Carbon dioxide in the cage: manganese metal–organic frameworks for high performance CO2electrodes in Li–CO2batteries

2018 ◽  
Vol 11 (5) ◽  
pp. 1318-1325 ◽  
Author(s):  
Siwu Li ◽  
Yu Dong ◽  
Junwen Zhou ◽  
Yuan Liu ◽  
Jiaming Wang ◽  
...  

Manganese MOF-based cathodes achieve high discharge capacity, reduced overpotentials and promoted reversibility in Li–CO2batteries.

2019 ◽  
Vol 7 (12) ◽  
pp. 7213-7220 ◽  
Author(s):  
Hongyan Lu ◽  
Yuanxin Wan ◽  
Tianyi Wang ◽  
Rong Jin ◽  
Peitao Ding ◽  
...  

A novel SnO2/C AIB with high discharge capacity and long cycle life is achieved.


2014 ◽  
Vol 16 (36) ◽  
pp. 19668-19673 ◽  
Author(s):  
Wei Chen ◽  
Lujiang Huang ◽  
Jun Hu ◽  
Tengfei Li ◽  
Feifei Jia ◽  
...  

Carbon nanotubes (CNTs) possess excellent structural and electronic properties and have been widely investigated as anode materials. Covalent modification of carbon nanotubes (CNTs) with organosilica-containing polyoxometalate (POM) leads to the formation of the nanocomposite CNTs–SiW11 with high discharge capacity, good capacity retention and cycling stability.


2020 ◽  
Vol 20 (3) ◽  
pp. 1715-1722
Author(s):  
Shu Hong ◽  
Yunzhao Han ◽  
Kun Zhang ◽  
Mingbo Wang ◽  
Nana Cui ◽  
...  

Lithium-sulphur batteries are considered as some of the most potent secondary-battery systems. These batteries are expected to have extensive applications in fields requiring high-energy density. However, such applications are hindered by some serious intrinsic obstacles. Herein, TiO2 nanosheets-rGO/sulphur (TiO2 NS-rGO/S) composites were fabricated through a two-process hydrothermal method. TiO2 nanosheets served as active sites for polysulphide absorption, whereas rGO offered space for sulphur improvement and TiO2 NS-rGO/S composites. The TiO2 NS-rGO/S composite exhibited high discharge capacity of 1099 mAh·g-1 at 0.2 C rate and retained a capacity of 690 mAh·g-1 after 100 cycles, with high sulphur loading of 3 mg·cm-2. The high initial specific discharge capacity and improved cyclic stability were attributed to the synergistic effects of TiO2 nanosheets and rGO. These results indicated that the simple, low-cost and scalable method provides a novel perspective on practical utilisation of lithium-sulphur batteries.


Author(s):  
Manpreet Singh ◽  
Athulya S. Palakkal ◽  
Renjith S. Pillai ◽  
Subhadip Neogi

Metal-organic frameworks (MOFs) have surfaced as incipient class of multifaceted materials for selective carbon dioxide (CO2) adsorption and luminescent detection of assorted classes of lethal organo-aromatics, where functional group assisted...


2021 ◽  
Author(s):  
Yurong Shan ◽  
Dexiang Liu ◽  
Chunyan Xu ◽  
Peng Zhan ◽  
Hui Wang ◽  
...  

In this work, PMA@NH2-MIL-68(Rh) with a mangosteen spherical structure was successfully synthesized by a hydrothermal method for the photocatalytic reduction of carbon dioxide. The electronic structure and morphology of the...


2021 ◽  
Author(s):  
Dae-Woon Lim ◽  
Hiroshi Kitagawa

Since the transition of energy platforms, the proton-conductive metal–organic frameworks (MOFs) exhibiting high performance have been extensively investigated with rational strategies for their potential application in solid-state electrolytes.


2021 ◽  
Author(s):  
Jinkwang Hwang ◽  
Rika Hagiwara ◽  
Hiroshi Shinokubo ◽  
Ji-Young Shin

Dual-ion sodium-organic secondary batteries were provided with antiaromatic porphyrinoid, NiNc as an active electrode material, which implemented inherent charge-discharge behaviors with high discharge capacity, high stability, high Coulombic efficiency with...


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