The solid-state reaction of a functionalised polypyrrole; analysis using high resolution X-ray photoelectron spectroscopy

2004 ◽  
Vol 6 (9) ◽  
pp. 2403 ◽  
Author(s):  
J. M. Cooper ◽  
A. Glidle ◽  
A. R. Hillman ◽  
M. D. Ingram ◽  
C. Ryder ◽  
...  
Keyword(s):  
Solid State ◽  
High Resolution ◽  
Solid State Reaction ◽  
Photoelectron Spectroscopy ◽  
X Ray

Study of Thermal Oxide Solid-State Reaction on GaAs Surfaces

1991 ◽  
Vol 238 ◽  
Author(s):  
Z. Lu ◽  
D. Chen ◽  
R. M. Osgood ◽  
D. V. Podlesnik
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Photoelectron Spectroscopy ◽  
Interface Reaction ◽  
Decomposition Reaction ◽  
Thermal Reaction ◽  
Native Oxide ◽  
X Ray ◽  
Temperature Range ◽  
Thermal Oxide

ABSTRACTIn this paper, we will present a study of the thermal reaction of AsjOs with GaAs at temperatures below 550°C using monochromatic X-ray photoelectron spectroscopy (MXPS). A solid-state interface reaction of 4GaAs + 3AS2O5 → 2Ga2O3 + 3AS2O3 + 4As, which includes the usual native oxide thermal reaction: 2GaAs + AS2O3 → Ga2O3 + 4As, as well as a decomposition reaction AS2O5 → AS2O3 + O2 is responsible for the thermal reaction in this temperature range.

Decaphenylferrocene

1995 ◽  
Vol 48 (4) ◽  
pp. 851 ◽  
Author(s):  
LD Field ◽  
TW Hambley ◽  
PA Humphrey ◽  
CM Lindall ◽  
GJ Gainsford ◽  
...  
Keyword(s):  
Solid State ◽  
High Resolution ◽  
Vibrational Spectroscopy ◽  
Powder Diffraction ◽  
Photoelectron Spectroscopy ◽  
Mossbauer Spectroscopy ◽  
57Fe Mössbauer Spectroscopy ◽  
X Ray ◽  
57Fe Mössbauer ◽  
57Fe Mossbauer Spectroscopy

Decaphenylferrocene was obtained as an extremely insoluble, maroon microcrystalline solid by heating [(η5-C5Ph5)((η6-C6H5)C5Ph4)Fe], and was characterized by 57Fe Mossbauer spectroscopy, X-ray photoelectron spectroscopy, mass, electronic and vibrational spectroscopy, solid-state 13C n.m.r. spectroscopy and high-resolution X-ray powder diffraction, which showed it to be isostructural with decaphenylnickelocene.

Facile Fabrication of Nanosized Nickel Powder via Solid-State Reaction at Low Heat and its Catalytic Performance

2011 ◽  
Vol 393-395 ◽  
pp. 1235-1241
Author(s):  
Liu Hong ◽  
Wu Bin ◽  
Feng Cheng Tao ◽  
Qin Xia
Keyword(s):  
Catalytic Activity ◽  
Solid State ◽  
Solid State Reaction ◽  
Photoelectron Spectroscopy ◽  
Catalytic Performance ◽  
X Ray ◽  
Nickel Powders ◽  
Transmission Electron ◽  
Raney Ni ◽  
Facile Fabrication

Nano-Nickel (Ni0) powders have been successfully prepared via the reduction of nanosized NiO powders by the solid state reaction. And the nanosized NiO powders were derived from low temperature (350°C) calcinations in muffle in air of nanosized Ni(OH)2 powders firstly prepared by the room temperature solid state reaction between NiSO4•6H2O and NaOH by H2 at 400°C for 4 h. The crystallinity, microstructure of surface and xps property of obtained nickel powders were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). Furthermore, the catalytic activity of the obtained nanosized Ni powders for hydrogenation of nitrobenzene to aniline was investigated. The results show that the spherical Ni parepared in particle sizes ranges from 20 to 25 nm and achieves enhanced catalytic activity for hydrogenation of nitrobenzene to aniline compared with Raney Ni.

Surface composition of the phases formed by solid state reaction at the interface studied by low energy ion scattering and X-ray photoelectron spectroscopy

1998 ◽  
Vol 412-413 ◽  
pp. 631-638 ◽  
Author(s):  
Irene Spolveri ◽  
Andrea Atrei ◽  
Brunetto Cortigiani ◽  
Ugo Bardi ◽  
Alessandro Santucci ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Photoelectron Spectroscopy ◽  
Surface Composition ◽  
Low Energy ◽  
Ion Scattering ◽  
X Ray ◽  
Low Energy Ion Scattering

Correlation between structure, surface defect chemistry and O18/O16 exchange for La2Mo2O9 and La2(MoO4)3

