Symmetrical cyclo-N5ˉ hydrogen bonds: stabilization mechanism of four non-metallic cyclo-pentazolate energetic salts

2022 ◽  
Author(s):  
Xiang Li ◽  
Yao Long ◽  
Chong Zhang ◽  
Chengguo Sun ◽  
Bingcheng Hu ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Energetic Materials ◽  
Stabilization Mechanism ◽  
Energetic Salts

Pairing different cations (R+) to stable cyclo-N5ˉ is one main synthesize path for non-metallic cyclo-pentazolate (cyclo-N5ˉ) salts. As novel energetic materials (EMs), crystalline packing-force of cyclo-N5ˉ salts has been a...

Synthesis of high-performance insensitive energetic materials based on nitropyrazole and 1,2,4-triazole

2019 ◽  
Vol 43 (28) ◽  
pp. 11157-11163 ◽  
Author(s):  
Minxian Xu ◽  
Guangbin Cheng ◽  
Hualin Xiong ◽  
Bohan Wang ◽  
Xuehai Ju ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Energetic Materials ◽  
High Performance ◽  
Triazole Derivatives ◽  
New Family ◽  
Energetic Salts ◽  
Positive Effect

A new family of symmetric nitropyrazole and 1,2,4-triazole derivatives and its energetic salts were obtained. The positive effect of ternary hydrogen bonds improve the performances of target compounds.

scholarly journals Taming nitroformate through encapsulation with nitrogen-rich hydrogen-bonded organic frameworks

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jichuan Zhang ◽  
Yongan Feng ◽  
Richard J. Staples ◽  
Jiaheng Zhang ◽  
Jean’ne M. Shreeve
Keyword(s):  
Thermal Stability ◽  
Hydrogen Bonds ◽  
Self Assembly ◽  
Energetic Materials ◽  
Decomposition Temperature ◽  
High Oxygen Content ◽  
The Poor ◽  
Simple Preparation ◽  
First Time ◽  
Hydrogen Bonded

AbstractOwing to its simple preparation and high oxygen content, nitroformate [−C(NO2)3, NF] is an extremely attractive oxidant component for propellants and explosives. However, the poor thermostability of NF-based derivatives has been an unconquerable barrier for more than 150 years, thus hindering its application. In this study, the first example of a nitrogen-rich hydrogen-bonded organic framework (HOF-NF) is designed and constructed through self-assembly in energetic materials, in which NF anions are trapped in pores of the resulting framework via the dual force of ionic and hydrogen bonds from the strengthened framework. These factors lead to the decomposition temperature of the resulting HOF-NF moiety being 200 °C, which exceeds the challenge of thermal stability over 180 °C for the first time among NF-based compounds. A large number of NF-based compounds with high stabilities and excellent properties can be designed and synthesized on the basis of this work.

A series of energetic cyclo-pentazolate salts: rapid synthesis, characterization, and promising performance

2019 ◽  
Vol 7 (20) ◽  
pp. 12468-12479 ◽  
Author(s):  
Yuangang Xu ◽  
Lili Tian ◽  
Dongxue Li ◽  
Pengcheng Wang ◽  
Ming Lu
Keyword(s):  
Rapid Method ◽  
Energetic Materials ◽  
Next Generation ◽  
Rapid Synthesis ◽  
Energetic Salts

A family of cyclo-pentazolate anion-based energetic salts was designed and synthesized by a rapid method, and these salts were evaluated as potential next generation energetic materials.

Synthesis and Characteristics of Energetic Materials Based on 1,2-Dinitroguanidine

2014 ◽  
Vol 67 (7) ◽  
pp. 1037 ◽  
Author(s):  
Bingcheng Hu ◽  
Xinghui Jin ◽  
Huanqing Jia ◽  
Zuliang Liu ◽  
Chunxu Lv
Keyword(s):  
Mass Spectrometry ◽  
Energetic Materials ◽  
Chemical Properties ◽  
Detonation Properties ◽  
Physical And Chemical Properties ◽  
Scanning Calorimetry ◽  
Energetic Salts ◽  
Thermal Kinetic Parameters ◽  
Physical And Chemical ◽  
And Chemical Properties

A series of energetic salts based on 1,2-dinitroguanidine were successfully synthesised and fully characterised using 1H NMR, 13C NMR, and IR spectroscopy, mass spectrometry, elemental analysis, and differential scanning calorimetry. The results show that all the salts possess higher detonation properties (detonation pressures and velocities ranging from 24.8 to 30.3 GPa and 7665 to 8422 m s–1, respectively) than those of trinitrotolouene (TNT, 2,4,6-trinitromethylbenzene). The thermal stability and thermal kinetic parameters were also investigated to give a better understanding of the physical and chemical properties of these energetic salts.

1,2,4,5-Dioxadiazine-functionalized [N–NO2]− furazan energetic salts

2016 ◽  
Vol 45 (39) ◽  
pp. 15382-15389 ◽  
Author(s):  
Haifeng Huang ◽  
Yameng Shi ◽  
Yanfang Liu ◽  
Jun Yang
Keyword(s):  
Energetic Materials ◽  
Detonation Performance ◽  
Energetic Salts

1,2,4,5-Dioxadiazine is identified as a key bridge to improve the density and detonation performance of energetic materials.

scholarly journals Synthetic and thermal studies of four insensitive energetic materials based on oxidation of the melamine structure

RSC Advances ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 288-295
Author(s):  
Jiarong Zhang ◽  
Fuqiang Bi ◽  
Junlin Zhang ◽  
Xiaohong Wang ◽  
Zhi Yang ◽  
...  
Keyword(s):  
Thermal Behavior ◽  
Energetic Materials ◽  
Thermal Studies ◽  
Detonation Performance ◽  
Energetic Salts

The synthesis, thermal behavior and detonation performance of MDO and its monoanionic energetic salts were comprehensively studied.

Synthesis of nitrogen-rich and thermostable energetic materials based on hetarenecarboxylic acids

2021 ◽  
Author(s):  
Caijin Lei ◽  
Hongwei Yang ◽  
Qinghua Zhang ◽  
Guangbin Cheng
Keyword(s):  
Energetic Materials ◽  
Neutral Compounds ◽  
Energetic Salts ◽  
New Compounds

Two series of both nitrogen-rich and thermostable energetic materials as well as their energetic salts based on hetarenecarboxylic acids are now described. Among these new compounds, the neutral compounds 3...

scholarly journals Can the sensitivity of energetic materials be tuned by using hydrogen bonds? Another look at the role of hydrogen bonding in the design of high energetic compounds.

2021 ◽  
Author(s):  
Danijela S. Kretić ◽  
Jelena I. Radovanović ◽  
Dušan Ž Veljković
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Electrostatic Potential ◽  
Energetic Materials ◽  
Energetic Compounds ◽  
Positive Electrostatic Potential

Strongly positive electrostatic potential in the central areas of molecules of the energetic materials is one of the most important factors that determine the sensitivity of these molecules towards detonation....

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