Water-based colourimetric optical indicators for the detection of carbon dioxide

The Analyst ◽  
2010 ◽  
Vol 135 (8) ◽  
pp. 1912 ◽  
Author(s):  
Andrew Mills ◽  
Graham A. Skinner
2012 ◽  
Vol 91 (12) ◽  
pp. 3057-3064 ◽  
Author(s):  
M.P. Caputo ◽  
E.R. Benson ◽  
E.M. Pritchett ◽  
D.P. Hougentogler ◽  
P. Jain ◽  
...  

Author(s):  
Douglas J. MacLean ◽  
Kim F. Hayes ◽  
Thomas Barnard ◽  
Timothy Hull ◽  
Ye Eun Park ◽  
...  

This paper investigates the influence of supercritical carbon dioxide (scCO2) metalworking fluids on tool wear in two automotive manufacturing processes. scCO2 is a low-cost minimum quantity lubrication (MQL) system with excellent cooling characteristics. In valve seat machining of sintered steel with cubic boron nitride (CBN) inserts, scCO2 reduced tool wear by up to 25% and cutting forces by 10% when compared with the benchmark water-based flood metalworking fluid currently used in production operations. In end milling of compacted graphite iron (CGI) with uncoated carbide inserts, scCO2 reduced tool wear by up to 50% when compared with the currently used metalworking fluid. These results are consistent with those from other applications that show scCO2-based metalworking fluids have the potential to reduce tool wear and cutting forces when compared with commonly used water-based metalworking fluids. At the same time scCO2 is environmentally benign, eliminates metalworking fluid maintenance and disposal, and removes the major health risks associated with today’s metalworking fluids.


2017 ◽  
Vol 253 ◽  
pp. 302-309 ◽  
Author(s):  
Isabel M. Perez de Vargas-Sansalvador ◽  
Miguel M. Erenas ◽  
Dermot Diamond ◽  
Brid Quilty ◽  
Luis Fermin Capitan-Vallvey

SPE Journal ◽  
2018 ◽  
Vol 24 (02) ◽  
pp. 857-876 ◽  
Author(s):  
Sanbai Li ◽  
Dongxiao Zhang

Summary Massive hydraulic fracturing requires an enormous consumption of water and introduces many potential environmental issues. In addition, water-based fluid tends to be trapped in formations, reducing oil/gas-phase relative permeability, and causes clay-mineral swelling, which lowers absolute permeability. Carbon dioxide (CO2) is seen as a promising alternative working fluid that poses no formation-damage risk, and it can stimulate more-complex and extensive fracture networks. However, very little, if any, extant research has quantitatively analyzed the effectiveness of CO2 fracturing, except for some qualitative fracturing experiments that are based on acoustic emissions. In this study, we systematically examine water and CO2 fracturing, and compare their performance on the basis of a rigorously coupled geomechanics and a fluid-heat-flow model. Parameters investigated include fluid viscosity, compressibility, in-situ stress, and rock permeability, illustrating how they affect breakdown pressure (BP) and leakoff, as well as fracturing effectiveness. It is found that (1) CO2 has the potential to lower BP, benefiting the propagation of fractures; (2) water fracturing tends to create wider and longer tensile fractures compared with CO2 fracturing, thereby facilitating proppant transport and placement; (3) CO2 fracturing could dramatically enhance the complexity of artificial fracture networks even under high-stress-anisotropy conditions; (4) thickened CO2 tends to generate simpler fracture networks than does supercritical CO2 (SC-CO2), but still more-complex fracture networks than fresh water; and (5) the alternative fracturing scheme (i.e., SC-CO2 fracturing followed by thickened-CO2 fracturing) can readily create complex fracture networks and carry proppant to keep hydraulic fractures open. This study reveals that, for intact reservoirs, water-based fracturing can achieve better fracturing performance than CO2 fracturing; however, for naturally fractured reservoirs, CO2 fracturing can constitute an effective way to stimulate tight/shale oil/gas reservoirs, thereby improving oil/gas production.


2016 ◽  
Vol 55 (16) ◽  
pp. 4682-4690 ◽  
Author(s):  
Seyyed Hamid Esmaeili-Faraj ◽  
Mohsen Nasr Esfahany

Wood Research ◽  
2021 ◽  
Vol 66 (3) ◽  
pp. 379-390
Author(s):  
Ahmet C. Yalinkilic ◽  
Eyup Aksoy ◽  
Musa Atar ◽  
Hamza Cinar ◽  
Hakan Keskin

This study was carried out to determine the effects of bleaching chemicals and varnishes on the amount of carbon dioxide (CO2) in the combustion of oriental beech (Fagus orientalis Lipsky). For this purpose, samples of Oriental beech prepared according to ASTM D 358 contain 18% R1 = (NaOH + H2O2), R2 = (NaOH + Ca(OH)2 + H2O2), R3 = (Na2S2O5 + H2C2O4), R4 = (NaSiO3 + H2O2), R5 = (KMnO4 + Na2S2O5 + H2O2) solution groups, after bleaching with solution groups, water based, synthetic, polyurethane and acrylic varnish were applied according to ASTM D 3023 and combustion tests were carried out in accordance with ASTM E 160-50. Gas measurements were made with the SIGMA 74172 NSU flue gas device during the combustion process. As a result, in respect to the burning types; the highest amount of CO2 (ppm) was found in the self-combustion (8.468 ppm) while the lowest was obtained from the flame combustion source (4.599 ppm). In respect to the types of bleaching; the highest in R5 (7.458 ppm) and the lowest in R3 (4.059 ppm) were found. According to the varnish types; the highest value was found in the synthetic varnish (8.261), and the lowest value was found in the acrylic varnish (4.772 ppm). According to combustion type + bleaching solution + varnish type interaction, the highest values were found for without flame combustion (II) + R3 + Sn (18.40 ppm) and lowest for flame source combustion (I) + R5 + Pu (0.600 ppm). Consequently, the highest values for combustion gases were found in samples of oriental beech wood samples treated with water-based varnish with R1 solution. According to this, in terms of human health and life safety, possibility of fire in places, R3 solution and acrylic varnish may be used in the related industries.


2013 ◽  
Vol 92 (12) ◽  
pp. 3144-3148 ◽  
Author(s):  
M.K. Rankin ◽  
R.L. Alphin ◽  
E.R. Benson ◽  
A.L. Johnson ◽  
D.P. Hougentogler ◽  
...  

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