Self-healing and shape-memory properties of polymeric materials cross-linked by hydrogen bonding and metal–ligand interactions

2019 ◽  
Vol 10 (33) ◽  
pp. 4519-4523 ◽  
Author(s):  
Yuichiro Kobayashi ◽  
Tomohiro Hirase ◽  
Yoshinori Takashima ◽  
Akira Harada ◽  
Hiroyasu Yamaguchi
Keyword(s):  
Hydrogen Bonding ◽  
Shape Memory ◽  
Polymeric Materials ◽  
Cross Linking ◽  
Self Healing ◽  
Shape Memory Properties ◽  
Ligand Interactions ◽  
Non Covalent Interactions ◽  
Covalent Interactions ◽  
Metal Ligand

Polymeric materials were prepared by cross-linking them with two independent non-covalent interactions, namely hydrogen bonding and metal–ligand interactions.

A novel supramolecular system with multiple fluorescent states constructed by orthogonal self-assembly

2016 ◽  
Vol 7 (23) ◽  
pp. 3827-3831 ◽  
Author(s):  
Qingchen Dong ◽  
Wenshan Qu ◽  
Pi Wang ◽  
Wai-Yeung Wong
Keyword(s):  
Self Assembly ◽  
Supramolecular System ◽  
Ligand Interactions ◽  
Non Covalent Interactions ◽  
Covalent Interactions ◽  
Metal Ligand

A novel supramolecular fluorescent system was successfully constructed by orthogonal self-assembly of host–guest and metal–ligand interactions. By controlling the non-covalent interactions in different ways, the system exhibits diverse fluorescent switching phenomena.

A facile strategy to fabricate highly-stretchable self-healing poly(vinyl alcohol) hybrid hydrogels based on metal–ligand interactions and hydrogen bonding

2016 ◽  
Vol 7 (47) ◽  
pp. 7269-7277 ◽  
Author(s):  
Yan Hui ◽  
Zhi-Bin Wen ◽  
Florence Pilate ◽  
Hui Xie ◽  
Cheng-Jie Fan ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Vinyl Alcohol ◽  
Poly Vinyl Alcohol ◽  
Self Healing ◽  
Hybrid Hydrogel ◽  
Hybrid Hydrogels ◽  
Ligand Interactions ◽  
Highly Stretchable ◽  
Metal Ligand

A novel poly(vinyl alcohol) hybrid hydrogel based on metal–ligand interactions and hydrogen bonding was fabricated, possessing highly-stretchable and self-healing properties.

Study on sisal-based polyurethane foam with multi-shape memory properties

2021 ◽  
Author(s):  
Lulu Pan ◽  
Jianfeng Ban ◽  
Tiwen Xu ◽  
Ruiquan Liu ◽  
Shaorong Lu
Keyword(s):  
Shape Memory ◽  
Polyurethane Foam ◽  
Cross Linking ◽  
Hydroxyl Groups ◽  
Shape Memory Properties ◽  
New Type ◽  
Shape Memory Polyurethane ◽  
Chemical Cross Linking

A new type of sisal-based shape memory polyurethane foam (SMPU-PSF) was prepared by chemical cross-linking of hydroxyl groups on sisal cellulose (PSF) with polycaprolactone and MDI, which used PSF as...

scholarly journals Reversible Assembly of Terpyridine Incorporated Norbornene-Based Polymer via a Ring-Opening Metathesis Polymerization and Its Self-Healing Property

Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1173 ◽  
Author(s):  
Jookyeong Lee ◽  
Hwi Moon ◽  
Keewook Paeng ◽  
Changsik Song
Keyword(s):  
Ring Opening ◽  
Transition Metal Ions ◽  
Self Healing ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Ligand Interactions ◽  
Healing Agent ◽  
Healing Property ◽  
External Stimuli ◽  
Metal Ligand

We induced a terpyridine moiety into a norbornene-based polymer to demonstrate its self-healing property, without an external stimulus, such as light, heat, or healing agent, using metal–ligand interactions. We synthesized terpyridine incorporated norbornene-based polymers using a ring-opening metathesis polymerization. The sol state of diluted polymer solutions was converted into supramolecular assembled gels, through the addition of transition metal ions (Ni2+, Co2+, Fe2+, and Zn2+). In particular, a supramolecular complex gel with Zn2+, which is a metal with a lower binding affinity, demonstrated fast self-healing properties, without any additional external stimuli, and its mechanical properties were completely recovered.

A room-temperature self-healing elastomer with ultra-high strength and toughness fabricated via optimized hierarchical hydrogen-bonding interactions

2022 ◽  
Author(s):  
Liangliang Xia ◽  
Ming Zhou ◽  
Hongjun Tu ◽  
wen Zeng ◽  
xiaoling Yang ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Mechanical Strength ◽  
Room Temperature ◽  
Polymeric Materials ◽  
High Strength ◽  
Self Healing ◽  
High Mechanical Strength ◽  
Hydrogen Bonding Interactions ◽  
Healing Efficiency ◽  
Good Healing

The preparation of room-temperature self-healing polymeric materials with good healing efficiency and high mechanical strength is challenging. Two processes are essential to realise the room-temperature self-healing of materials: (a) a...

Construction of triple non-covalent interaction-based ultra-strong self-healing polymeric gels via frontal polymerization

2020 ◽  
Vol 8 (40) ◽  
pp. 14083-14091
Author(s):  
Ji-Dong Liu ◽  
Xiang-Yun Du ◽  
Cai-Feng Wang ◽  
Qing Li ◽  
Su Chen
Keyword(s):  
Frontal Polymerization ◽  
Self Healing ◽  
Smart Window ◽  
Covalent Interaction ◽  
Polymeric Gels ◽  
Non Covalent Interactions ◽  
Covalent Interactions

Robust and self-healing polymeric gels based on triple non-covalent interactions have been constructed for generation of a new self-healing thermoresponsive smart window.

Sign in / Sign up

Export Citation Format

Share Document