sr concentration ratios (CRs) and exchangeable bases, expressed in absolute (mmol/kg) or relative (percentage of cation exchange capacity (CEC)) terms, was considered using the results of a glasshouse pot experiment conducted in 1989, for soils and crops of Greece. Exchangeable calcium, expressed in mmol/kg, presented, in most instances, a significant (P = 0·05–0·01) or highly significant (P < 0·01) negative correlation with the CRs of various crops or plant parts, while exchangeable calcium plus magnesium or total exchangeable bases (expressed also in mmol/kg) showed an even better correlation (higher values of r, lower variability). Expression of the amounts of exchangeable bases in relative terms further improved the correlation coefficient in each comparison. The correlations between the percentage of exchangeable (Ca + Mg) or exchangeable bases and CRs, which were always negative, were significant or highly significant for all tested crops or plant parts. The correlation between CRs and soil properties was greatest for exchangeable (Ca + Mg) expressed as a percentage of CEC (r = -0·92) and followed the order: Exchangeable (Ca + Mg) as % of CEC ≈ exchangeable bases as % of CEC ≈ exchangeable (Ca + Mg) in mmol/kg ≈ exchangeable bases in mmol/kg > exchangeable Ca as % of CEC > exchangeable Ca in mmol/kg.Quantitative relationships between CRs of the tested crops or plant parts and exchangeable calcium plus magnesium (% of CEC) of soils are also presented.


1962 ◽  
Vol 10 (3) ◽  
pp. 194-210
Author(s):  
P. Delver

Data on soil texture, lime, gypsum, cation-exchange capacity, salinity, alkalinity, hydraulic conductivity and their interrelations and variations are discussed. An equation expresses the relationship between exchangeable Na and cations soluble in 1: 1 extracts. Special attention is paid to whether alkalization and structure deterioration will occur during reclamation. Gypsum contents seem to be adequate for replacement of Na by Ca during leaching but temporary decrease in permeability in early stages of leaching may occur due to retarded exchange reactions caused by the nature of the clay minerals. (Abstract retrieved from CAB Abstracts by CABI’s permission)


2011 ◽  
Vol 255-260 ◽  
pp. 2766-2770 ◽  
Author(s):  
Amin Eisazadeh ◽  
Khairul Anuar Kassim ◽  
Hadi Nur

In this research, the time-dependent changes induced in charge characteristics of phosphoric acid and lime treated quartz-rich kaolinitic soil were investigated. Also, in order to study the relationship between the exchange capacity and the pore water chemistry, pH measurements was performed on cured samples. Based on the collected data, it was found that the pH of stabilized soils showed a tendency for reaching soil’s natural pH with increasing curing time. In addition, the increase in number of broken bonds around the edges of soil particles and also the formation of cementitious compounds that acquired negative charges contributed to achieving higher CECpvalues at longer curing periods. From engineering point of view, the lime treated samples revealed the highest degree of improvement with an approximately 16-fold strength increase in comparison to the natural soil over an 8 months curing period.


Geoderma ◽  
2010 ◽  
Vol 154 (3-4) ◽  
pp. 353-358 ◽  
Author(s):  
A. Savvides ◽  
R. Corstanje ◽  
S.J. Baxter ◽  
B.G. Rawlins ◽  
R.M. Lark

2018 ◽  
Vol 4 (1) ◽  
Author(s):  
Mardi Wibowo

Since year 1977 until 2005, PT. ANTAM has been exploited nickel ore resources at Gebe Island – Center ofHalmahera District – North Maluku Province. Mining activity, beside give economically advantages also causedegradation of environment quality espicially land quality. Therefore, it need evaluation activity for change ofland quality at Gebe Island after mining activity.From chemical rehabilitation aspect, post mining land and rehabilitation land indacate very lack and lackfertility (base saturated 45,87 – 99,6%; cation exchange capacity 9,43 – 12,43%; Organic Carbon 1,12 –2,31%). From availability of nutrirnt element aspect, post mining land and rehabilitation land indicate verylack and lack fertility (nitrogen 0,1 – 1,19%). Base on that data, it can be concluded that land reclamationactivity not yet achieve standart condition of chemical land.Key words : land quality, post mining lan


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