Blue-emitting butterfly-shaped donor–acceptor-type 1,3,5,9-tetraarylpyrenes: easily available, low-cost conventional fluorophores for high-performance near ultraviolet electroluminescence with CIEy < 0.05

2021 ◽  
Vol 9 (1) ◽  
pp. 260-269
Author(s):  
Huijuan Ran ◽  
Zhen Zhao ◽  
Xuewei Duan ◽  
Fuli Xie ◽  
Ruijun Han ◽  
...  
Keyword(s):  
Thermal Stability ◽  
High Performance ◽  
Low Cost ◽  
Good Thermal Stability ◽  
Near Ultraviolet ◽  
Donor Acceptor ◽  
Blue Emitters

Three donor–acceptor (DA)-type pyrene-based blue emitters with good thermal stability and their applications in NUV OLEDs are demonstrated.

Advances in preparation, modification, and application of polypropylene membrane

2016 ◽  
Vol 36 (4) ◽  
pp. 329-362 ◽  
Author(s):  
Nurul F. Himma ◽  
Sofiatun Anisah ◽  
Nicholaus Prasetya ◽  
I Gede Wenten
Keyword(s):  
Thermal Stability ◽  
High Performance ◽  
Chemical Resistance ◽  
Low Cost ◽  
Comprehensive Overview ◽  
Preparation Methods ◽  
Good Thermal Stability ◽  
Polypropylene Membrane ◽  
Membrane Fabrication ◽  
Potential Applications

Abstract Polypropylene (PP) is one of the most used polymers for microporous membrane fabrication due to its good thermal stability, chemical resistance, mechanical strength, and low cost. There have been numerous studies reporting the developments and applications of PP membranes. However, PP membrane with high performance is still a challenge. Thus, this article presents a comprehensive overview of the advances in the preparation, modification and application of PP membrane. The preparation methods of PP membrane are firstly reviewed, followed by the modification approaches of PP membrane. The modifications includes hydrophilic and superhydrophobic modification so that the PP membranes become more suitable to be applied either in aqueous applications or in non-aqueous ones. The fouling resistant of hydrophilized PP membrane and the wetting resistant of superhydrophobized PP membrane are then reviewed. Finally, special attention is given to the various potential applications and industrial outlook of the PP membranes.

Semi-bio-based aromatic polyamides from 2,5-furandicarboxylic acid: toward high-performance polymers from renewable resources

RSC Advances ◽  
2016 ◽  
Vol 6 (90) ◽  
pp. 87013-87020 ◽  
Author(s):  
Kaiju Luo ◽  
Yan Wang ◽  
Junrong Yu ◽  
Jing Zhu ◽  
Zuming Hu
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Molecular Weight ◽  
High Molecular Weight ◽  
Renewable Resources ◽  
High Performance ◽  
Good Thermal Stability ◽  
Aromatic Polyamides ◽  
High Performance Polymers ◽  
Furandicarboxylic Acid

Aromatic furanic polyamides with relatively high molecular weight were synthesized, and good thermal stability and mechanical properties were demonstrated.

scholarly journals Preparation and Thermal Properties of Modified Cu2O/Polypropylene (PP) Composite

Materials ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 309
Author(s):  
Yurong Wu ◽  
Longshan Xu ◽  
Yanying Jiang
Keyword(s):  
Thermal Stability ◽  
Surface Modification ◽  
Thermal Properties ◽  
Coupling Agent ◽  
Cuprous Oxide ◽  
Silane Coupling Agent ◽  
Low Cost ◽  
Good Thermal Stability ◽  
Silane Coupling ◽  
Pp Composites

A uniform, monodispersed superfine cuprous oxide (Cu2O) sphere with a mean diameter of 850 nm has been synthesized by solution reduction. The study reported the synthesis and thermal properties of Cu2O/PP composites for the first time. The surface modification of the superfine Cu2O sphere was carried out by using a silane coupling agent KH-570. Fourier-transform infrared (FTIR) spectroscopy and the thermogravimetric analysis (TGA) curve revealed that the Cu2O had been successfully modified by silane coupling agent KH570. The scanning electron microscope (SEM) shows that the modified Cu2O can be uniformly dispersed in the polypropylene (PP) matrix, because through surface modification, there are some active functional groups on its surface, such as the ester group, which improves its compatibility with the PP matrix. The thermal stability of Cu2O/PP composites was improved by adding a small amount of Cu2O (1 wt % of PP). Therefore, based on the potential bacteriostasis of cuprous oxide, the low cost of PP and the results of this study, it is predicted that Cu2O/PP composites can be used in infant preparation (such as milk bottles) with low cost and good thermal stability in the near future.

