scholarly journals Estimation and correction of instrument artefacts in dynamic impedance spectra

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Collins Erinmwingbovo ◽  
Fabio La Mantia

AbstractDynamic impedance spectroscopy is one of the most powerful techniques in the qualitative and quantitative mechanistic studies of electrochemical systems, as it allows for time-resolved investigation and dissection of various physicochemical processes occurring at different time scales. However, due to high-frequency artefacts connected to the non-ideal behaviour of the instrumental setup, dynamic impedance spectra can lead to wrong interpretation and/or extraction of wrong kinetic parameters. These artefacts arise from the non-ideal behaviour of the voltage and current amplifier (I/E converters) and stray capacitance. In this paper, a method for the estimation and correction of high-frequency artefacts arising from non-ideal behaviour of instrumental setup will be discussed. Using resistors, $$[\hbox {Fe(CN)}_6]^{3-/4-}$$ [ Fe(CN) 6 ] 3 - / 4 - redox couple and nickel hexacyanoferrate nanoparticles, the effect of high-frequency artefacts will be investigated and the extraction of the impedance of the system from the measured dynamic impedance is proposed. It is shown that the correction allows acquiring proper dynamic impedance spectra at frequencies higher than the bandwidth of the potentiostat, and simultaneously acquire high precision cyclic voltammetry.

2019 ◽  
Vol 139 (3) ◽  
pp. 339-347 ◽  
Author(s):  
Shotaro Takahashi ◽  
Satoshi Ogasawara ◽  
Masatsugu Takemoto ◽  
Koji Orikawa ◽  
Michio Tamate

2021 ◽  
Vol 129 (21) ◽  
pp. 215305
Author(s):  
Wei Zhao ◽  
Baptiste Bérenguier ◽  
Cendra Rakotoarimanana ◽  
Anne-Marie Gonçalves ◽  
Arnaud Etcheberry ◽  
...  

2015 ◽  
Vol 55 (1) ◽  
pp. 016101 ◽  
Author(s):  
Anil Pandey ◽  
Wataru Sakakibara ◽  
Hiroyuki Matsuoka ◽  
Keiji Nakamura ◽  
Hideo Sugai

2006 ◽  
Vol 19 (6) ◽  
pp. 667-670 ◽  
Author(s):  
A Lucarelli ◽  
G Lüpke ◽  
T J Haugan ◽  
G A Levin ◽  
P N Barnes

2019 ◽  
Vol 669 ◽  
pp. 520-524
Author(s):  
Baptiste Bérenguier ◽  
Nicolas Barreau ◽  
Alexandre Jaffre ◽  
Daniel Ory ◽  
Jean-François Guillemoles ◽  
...  

2020 ◽  
Author(s):  
Vasily Matkivsky ◽  
Alexander Moiseev ◽  
Pavel Shilyagin ◽  
Alexander Rodionov ◽  
Hendrik Spahr ◽  
...  

A method for numerical estimation and correction of aberrations of the eye in fundus imaging with optical coherence tomography (OCT) is presented. Aberrations are determined statistically by using the estimate based on likelihood function maximization. The method can be considered as an extension of the phase gradient autofocusing algorithm in synthetic aperture radar imaging to 2D optical aberrations correction. The efficiency of the proposed method has been demonstrated in OCT fundus imaging with 6λ aberrations. After correction, single photoreceptors were resolved. It is also shown that wavefront distortions with high spatial frequencies can be determined and corrected.Graphical Abstract for Table of Contents[Text. This work is dedicated to development a method for numerical estimation and correction of aberrations of the eye in fundus imaging with OCT. Aberration evaluation is performed statistically by using estimate based on likelihood function maximization. The efficiency of the proposed method has been demonstrated in OCT fundus imaging with 6λ aberrations. It has been shown that spatial high-frequency wavefront distortions can be determined]


2001 ◽  
Vol 89 (11) ◽  
pp. 7702-7704 ◽  
Author(s):  
C. M. Fu ◽  
C. J. Lai ◽  
J. S. Wu ◽  
J. C. A. Huang ◽  
C.-C. Wu ◽  
...  

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