scholarly journals A three-dimensional self-assembled SnS2-nano-dots@graphene hybrid aerogel as an efficient polysulfide reservoir for high-performance lithium–sulfur batteries

2018 ◽  
Vol 6 (17) ◽  
pp. 7659-7667 ◽  
Author(s):  
Liu Luo ◽  
Sheng-Heng Chung ◽  
Arumugam Manthiram

A free-standing self-assembled graphene aerogel embedded with SnS2nano-dots (SnS2-ND@G) is established as an efficient substrate for high-loading sulfur cathodes with synergistically physical and chemical polysulfide-trapping capability.

2015 ◽  
Vol 3 (41) ◽  
pp. 20482-20486 ◽  
Author(s):  
A. Schneider ◽  
C. Suchomski ◽  
H. Sommer ◽  
J. Janek ◽  
T. Brezesinski

A practical high-loading Li–S battery is realized by using free-standing and highly conductive N-doped carbon paper as sulfur host.


2018 ◽  
Vol 6 (48) ◽  
pp. 24841-24847 ◽  
Author(s):  
Ran Yu ◽  
Sheng-Heng Chung ◽  
Chun-Hua Chen ◽  
Arumugam Manthiram

The internal porous core and external dense shell of the three-dimensional cathode substrate, respectively, accommodate and encapsulate a large amount of active material.


Materials ◽  
2021 ◽  
Vol 14 (20) ◽  
pp. 6131
Author(s):  
Donghuang Wang ◽  
Aijun Zhou ◽  
Zhujun Yao ◽  
Xinhui Xia ◽  
Yongqi Zhang

Improving the utilization efficiency of active materials and suppressing the dissolution of lithium polysulfides into the electrolyte are very critical for development of high-performance lithium-sulfur batteries. Herein, a novel strategy is proposed to construct a three-dimensional (3D) N-doped carbon nanotubes (CNTs) networks to support lithium polysulfides (3D-NCNT-Li2S6) as a binder-free cathode for high-performance lithium-sulfur batteries. The 3D N-doped CNTs networks not only provide a conductive porous 3D architecture for facilitating fast ion and electron transport but also create void spaces and porous channels for accommodating active sulfur. In addition, lithium polysulfides can be effectively confined among the networks through the chemical bond between Li and N. Owing to the synergetic effect of the physical and chemical confinement for the polysulfides dissolution, the 3D-NCNT-Li2S6 cathodes exhibit enhanced charge capacity and cyclic stability with lower polarization and faster redox reaction kinetics. With an initial discharge capacity of 924.8 mAh g−1 at 1 C, the discharge capacity can still maintain 525.1 mAh g−1 after 200 cycles, which is better than that of its counterparts.


2019 ◽  
Vol 6 (9) ◽  
pp. 2528-2538
Author(s):  
Mengxia Li ◽  
Ying Dai ◽  
Xinmei Pei ◽  
Wen Chen

A three-dimensional HrGO with a hierarchically porous structure was successfully synthesized as a sulfur-hosting material with high sulfur loading for high-performance lithium–sulfur batteries.


RSC Advances ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 6568-6575 ◽  
Author(s):  
Mengmeng Liu ◽  
Xiaohang Zhu ◽  
Tianye Ma ◽  
Congcong Zhang ◽  
Xiang Chen ◽  
...  

GA–TiO2 composites as a cathode material realize an excellent electrochemical performance in Li–S batteries.


2019 ◽  
Vol 31 (19) ◽  
pp. 7910-7921 ◽  
Author(s):  
Hyuksoo Shin ◽  
Doyun Kim ◽  
Hyeon Jin Kim ◽  
Jiheon Kim ◽  
Kookheon Char ◽  
...  

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