scholarly journals CO2-switchable polymer-hybrid silver nanoparticles and their gas-tunable catalytic activity

RSC Advances ◽  
2017 ◽  
Vol 7 (78) ◽  
pp. 49777-49786 ◽  
Author(s):  
Zanru Guo ◽  
Hongjian Gu ◽  
Wei Ma ◽  
Qiang Chen ◽  
Zhanfeng He ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Catalytic Activity ◽  
Flow Rate ◽  
Reaction System ◽  
Polymer Hybrid ◽  
System P ◽  
New Type

A new type CO2-switchable AgNPs hybrids show switchable and monotonous tunable catalytic activity for the reduction of 4-nitrophenol by varying the flow rate of CO2purged into the reaction system.

Catalytic conversion of biomass derivatives to lactic acid with increased selectivity in an aqueous tin(ii) chloride/choline chloride system

2018 ◽  
Vol 20 (17) ◽  
pp. 4112-4119 ◽  
Author(s):  
Asep Bayu ◽  
Akihiro Yoshida ◽  
Surachai Karnjanakom ◽  
Katsuki Kusakabe ◽  
Xiaogang Hao ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Lactic Acid ◽  
Aqueous Phase ◽  
Choline Chloride ◽  
Reaction System ◽  
Catalytic Conversion ◽  
Phase Reaction ◽  
Chloride System ◽  
System P

The catalytic activity and selectivity of SnCl2 for the conversion of biomass derivatives into LacA in the aqueous phase reaction system was found to be increased by the addition of choline chloride.

Hydroxyapatite-supported Silver Nanoparticles and Preliminary Investigations of their Catalytic Potential

2017 ◽  
Vol 68 (6) ◽  
pp. 1371-1374 ◽  
Author(s):  
Leonard Ignat ◽  
Maurusa Elena Ignat ◽  
Irina Gradinaru
Keyword(s):  
Silver Nanoparticles ◽  
Catalytic Activity ◽  
Point Of View ◽  
Structure And Morphology ◽  
Catalytic Potential ◽  
Visible Spectra ◽  
Before And After ◽  
New Type ◽  
Main Factors ◽  
Absorbance Data

The hydroxyapatite-supported silver nanoparticles were synthesized and used as a new type of catalyst for the discoloration of a model cationic dye in a Fenton-like process. The structure and morphology of the catalyst were investigated by FTIR, TEM and SEM before and after reaction. The main factors that could influence the catalytic activity were summary investigated. The catalytic activity was monitored by evaluating the discoloration degree from the absorbance data recorded in the visible spectra. The results obtained during these preliminary investigations are very promising from applicative point of view.

Synthesis of N ‐Acetylcysteine Conjugated Cholic Acid Stabilized Gold and Silver Nanoparticles: Evaluation of Their Catalytic Activity and Toxicity Assessment

2021 ◽  
Vol 6 (22) ◽  
pp. 5474-5487
Author(s):  
Nishanthi Ezhumalai ◽  
Manivannan Nanthagopal ◽  
Shanmugam Chandirasekar ◽  
Manikandan Elumalai ◽  
Mathivanan Narayanasamy ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Catalytic Activity ◽  
Cholic Acid ◽  
Toxicity Assessment ◽  
Gold And Silver Nanoparticles

Research on an axial-mounted dual magnetostrictive material rods-based electro-hydrostatic actuator

2021 ◽  
pp. 1045389X2110145
Author(s):  
Yuchuan Zhu ◽  
Chang Liu ◽  
Yunze Song ◽  
Long Chen ◽  
Yulei Jiang ◽  
...  
Keyword(s):  
Mathematical Model ◽  
Flow Rate ◽  
Flow Distribution ◽  
Maximum Flow ◽  
Magnetostrictive Material ◽  
Simulation Techniques ◽  
Motion State ◽  
New Type ◽  
Output Characteristics ◽  
Active Rectification

In this paper, an electro-hydrostatic actuator driven by dual axial-mounted magnetostrictive material rods-based pumps (MMPs) with a new type of active rectification valve is designed in the current study. Based on flow distribution of the active rectification valve and driving energy provided by two MMPs, the actuator can output continuous and bidirectional displacement. By establishing a mathematical model of the actuating system, using simulation techniques, the change rule of hydraulic cylinder’s motion state caused by different driving signals are studied and analyzed. Test equipment platform is constructed in the laboratory to test the output characteristics and confirm the feasibility of the new concept. The experimental results indicate that the maximum flow rate can reach approximately 2.7 L·min−1, while the operating frequency is 180 Hz.

