Post-synthetic functionalization of a polysulfone scaffold with hydrazone-linked functionality

2018 ◽  
Vol 9 (27) ◽  
pp. 3791-3797 ◽  
Author(s):  
Dylan W. Domaille ◽  
Dillon M. Love ◽  
Xilal Y. Rima ◽  
Albert Harguindey ◽  
Benjamin D. Fairbanks ◽  
...  
Keyword(s):  
Linear Polymer ◽  
Divinyl Sulfone ◽  
Step Growth

The synthesis, characterization, and post-synthetic functionalization of a readily functionalized step-growth linear polymer derived from divinyl sulfone (DVS) and tert-butylcarbazate (TBC) is presented.

scholarly journals Nucleophile-mediated oxa-Michael addition reactions of divinyl sulfone – a thiol-free option for step-growth polymerisations

2015 ◽  
Vol 5 (12) ◽  
pp. 5091-5094 ◽  
Author(s):  
Simone Strasser ◽  
Christian Slugovc
Keyword(s):  
Michael Addition ◽  
Addition Reactions ◽  
Divinyl Sulfone ◽  
Step Growth

The first example of an aa–bb-type nucleophile-mediated oxa-Michael addition polymerisation reaction is reported.

Anisotropy of interfacial defects in the initial stage of MOVPE GaAs growth On Si

1990 ◽  
Vol 48 (4) ◽  
pp. 592-593
Author(s):  
C. Vannuffel ◽  
C. Schiller ◽  
J. P. Chevalier
Keyword(s):  
Early Stage ◽  
Threading Dislocations ◽  
Mbe Growth ◽  
Detailed Mechanism ◽  
Si Substrates ◽  
Initial Stage ◽  
Interfacial Defects ◽  
Interfacial Dislocations ◽  
Step Growth ◽  
Essential Problem

Recently, interest has focused on the epitaxy of GaAs on Si as a promising material for electronic applications, potentially for integration of optoelectronic devices on silicon wafers. The essential problem concerns the 4% misfit between the two materials, and this must be accommodated by a network of interfacial dislocations with the lowest number of threading dislocations. It is thus important to understand the detailed mechanism of the formation of this network, in order to eventually reduce the dislocation density at the top of the layers.MOVPE growth is carried out on slightly misoriented, (3.5°) from (001) towards , Si substrates. Here we report on the effect of this misorientation on the interfacial defects, at a very early stage of growth. Only the first stage, of the well-known two step growth process, is thus considered. Previously, we showed that full substrate coverage occured for GaAs thicknesses of 5 nm in contrast to MBE growth, where substantially greater thicknesses are required.

Polydispersity and scaling in linear polymer condensates

1984 ◽  
Vol 45 (1) ◽  
pp. 151-155 ◽  
Author(s):  
M. Daoud ◽  
F. Family
Keyword(s):  
Linear Polymer

Polymer Chemistry

2004 ◽  
Keyword(s):  
Conducting Polymers ◽  
Liquid Crystalline ◽  
Polymer Chemistry ◽  
Chain Growth ◽  
Crystalline Polymers ◽  
Wide Range ◽  
Cyclic Oligomers ◽  
Step Growth

Polymer Chemistry: A Practical Approach in Chemistry has been designed for both chemists working in and new to the area of polymer synthesis. It contains detailed instructions for preparation of a wide-range of polymers by a wide variety of different techniques, and describes how this synthetic methodology can be applied to the development of new materials. It includes details of well-established techniques, e.g. chain-growth or step-growth processes together with more up-to-date examples using methods such as atom-transfer radical polymerization. Less well-known procedures are also included, e.g. electrochemical synthesis of conducting polymers and the preparation of liquid crystalline elastomers with highly ordered structures. Other topics covered include general polymerization methodology, controlled/"living" polymerization methods, the formation of cyclic oligomers during step-growth polymerization, the synthesis of conducting polymers based on heterocyclic compounds, dendrimers, the preparation of imprinted polymers and liquid crystalline polymers. The main bulk of the text is preceded by an introductory chapter detailing some of the techniques available to the scientist for the characterization of polymers, both in terms of their chemical composition and in terms of their properties as materials. The book is intended not only for the specialist in polymer chemistry, but also for the organic chemist with little experience who requires a practical introduction to the field.

One step “growth to spinning” of biaxially multilayered CNT web electrode for long cycling Li-O2 batteries

Carbon ◽  
2021 ◽  
Author(s):  
Young Shik Cho ◽  
Hyunjin Kim ◽  
Minhoo Byeon ◽  
Yeonsu Jung ◽  
DongJoon Lee ◽  
...  
Keyword(s):  
One Step ◽  
Step Growth

Chemiluminescent self-reported unfolding of single-chain nanoparticles

2021 ◽  
Author(s):  
Fabian R. Bloesser ◽  
Sarah L. Walden ◽  
Ishrath M. Irshadeen ◽  
Lewis C. Chambers ◽  
Christopher Barner-Kowollik
Keyword(s):  
Polymer Chains ◽  
Linear Polymer ◽  
Single Chain

We demonstrate the light-induced, crosslinker mediated collapse of linear polymer chains into single-chain nanoparticles (SCNPs) capable of self-reporting their unfolding.

scholarly journals T4-like Bacteriophages Isolated from Pig Stools Infect Yersinia pseudotuberculosis and Yersinia pestis Using LPS and OmpF as Receptors

Viruses ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 296
Author(s):  
Mabruka Salem ◽  
Maria I. Pajunen ◽  
Jin Woo Jun ◽  
Mikael Skurnik
Keyword(s):  
Yersinia Pseudotuberculosis ◽  
Host Recognition ◽  
Tail Fiber ◽  
Long Tail ◽  
Phage T4 ◽  
One Step ◽  
In Trans ◽  
Step Growth ◽  
Resistant Strains ◽  
Salmonella Phage

The Yersinia bacteriophages fPS-2, fPS-65, and fPS-90, isolated from pig stools, have long contractile tails and elongated heads, and they belong to genus Tequatroviruses in the order Caudovirales. The phages exhibited relatively wide host ranges among Yersinia pseudotuberculosis and related species. One-step growth curve experiments revealed that the phages have latent periods of 50–80 min with burst sizes of 44–65 virions per infected cell. The phage genomes consist of circularly permuted dsDNA of 169,060, 167,058, and 167,132 bp in size, respectively, with a G + C content 35.3%. The number of predicted genes range from 267 to 271. The phage genomes are 84–92% identical to each other and ca 85% identical to phage T4. The phage receptors were identified by whole genome sequencing of spontaneous phage-resistant mutants. The phage-resistant strains had mutations in the ompF, galU, hldD, or hldE genes. OmpF is a porin, and the other genes encode lipopolysaccharide (LPS) biosynthetic enzymes. The ompF, galU, and hldE mutants were successfully complemented in trans with respective wild-type genes. The host recognition was assigned to long tail fiber tip protein Gp38, analogous to that of T-even phages such as Salmonella phage S16, specifically to the distal β-helices connecting loops.

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