2021 ◽  
Author(s):  
Natalia M. Porotnikova ◽  
Maxim I. Vlasov ◽  
Yuri Zhukov ◽  
Christian Kirschfeld ◽  
Anna Khodimchuk ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Solid State ◽  
Solid State Reaction ◽  
Photoelectron Spectroscopy ◽  
Surface Defect ◽  
Solid State Reaction Method ◽  
Defect Chemistry ◽  
Reaction Method ◽  
X Ray ◽  
Structure Surface

The La2Mo2O9 and La2(MoO4)3 powders were synthesized by the solid-state reaction method and were used to prepare dense ceramics. X-ray photoelectron spectroscopy was used to study the chemical composition and...

scholarly journals Formation of CoAl2O4Nanoparticles via Low-Temperature Solid-State Reaction of Fine Gibbsite and Cobalt Precursor

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
Natpakan Srisawad ◽  
Wasu Chaitree ◽  
Okorn Mekasuwandumrong ◽  
Piyasan Praserthdam ◽  
Joongjai Panpranot
Keyword(s):  
Electron Microscopy ◽  
Solid State ◽  
Solid State Reaction ◽  
Photoelectron Spectroscopy ◽  
Cobalt Chloride ◽  
Solid State Reaction Method ◽  
Uv Spectra ◽  
Visible Absorption ◽  
X Ray ◽  
Chloride Hexahydrate

Nanocrystalline cobalt aluminate (CoAl2O4) was synthesized by the solid-state reaction method with cobalt chloride hexahydrate (CoCl2 · 6H2O) as the source of Co and gibbsite (Al(OH)3) as the source of Al, respectively. The effects of particle size of the starting fine gibbsite (0.6 and 13 μm) and calcination temperatures (450, 550, and 650°C) on the properties of CoAl2O4were investigated by means of X-ray diffraction (XRD), thermogravimetry analysis and differential thermal analysis (TG/DTA), X-ray photoelectron spectroscopy (XPS), UV-visible absorption spectroscopy (UV-Vis), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Increasing of calcination temperature promoted the insertion amounts of Co2+in alumina matrix in CoAl2O4structure, which resulted in the brighter blue particles and increasing of UV spectra band. The lowest temperature for the formation of nanocrystalline CoAl2O4particles was 550°C for the solid-state reaction of cobalt chloride and 0.6 μm fine gibbsite.

scholarly journals PEAXIS: A RIXS and XPS Endstation for Solid-State Quantum and Energy Materials at BESSY II

2021 ◽  
Vol 7 ◽  
Author(s):  
Deniz Po Wong ◽  
Christian Schulz ◽  
Maciej Bartkowiak
Keyword(s):  
Electronic Structure ◽  
Solid State ◽  
High Resolution ◽  
Photoelectron Spectroscopy ◽  
Collective Excitations ◽  
Spectroscopic Techniques ◽  
Energy Materials ◽  
X Ray ◽  
X Ray Scattering ◽  
Sample Environment

PEAXIS (Photo Electron Analysis and resonant X-ray Inelastic Spectroscopy) is a dedicated endstation installed at the beamline U41-PEAXIS that offers high resolution soft X-ray spectroscopy measurements with incident photon energies ranging from 180 – 1600 eV. The endstation combines two X-ray spectroscopic techniques, X-ray photoelectron spectroscopy (XPS) and resonant inelastic soft X-ray scattering (RIXS), which are important for probing the electronic structure and local and collective excitations of solid-state materials. It features a continuous variation of scattering angle under UHV conditions for wave vector-resolved studies and a modular sample environment that allows investigation in the temperature range between 10 K and 1000 K.

X-ray Structure Refinement and Vibrational Spectroscopy of Ca8Gd2 (PO4)6 O2

2013 ◽  
Vol 12 (10) ◽  
pp. 719-726
Author(s):  
R. Ayadi ◽  
Mohamed Boujelbene ◽  
T. Mhiri
Keyword(s):  
Solid State ◽  
General Formula ◽  
Vibrational Spectroscopy ◽  
Powder Diffraction ◽  
Infrared Spectra ◽  
Solid State Reaction ◽  
Structure Refinement ◽  
Unit Cell ◽  
Cell Group ◽  
X Ray

The present paper is interested in the study of compounds from the apatite family with the general formula Ca10 (PO4)6A2. It particularly brings to light the exploitation of the distinctive stereochemistries of two Ca positions in apatite. In fact, Gd-Bearing oxyapatiteCa8 Gd2 (PO4)6O2 has been synthesized by solid state reaction and characterized by X-ray powder diffraction. The site occupancies of substituents is0.3333 in Gd and 0.3333 for Ca in the Ca(1) position and 0. 5 for Gd in the Ca (2) position.  Besides, the observed frequencies in the Raman and infrared spectra were explained and discussed on the basis of unit-cell group analyses.

Sign in / Sign up

Export Citation Format

Share Document