Uncommon Carbene-to-Azole Ligand Rearrangement of N-heterocyclic Carbenes in a Ruthenium System

2021 ◽  
Author(s):  
Bo Zhang ◽  
Yu'ai Duan ◽  
Xin Zhang ◽  
Shuai Guo
Keyword(s):  
Heterocyclic Carbenes ◽  
System P ◽  
New Type

The study of non-innocent behavior of NHCs (NHCs = N-heterocyclic carbenes) has great implications for NHC-involved catalysis. Herein, we report a new type of NHC-to-azole rearrangement, during which process the...

scholarly journals Kinetics and mechanism of meso-tetraphenylporphyriniron(III) chloride (TPP) catalysed oxidation of indole by sodium perborate

2013 ◽  
Vol 15 (2) ◽  
pp. 107-111 ◽  
Author(s):  
D. Kungumathilagam ◽  
K. Karunakaran
Keyword(s):  
Acetic Acid ◽  
Catalytic Activity ◽  
Reaction System ◽  
Kinetic Scheme ◽  
Mechanistic Study ◽  
Radical Mechanism ◽  
Aqueous Acetic Acid ◽  
Sodium Perborate ◽  
Acetic Acid Medium ◽  
Catalysed Oxidation

Developing catalyst is very significant for biologically important reactions which yield products, used as drugs. Mechanistic study on meso-tetraphenylporphyriniron(III) chloride (TPP) catalysed oxidation of indole by sodium perborate in aqueous acetic acid medium have been carried out. The reaction follows a fractional order with respect to substrate and catalyst. The order with respect to oxidant was found to be one. Increase in the percentage of acetic acid and increase in the concentration of [H+] decreased the rate. The reaction fails to initiate polymerization, and a radical mechanism is ruled out. Activation and thermodynamic parameters have been computed. A suitable kinetic scheme based on these observations has been proposed. Significant catalytic activity is observed for the reaction system in the presence of TPP.

scholarly journals Effect of acrylic acid feed contents of microgels on catalytic activity of silver nanoparticles fabricated hybrid microgels

2015 ◽  
Vol 39 ◽  
pp. 96-107 ◽  
Author(s):  
Zahoor H. FAROOQI ◽  
Shanza Rauf KHAN ◽  
Robina BEGUM ◽  
Farah KANWAL ◽  
Ahsan SHARIF ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Catalytic Activity ◽  
Acrylic Acid ◽  
Hybrid Microgels

PHOTO-CATALYTIC ACTIVITY AND PHOTO-ABSORPTION OF PLASMA-SPRAYED NANO-STRUCTURED TiO2 COATINGS

2010 ◽  
Vol 24 (31) ◽  
pp. 6115-6127 ◽  
Author(s):  
MARYAMOSSADAT BOZORGTABAR ◽  
MEHDI SALEHI ◽  
MOHAMMADREZA RAHIMIPOUR ◽  
MOHAMMADREZA JAFARPOUR
Keyword(s):  
Catalytic Activity ◽  
Flow Rate ◽  
Test Chamber ◽  
Catalytic Efficiency ◽  
Surface Characteristics ◽  
Catalytic Performance ◽  
Atmospheric Plasma ◽  
Argon Flow Rate ◽  
Photo Catalytic Activity ◽  
Argon Flow

Titanium dioxide coatings were deposited by utilizing atmospheric plasma-spraying system. The agglomerated P25/20 nano-powder and different spraying parameters (e.g., Argon flow rate and spray distance) were used to determine their influences on the microstructure, crystalline structure, photo-absorption, and photo-catalytic performance of the coatings. The microstructure and phases of as-sprayed TiO 2 coatings were characterized by scanning electron microscope SEM and X-ray diffraction, respectively. Surface characteristics were investigated by Fourier Transform Infrared. Photo-catalytic efficiency of the elaborated samples was also determined in an environmental test chamber set-up and evaluated from the conversion rate of ethanol. The photo-absorption was determined by UV–Vis spectrophotometer. The as-sprayed TiO2 coating was photo-catalytically reactive for the degradation of ethanol. The photo-catalytic activity was influenced by spray conditions. It is found that the photo-catalytic activity is significantly influenced by anatase content, surface area, and surface state. The results showed that the argon flow rate has an influence on the microstructure, anatase content, and photo-catalytic activity of the TiO 2 coatings.

Catalytic activity and selectivity of a range of ruthenium complexes tested in the styrene/EDA reaction system

2014 ◽  
Vol 386 ◽  
pp. 86-94 ◽  
Author(s):  
Fu Ding ◽  
Ya-guang Sun ◽  
Francis Verpoort ◽  
Valerian Dragutan ◽  
Ileana Dragutan
Keyword(s):  
Catalytic Activity ◽  
Ruthenium Complexes ◽  
Reaction System
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