Defect-related luminescence behavior of a Mn4+ non-equivalently doped fluoroantimonate red phosphor

2021 ◽  
Author(s):  
Tingting Deng ◽  
Shuai Zhang ◽  
Rongfu Zhou ◽  
Ting Yu ◽  
M. Wu ◽  
...  
Keyword(s):  
Fluorescence Lifetime ◽  
Structural Defect ◽  
Red Phosphor ◽  
Red Phosphors ◽  
Octahedral Substitution ◽  
Luminescence Behavior

Constructing non-equivalent or non-octahedral substitution is a crucial strategy to gain Mn4+-doped fluoride red phosphors with short fluorescence lifetime, whereas their structural defect impact on photoluminescence (PL) property remains unrevealed....

Mn4+ doped narrowband red phosphors with short fluorescence lifetime and high color stability for fast-response backlight display application

2021 ◽  
Vol 855 ◽  
pp. 157347
Author(s):  
Yuanjing Wang ◽  
Changkai Yu ◽  
Yayun Zhou ◽  
Enhai Song ◽  
Hong Ming ◽  
...  
Keyword(s):  
Fluorescence Lifetime ◽  
Color Stability ◽  
Fast Response ◽  
Red Phosphors

Novel polygonal structure Mn4+ activated In3+-based Elpasolite-type hexafluorides red phosphor for warm white light-emitting diodes (WLEDs)

2019 ◽  
Vol 48 (4) ◽  
pp. 1376-1385 ◽  
Author(s):  
Feng Hong ◽  
Haiming Cheng ◽  
Chao Song ◽  
Guixia Liu ◽  
Wensheng Yu ◽  
...  
Keyword(s):  
White Light ◽  
Light Emitting Diodes ◽  
Synthetic Methods ◽  
Red Phosphor ◽  
Light Emitting ◽  
White Leds ◽  
Red Phosphors ◽  
Polygonal Structure ◽  
Warm White Light ◽  
White Light Emitting Diodes

Red phosphors (NH4)2NaInF6:Mn4+ with controllable morphology were synthesized via different synthetic methods, which can be fabricated for warm white LEDs.

Synthesis and Photoluminescence Properties of Sc0.88-xLu0.05VO4:Eu3+0.07,Bi3+x Red Phosphor

2017 ◽  
Vol 727 ◽  
pp. 604-611
Author(s):  
Di Wu ◽  
Xin Yu Ye ◽  
Xin Hua Yang ◽  
Jian Zhou ◽  
Xiao Qiang Wen ◽  
...  
Keyword(s):  
Quantum Efficiency ◽  
Emission Intensity ◽  
Doping Concentration ◽  
Internal Quantum Efficiency ◽  
The Body ◽  
Luminescence Spectra ◽  
Intensity Increase ◽  
X Ray Diffraction ◽  
Red Phosphor ◽  
Red Phosphors

Sc0.88-xLu0.05VO4:Eu3+0.07,Bi3+x(0≤x≤0.05) red phosphors were synthesized by solid state reaction at 1200°C for 3h. The structure, morphology and luminescence spectra of samples are investigated by X-ray diffraction (XRD), Scanning electron microscope (SEM) and fluorescence spectrophotometer, respectively. The samples doped with Eu3+, Lu3+ and Bi3+ maintain the body-centered tetragonal structure of ScVO4 and the morphology remains essentially unchanged with slight agglomeration. The excitation spectrum of Sc0.88-xLu0.05VO4:Eu3+0.07,Bi3+x emerged redshift and the excitation intensity increase within the near UV excitation (360-400nm). The optimum doping concentration of Bi3+ is 0.02(x value), and the maximum emission intensity of Sc0.86Lu0.05VO4:Eu3+0.07,Bi3+0.02 is higher than 88 % in comparison with Sc0.88Lu0.05VO4:Eu3+0.07 under 365 nm excitation. Decay curve of 5D0 state for as-prepared samples fits the single order exponential behavior, the lifetime of 5D0 increase first and then decrease with the increase of Bi3+ doping concentration. The internal quantum efficiency is up to 74.08% under 365nm excitation; When the temperature raises to 200°C, the emission intensity maintains 79% of that in the room temperature. Sc0.86Lu0.05VO4:Eu3+0.07,Bi3+0.02 phosphor show high internal quantum efficiency and thermal stability, which is suitable for the UV-pumped white LED as red phosphor.

The dual charge compensation effect of Na+ ions on the luminescence behavior of red phosphor NaMgPO4:Eu3+

2015 ◽  
Vol 160 ◽  
pp. 436-439 ◽  
Author(s):  
Qiwei Long ◽  
Yong Gao ◽  
Yingheng Huang ◽  
Sen Liao ◽  
Baoling Song ◽  
...  
Keyword(s):  
Compensation Effect ◽  
Charge Compensation ◽  
Red Phosphor ◽  
Na Ions ◽  
Luminescence Behavior

A red phosphor BaTiF6:Mn4+: reaction mechanism, microstructures, optical properties, and applications for white LEDs

2014 ◽  
Vol 43 (25) ◽  
pp. 9414-9418 ◽  
Author(s):  
Xianyu Jiang ◽  
Zhen Chen ◽  
Shaoming Huang ◽  
Jiaguo Wang ◽  
Yuexiao Pan
Keyword(s):  
Optical Properties ◽  
Reaction Mechanism ◽  
White Light ◽  
Red Phosphor ◽  
White Leds ◽  
Red Phosphors ◽  
Warm White Light ◽  
Color Rendering Index ◽  
Color Rendering

Red phosphors BaTiF6:Mn4+ were obtained by etching Ti(OC4H9)4 and TiO2 with BaF2 in HF and a KMnO4 solution. The WLED fabricated with BaTiF6:Mn4+ exhibits a “warm” white light with a color rendering index of 93.13.