Heat-resistant and photoluminescent indole-based poly(ether sulfone)s

2017 ◽  
Vol 30 (4) ◽  
pp. 475-479 ◽  
Author(s):  
Wenxuan Wei ◽  
Li Yang ◽  
Guanjun Chang
Keyword(s):  
Thermal Stability ◽  
High Performance ◽  
Proton Nuclear Magnetic Resonance ◽  
Resonance Spectroscopy ◽  
Condensation Polymerization ◽  
High Glass Transition Temperature ◽  
Scanning Calorimetry ◽  
Good Thermal Stability ◽  
High Performance Polymers ◽  
Good Agreement

Indole-based poly(ether sulfone)s (PINESs), as novel high-performance polymers, have been obtained by the condensation polymerization of 4-hydroxyindole and hydroquinone with activated difluoro monomers via a catalyst-free nucleophilic substitution reaction. The structures of the polymers are characterized by means of Fourier transform infrared and proton nuclear magnetic resonance spectroscopy, and the results show good agreement with the proposed structures. Differential scanning calorimetry and thermogravimetric analysis measurements exhibit that polymers possess high glass transition temperature ( Tgs > 245°C) and good thermal stability with high decomposition temperatures ( Tds > 440°C). In addition, due to their special structure, PINESs are endowed with significantly strong photonic luminescence in N, N-dimethylformamide.

MBE Growth of Oxides for III–N MOSFETs

1999 ◽  
Vol 573 ◽  
Author(s):  
B. Gila ◽  
K N. Lee ◽  
J Laroche ◽  
F Ren ◽  
S. M. Donovan ◽  
...  
Keyword(s):  
Thermal Stability ◽  
High Performance ◽  
Gate Dielectric ◽  
Field Effect Transistors ◽  
Electrical Characterization ◽  
Dielectric Materials ◽  
Interface State ◽  
Oxide Semiconductor ◽  
Good Thermal Stability ◽  
Deposition Conditions

ABSTRACTReproducible fabrication of high performance metal oxide semiconductor field effect transistors (MOSFETs) from compound semiconductors will require both good interfacial electrical characteristics and good thermal stability. While dielectrics such as SiO2, AIN, and GdGaOx have demonstrated low to moderate interface state densities, questions remain about their thermal stability and reliability, particularly for use in high power or high temperature widebandgap devices. In this paper we will compare the utility of two potential gate dielectric materials: GdOx and GaOx. GdOx has been found to produce layers with excellent surface morphologies as evidenced by surface roughness of less than I nm. Stoichiometric films can be easily obtained over a range of deposition conditions, though deposition temperatures of 500°C appear to offer the optimum interfacial electrical quality. By contrast GaOx films are quite rough, polycrystalline and show poor thermal stability. Further they exhibit a range of stoichiometries depending upon deposition temperature, Ga flux and oxygen flux. This paper will describe the relationship between deposition conditions and film characteristics for both materials, and will present electrical characterization of capacitors fabricated from GdOx on Si.

scholarly journals Fluorescent Indolo[2,3-b]quinoxalin-2-yl)(Phenyl)methanone Dyes: Photophysical, Aie Activity, Electrochemical, and Theoretical Studies

2021 ◽  
Author(s):  
Deepali Kanekar ◽  
Sudhakar Dhanawade ◽  
Anand Jadhav ◽  
Mohmmed Ghadiyali ◽  
Sajeev Chacko ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Energy Levels ◽  
Potential Candidate ◽  
Good Thermal Stability ◽  
Td Dft ◽  
Solid Film ◽  
Donor Acceptor ◽  
Homo And Lumo ◽  
Photophysical Studies ◽  
Homo And Lumo Energy

Abstract Herein, we have synthesized four indolo[2,3-b]quinoxalin-2-yl)(phenyl)methanone derivatives 1−4 by cyclocondensation. The photophysical studies of dyes in various solvents and neat solid film exhibit typical electronic spectra with inbuilt intramolecular charge transfer (ICT) (λmax: 397‒490 nm) confirming donor-acceptor architecture. Herein, dyes fluoresce in the blue-orange region (λEmax: 435–614) on excitation at their ICT maxima in toluene, ethyl acetate, chloroform, DMSO, and neat solid film. 1 and 2 which exhibit good emission intensity in all mediums, were studied for aggregation-induced emission (AIE) effect. Electrochemical studies indicate 1−4 possess relatively low lying LUMO (‒3.65 to ‒3.98 eV) comparable to reported n-type/electron-transporting materials. The HOMO and LUMO energy levels in 1−4 were evaluated by DFT and TD-DFT calculations. TGA analysis shows 1−4 exhibit good thermal stability. The characteristic optoelectronic properties and thermal stability signify these dyes are potential candidate for their application in optoelectronics.

Energetic salts of 4-nitramino-3-(5-dinitromethyl-1,2,4-oxadiazolyl)-furazan: powerful alliance towards good thermal stability and high performance

2018 ◽  
Vol 6 (35) ◽  
pp. 16833-16837 ◽  
Author(s):  
Chunlin He ◽  
Gregory H. Imler ◽  
Damon A. Parrish ◽  
Jean'ne M. Shreeve
Keyword(s):  
Thermal Stability ◽  
High Performance ◽  
Energetic Compounds ◽  
Good Thermal Stability ◽  
Straightforward Method ◽  
Energetic Salts

A new series of 4-nitramino-3-(5-dinitromethyl-1,2,4-oxadiazolyl)-furazan-based energetic compounds which are competitive with HMX was synthesized in four steps with an overall yield of ∼50% by using a straightforward method.

