scholarly journals Calculations of the light absorption spectra of porphyrinoid chromophores for dye-sensitized solar cells

2016 ◽  
Vol 18 (40) ◽  
pp. 27877-27884 ◽  
Author(s):  
Raúl Mera-Adasme ◽  
Wen-Hua Xu ◽  
Dage Sundholm ◽  
Fernando Mendizabal

Solar power is a strong alternative to the currently used fossil fuels in order to satisfy the world's energy needs.




2021 ◽  
Vol 5 (4) ◽  
pp. 1171-1183 ◽  
Author(s):  
Alessio Dessì ◽  
Dimitris A. Chalkias ◽  
Stefania Bilancia ◽  
Adalgisa Sinicropi ◽  
Massimo Calamante ◽  
...  

In this paper, we present the design and synthesis of three organic dyes specially developed for the fabrication of dye-sensitized solar cells with potential application in greenhouses cladding.



RSC Advances ◽  
2015 ◽  
Vol 5 (75) ◽  
pp. 61284-61289 ◽  
Author(s):  
Joo Ho Lim ◽  
Jung Woo Leem ◽  
Jae Su Yu

A negatively tapered nanohole-patterned polydimethylsiloxane (PDMS) antireflective protection layer with a hydrophobic surface improves the sunlight absorption of dye-sensitized solar cells.



2019 ◽  
Vol 233 (9) ◽  
pp. 1247-1259
Author(s):  
Madhu Prakasam

Abstract In this work, we systematically investigate the impacts of electron-donor based on Triphenylamine (TPA). The Geometry structure, energy levels, light-harvesting ability and ultraviolet-visible absorption spectra were calculated by using Density Functional Theory (DFT) and Time-Dependent-DFT. The electron injection rate of the TPA-N(CH3)2 based dyes has 0.71 eV for high among the dye sensitizer. The First and Second order Hyperpolarizability of the 11.95 × 10−30 e.s.u and 12195.54 a.u, respectively for TPA-N(CH3)2 based dye. The calculated absorption spectra were showed in the ultra-violet visible region for power conversion region. The study reveals that the electron transfer character of TPA-N(CH3)2 based dyes can be made suitable for applications in Dye-Sensitized Solar Cells.



2019 ◽  
Vol >15 (5) ◽  
pp. 501-505 ◽  
Author(s):  
Mohammad Rezaul Karim ◽  
Muhammad Ali Shar ◽  
Syed Abdullah

Background: Energy crisis is a vital issue worldwide and it will be increased tremendously in future. Alternative energy sources have been sought for the betterment of the future world. Solar energy is an alternative energy resource with plenty of opportunities. To make user- friendly and cheaper solar cells, dye-sensitized solar cells are tried to develop in this aspect. Objective: Single dye is not good enough to capture a wide range of solar light. The blending of different dyes is an alternative approach to harvest a wider range of solar lights on solar cells. Here, N719 and IR dyes were utilized to get UV-VIS and NIR ranges of solar lights in dye-sensitized solar cells. Methods: Dye-sensitized solar cells (DSSCs) were fabricated by using mixed dyes with various combinations of N719 (dye A) and IR dyes (dye B). The mixed dyes solutions were adsorbed on titanium dioxide (TiO2) and revealed significant light absorption & photosensitization compared with the individual dye solutions. The DSSCs fabricated with more percentage of IR dyes exhibited the best sensitization and broader spectrum. Results: The light absorption spectrum of the blended dyes solutions was confined peaks resultant of both N719 and IR dyes. The maximum efficiencies of 7.91% and 7.77% were obtained with 70% and 80% of IR dyes, respectively. Conclusion: Both N719 and IR mixed dyes solar cells were fabricated successfully for the first time. The relevant reasons behind the working of N719 and IR mixed dyes solar cells have been discussed. It was also noted that only IR dyes sensitized cells did not function under the simulated sunlight.



2011 ◽  
Vol 2011 ◽  
pp. 1-11 ◽  
Author(s):  
Xiaoqing Lu ◽  
Shuxian Wei ◽  
Chi-Man Lawrence Wu ◽  
Ning Ding ◽  
Shaoren Li ◽  
...  

The design of light-absorbent dyes with cheaper, safer, and more sustainable materials is one of the key issues for the future development of dye-sensitized solar cells (DSSCs). We report herein a theoretical investigation on a series of polypyridyl Fe(II)-based complexes of FeL2(SCN)2, [FeL3]2+, [FeL′(SCN)3]-, [FeL′2]2+, and FeL′′(SCN)2(L = 2,2′-bipyridyl-4,4′-dicarboxylic acid, L′ = 2,2′,2″-terpyridyl-4,4′,4″-tricarboxylic acid, L″= 4,4‴-dimethyl-2,2′ : 6′,2″ :6″,2‴-quaterpyridyl-4′,4″-biscarboxylic acid) by density functional theory (DFT) and time-dependent DFT (TD-DFT). Molecular geometries, electronic structures, and optical absorption spectra are predicted in both the gas phase and methyl cyanide (MeCN) solution. Our results show that polypyridyl Fe(II)-based complexes display multitransition characters of Fe → polypyridine metal-to-ligand charge transfer and ligand-to-ligand charge transfer in the range of 350–800 nm. Structural optimizations by choosing different polypyridyl ancillary ligands lead to alterations of the molecular orbital energies, oscillator strength, and spectral response range. Compared with Ru(II) sensitizers, Fe(II)-based complexes show similar characteristics and improving trend of optical absorption spectra along with the introduction of different polypyridyl ancillary ligands.



2016 ◽  
Vol 4 (2) ◽  
pp. 519-528 ◽  
Author(s):  
Heng Wu ◽  
Lin Yang ◽  
Yang Li ◽  
Min Zhang ◽  
Jing Zhang ◽  
...  

We scrutinize the effects of ancillary electron-donors on light absorption and charge recombination in phenanthrocarbazole dye-sensitized solar cells.



ACS Photonics ◽  
2014 ◽  
Vol 1 (8) ◽  
pp. 710-717 ◽  
Author(s):  
Min Zhang ◽  
Zhaoyang Yao ◽  
Cancan Yan ◽  
Yanchun Cai ◽  
Yameng Ren ◽  
...  


2016 ◽  
Vol 3 (1) ◽  
Author(s):  
Taeheon Kim ◽  
Yogeenth Kumaresan ◽  
Sung Jun Cho ◽  
Chang-Lyoul Lee ◽  
Heon Lee ◽  
...  


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