scholarly journals Homogeneous melting near the superheat limit of hard-sphere crystals

Soft Matter ◽  
2018 ◽  
Vol 14 (13) ◽  
pp. 2447-2453 ◽  
Author(s):  
Feng Wang ◽  
Ziren Wang ◽  
Yi Peng ◽  
Zhongyu Zheng ◽  
Yilong Han

We find the superheat limit of hard-sphere fcc crystals at volume fraction 0.494 due to the vanishing bulk modulus.


Geophysics ◽  
2021 ◽  
pp. 1-101
Author(s):  
Kun Li ◽  
Xingyao Yin ◽  
Zhaoyun Zong ◽  
Dario Grana

The estimation of petrophysical and fluid-filling properties of subsurface reservoirs from seismic data is a crucial component of reservoir characterization. Seismic amplitude variation with offset (AVO) inversion driven by rock physics is an effective approach to characterize reservoir properties. Generally, PP-wave reflection coefficients, elastic moduli and petrophysical parameters are nonlinearly coupled, especially in the multiple type pore-space reservoirs, which makes seismic AVO petrophysics inversion ill-posed. We propose a new approach that combines Biot-Gassmann’s poro-elasticity theory with Russell’s linear AVO approximation, to estimate the reservoir properties including elastic moduli and petrophysical parameters based on multi-trace probabilistic AVO inversion algorithm. We first derive a novel PP-wave reflection coefficient formulation in terms of porosity, stiff-pore volume fraction, rock matrix shear modulus, and fluid bulk modulus to incorporate the effect of pore structures on elastic moduli by considering the soft and stiff pores with different aspect ratios in sandstone reservoirs. Through the analysis of the four types of PP-wave reflection coefficients, the approximation accuracy and inversion feasibility of the derived formulation are verified. The proposed stochastic inversion method aims to predict the posterior probability density function in a Bayesian setting according to a prior Laplace distribution with vertical correlation and prior Gaussian distribution with lateral correlation of model parameters. A Metropolis-Hastings stochastic sampling algorithm with multiple Markov chains is developed to simulate the posterior models of porosity, stiff-pore volume fraction, rock-matrix shear modulus, and fluid bulk modulus from seismic AVO gathers. The applicability and validity of the proposed inversion method is illustrated with synthetic examples and a real data application.



1996 ◽  
Vol 53 (2) ◽  
pp. 1990-1993 ◽  
Author(s):  
S. Amokrane ◽  
C. Regnaut


Soft Matter ◽  
2016 ◽  
Vol 12 (2) ◽  
pp. 402-407 ◽  
Author(s):  
Yuxing Zhou ◽  
Scott T. Milner

In glassy hard-sphere fluids, with varying particle volume fraction and distance between pinned particles, particle diffusivities and structural relaxation times both collapse to master curves, revealing a growing static length scale.



2020 ◽  
Vol 6 (43) ◽  
pp. eabc5916
Author(s):  
Felix Lehmkühler ◽  
Birgit Hankiewicz ◽  
Martin A. Schroer ◽  
Leonard Müller ◽  
Beatrice Ruta ◽  
...  

Despite intensive studies in the past decades, the local structure of disordered matter remains widely unknown. We show the results of a coherent x-ray scattering study revealing higher-order correlations in dense colloidal hard-sphere systems in the vicinity of their crystallization and glass transition. With increasing volume fraction, we observe a strong increase in correlations at both medium-range and next-neighbor distances in the supercooled state, both invisible to conventional scattering techniques. Next-neighbor correlations are indicative of ordered precursor clusters preceding crystallization. Furthermore, the increase in such correlations is accompanied by a marked slowing down of the dynamics, proving experimentally a direct relation between orientational order and sample dynamics in a soft matter system. In contrast, correlations continuously increase for nonequilibrated, glassy samples, suggesting that orientational order is reached before the sample slows down to reach (quasi-)equilibrium.



1999 ◽  
Vol 32 (3) ◽  
pp. 426-435 ◽  
Author(s):  
Cheng-Si Tsao ◽  
Tsang-Lang Lin