A New Blue-Emitting Mg2Al4Si5O18:Ce3+ Phosphor for White Light Emitting Diodes

2016 ◽  
Vol 16 (4) ◽  
pp. 3506-3510 ◽  
Author(s):  
Jian Chen ◽  
Hongyun Ma ◽  
Yangai Liu
Keyword(s):  
Thermal Stability ◽  
White Light ◽  
Light Emitting Diodes ◽  
Broad Band ◽  
Blue Emission ◽  
Solid State Reaction Method ◽  
Light Emitting ◽  
Good Thermal Stability ◽  
Near Ultraviolet ◽  
White Light Emitting Diodes

A series of blue-emitting Mg2Al4Si5O18:Ce3+ phosphors were prepared via the conventional high temperature solid-state reaction method. The phase structure, photoluminescence (PL) properties, PL thermal stability, and fluorescence decay curves of the samples were investigated for the first time. Under excitation at 365 nm, the phosphor exhibited a broad band blue emission with peak at 440 nm, which was ascribed to the 4f → 5d transition of Ce3+, and the color coordinate was (0.1602, 0.0849). When the temperature increased to 150 °C, the luminescence intensity of the Mg2Al4Si5O18:0.06Ce3+ phosphor was 55.73% of the initial value at room temperature. The activation energy ΔE was calculated to be 0.25 eV, which proved the good thermal stability of the sample. The energy transfer critical distance between Ce3+ ions in Mg2Al4Si5O18 host were also calculated. The above results indicate that the Mg2Al4Si5O18:Ce3+ is a promising candidate as a blue-emitting near ultraviolet convertible phosphor for application in white light emitting diodes (WLEDs).

scholarly journals Ionic Liquid-Based Electrolytes for Aluminum/Magnesium/Sodium-Ion Batteries

2021 ◽  
Vol 2021 ◽  
pp. 1-29
Author(s):  
Na Zhu ◽  
Kun Zhang ◽  
Feng Wu ◽  
Ying Bai ◽  
Chuan Wu
Keyword(s):  
Ionic Liquid ◽  
High Performance ◽  
Large Scale ◽  
Low Cost ◽  
Lithium Ion ◽  
Raw Material ◽  
Side Reactions ◽  
Good Thermal Stability ◽  
Electrochemical Window ◽  
Battery Systems

Developing post-lithium-ion battery technology featured with high raw material abundance and low cost is extremely important for the large-scale energy storage applications, especially for the metal-based battery systems such as aluminum, sodium, and magnesium ion batteries. However, their developments are still in early stages, and one of the major challenges is to explore a safe and reliable electrolyte. An ionic liquid-based electrolyte is attractive and promising for developing safe and nonflammable devices with wide temperature ranges owing to their several unique properties such as ultralow volatility, high ionic conductivity, good thermal stability, low flammability, a wide electrochemical window, and tunable polarity and basicity/acidity. In this review, the recent emerging limitations and strategies of ionic liquid-based electrolytes in the above battery systems are summarized. In particular, for aluminum-ion batteries, the interfacial reaction between ionic liquid-based electrolytes and the electrode, the mechanism of aluminum storage, and the optimization of electrolyte composition are fully discussed. Moreover, the strategies to solve the problems of electrolyte corrosion and battery system side reactions are also highlighted. Finally, a general conclusion and a perspective focusing on the current development limitations and directions of ionic liquid-based electrolytes are proposed along with an outlook. In order to develop novel high-performance ionic liquid electrolytes, we need in-depth understanding and research on their fundamentals, paving the way for designing next-generation products.

scholarly journals Adsorption of nitrate onto biochar derived from agricultural residuals

2017 ◽  
Vol 77 (2) ◽  
pp. 548-554 ◽  
Author(s):  
Haihua Zhao ◽  
Yingwen Xue ◽  
Li Long ◽  
Xiaolan Hu
Keyword(s):  
Thermal Stability ◽  
Aqueous Solutions ◽  
Porous Structure ◽  
Adsorption Capacity ◽  
Adsorption Kinetics ◽  
Low Cost ◽  
Batch Adsorption ◽  
Surface Functional Groups ◽  
Good Thermal Stability ◽  
Langmuir Adsorption

Abstract To develop low-cost adsorbents for aqueous nitrate, biochars were prepared from three types of agricultural residuals at different pyrolysis temperatures (300 °C, 450 °C, and 600 °C). The corncob biochar produced at 600 °C (CC600) was the best nitrate adsorbent of all the tested biochars. Characterization results showed that CC600 had good thermal stability, porous structure, and abundant surface functional groups. Findings from batch adsorption experiments demonstrated that CC600 showed relatively fast adsorption kinetics to nitrate in aqueous solutions. In addition, the Langmuir adsorption capacity of CC600 to nitrate was 14.46 mg/g, comparable to that of other biochar-based adsorbents. Therefore, CC600 showed promising potential to be used as a low-cost adsorbent for the treatment of nitrate in water.

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