An improved method for small-angle X-ray scattering (SAXS) data analysis is developed to reconstruct the free-form particle size distribution of δ′ precipitation in an Al–Li alloy. This improved method consists of four iterative steps; the interparticle interference is also included. The indirect transform method (ITM) plus a hard-sphere (HS) model which considers the depleted zones are used in the analysis of δ′ precipitation in an Al–Li alloy. Two parameters, namely the hard-sphere volume fraction, ηHS, and the ratio of hard-sphere radius to the particle radius,RHS/R, which determine the structure factor of the interparticle effect, are iteratively calculated using the monodisperse assumption and Gaussian size distribution. These two parameters are finally used in reconstructing the particle size distribution by the ITM + HS method. This method is tested by analysing simulated SAXS data and shows a better agreement than found in similar studies. This improved method is applied to analyse a set of experimental SAXS intensities from δ′ (Al3Li particles) precipitation in an Al–9.7 at.% Li alloy. The monodisperse results are compared with the polydisperse ITM + HS results. The current ITM + HS method fits the SAXS data better than the other methods. The variations of average radii with aging time were found to follow the kinetic power law. The SAXS results are used to investigate the theoretical kinetic model of the volume-fraction effect on late-stage coarsening (Ostwald ripening). By comparing both experimentally obtained asymptotic size distributions of δ′ particles as well as coarsening rate constants with those predicted by the various kinetic models, the modified Lifshitz–Slyozov–Wagner (MLSW) theory is found to be in better agreement with the experimental results than the other theories.



2017 ◽  
Vol 28 (1) ◽  
pp. 134-161 ◽  
Author(s):  
Amade Pouya ◽  
Cheng Zhu ◽  
Chloé Arson

In quasi-brittle polycrystalline materials, damage by cracking or cleavage dominates plastic and viscous deformation. This paper proposes a micromechanical model for rock-like materials, incorporating the elastic-damage accommodation of the material matrix, and presents an original method to solve the system of implicit equations involved in the formulation. A self-consistent micromechanical approach is used to predict the anisotropic behavior of a polycrystal in which grain inclusions undergo intragranular damage. Crack propagation along planes of weakness with various orientation distributions at the mineral scale is modeled by a softening damage law and results in mechanical anisotropy at the macroscopic scale. One original aspect of the formulated inclusion–matrix model is the use of an explicit expression of Hill’s tensor to account for matrix ellipsoidal anisotropy. To illustrate the model capabilities, a uniaxial compression test was simulated for a variety of polycrystals made of two types of mineral inclusions with each containing only one plane of weakness. Damage always occurred in only one mineral type: the damaging mineral was that with a smaller shear modulus (respectively higher bulk modulus) when bulk modulus (respectively shear modulus) was the same. For two minerals with the same shear moduli but different bulk moduli, the maximum damage in the polycrystal under a given load was obtained at equal mineral fractions. However, for two minerals with different shear moduli, the macroscopic damage was not always maximum when the volume fraction of two minerals was the same. When the weakness planes’ orientations in the damaging mineral laid within a narrow interval close to the loading direction, the macroscopic damage behavior was more brittle than when the orientations were distributed over a wider interval. Parametric studies show that upon proper calibration, the proposed model can be extended to understand and predict the micro–macro behavior of different types of quasi-brittle materials.



1989 ◽  
Vol 155 ◽  
Author(s):  
L. Marshall ◽  
C. F. Zukoski

ABSTRACTThe flow of hard sphere-like suspensions near close packing is explored. The change in viscosity with stress and volume fraction shows that at volume fractions above 0.5 shear thickening occurs and that the characteristic shear rates for shear thinning and shear thickening decrease rapidly above this volume fraction. The creep compliance is well characterized by a stretched exponential relaxation time spectrum above volume fractions of 0.52. These results suggest that the limiting volume fraction where the zero shear rate viscosity diverges is determined by a liquid/glass phase transition very similar to that predicted for hard sphere liquids.



2004 ◽  
Vol 121 (16) ◽  
pp. 7849 ◽  
Author(s):  
H. Kriegs ◽  
G. Petekidis ◽  
G. Fytas ◽  
R. S. Penciu ◽  
E. N. Economou ◽  
...  
Keyword(s):  


1990 ◽  
Vol 195 ◽  
Author(s):  
D.A. Weitz ◽  
J. Liu ◽  
L. Ye ◽  
Ping Sheng

ABSTRACTWe use Brillouin scattering to measure the dispersion of the propagating acoustic modes in a suspension of hard sphere colloids. We find two distinct longitudinal modes when the sound wavelength becomes comparable to the sphere diameter. The higher frequency mode has a velocity intermediate between those of the pure solid and the pure liquid phases, and its velocity increases with increasing volume fraction, ø. The lower frequency mode has a velocity less than the velocities in either the pure fluid or pure solid phases, and its velocity decreases with increasing ø. We interpret the higher frequency mode as a compressional wave which propagates through both the solid and the fluid, as expected for a composite medium. The lower frequency mode has not been observed before, and is interpreted as a surface acoustic mode, which propagates between adjacent spheres through a decaying portion of the excitation in the fluid.





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