A novel orange-red phosphor Ca3B2O6:Sm3+, A+(A = Li, Na, K) for white light emitting diodes

2014 ◽  
Vol 07 (03) ◽  
pp. 1450033 ◽  
Author(s):  
Qingbo Liu ◽  
Yufeng Liu ◽  
Fu Yang ◽  
Bing Han ◽  
Hao Feng ◽  
...  
Keyword(s):  
Emission Spectrum ◽  
Integral Intensity ◽  
Red Light ◽  
Red Phosphor ◽  
Light Emitting ◽  
Red Phosphors ◽  
Near Ultraviolet ◽  
Bright Orange ◽  
Cie Chromaticity ◽  
White Light Emitting Diodes

A novel orange-red phosphor Ca 3 B 2 O 6: Sm 3+, A+( A = Li , Na , K ) has been synthesized by solid-state reaction at 950°C. The phase purity and photoluminescence (PL) behavior of the phosphor are studied in detail using the powder X-ray diffraction (XRD) technique and PL measurements. Ca 3 B 2 O 6: Sm 3+ phosphor can be efficiently excited by near ultraviolet (n-UV) and blue light, and the emission spectrum consists of four emission peaks at 563, 599, 646 and 709 nm, generating bright orange-red light. When a cation A+ is introduced into Ca 3 B 2 O 6: Sm 3+ as charge compensator, the emission intensity of Ca 3 B 2 O 6: Sm 3+ is evidently enhanced, but the PL spectral profile is unchanged. The integral intensity of the emission spectrum of Ca 2.96 Sm 0.02 Na 0.02 B 2 O 6 excited at 401 nm is about 1.2 times than that of Y 2 O 2 S : Eu 3+ commercial red phosphor. The CIE chromaticity coordinates of Ca 2.96 Sm 0.02 Na 0.02 B 2 O 6 phosphor were (0.608, 0.365), which are close to that of the commercial red phosphors Y 2 O 3: Eu 3+ (0.655, 0.345), Y 2 O 2 S : Eu 3+ (0.622, 0.351) and Sr 2 Si 5 N 8: Eu 2+ (0.620, 0.370).

Optimized photoluminescence of red phosphor K2TiF6:Mn4+synthesized at room temperature and its formation mechanism

2015 ◽  
Vol 3 (9) ◽  
pp. 1935-1941 ◽  
Author(s):  
Lifen Lv ◽  
Zhen Chen ◽  
Guokui Liu ◽  
Shaoming Huang ◽  
Yuexiao Pan
Keyword(s):  
Formation Mechanism ◽  
Luminescence Intensity ◽  
Room Temperature ◽  
Synthetic Process ◽  
Red Phosphor ◽  
White Leds ◽  
Red Phosphors ◽  
Color Rendering

The formation mechanism for red phosphors K2TiF6:Mn4+synthesized at room temperature has been discussed. The luminescence intensity has been improved by optimizing the synthetic process. Encapsulation of the red phosphor K2TiF6:Mn4+with YAG:Ce on a GaN layer produces “warm” white LEDs with color rendering 86 at 3251 K.

A novel inequivalent double-site substituted red phosphor Li4AlSbO6:Mn4+ with high color purity: Structure, photoluminescence properties, and application in warm white LEDs

2021 ◽  
Author(s):  
Zhiyuan Li ◽  
Xuhui Zhang ◽  
Ji Wu ◽  
Rui Guo ◽  
Lan Luo ◽  
...  
Keyword(s):  
Rare Earth ◽  
Spectral Properties ◽  
Light Emitting Diode ◽  
Color Purity ◽  
Photoluminescence Properties ◽  
Red Phosphor ◽  
Light Emitting ◽  
White Leds ◽  
Red Phosphors ◽  
High Color Purity

Non-rare-earth Mn4+-doped oxide red phosphors received increasing attention in the white light-emitting diode (LED) field for their admirable chemical stability and spectral properties. Here, a new inequivalent double-site substituted Mn4+-doped...

Hydrothermal Synthesis and Size-Enhanced Chromaticity of Sr2ZnSi2O7:Eu3+ Nanoparticles

2008 ◽  
Vol 8 (3) ◽  
pp. 1449-1453 ◽  
Author(s):  
Junxi Wan ◽  
Youwei Yao ◽  
Guoyi Tang ◽  
Yitai Qian
Keyword(s):  
Bulk Material ◽  
Emission Spectra ◽  
Luminescent Properties ◽  
Blue Shift ◽  
Average Diameter ◽  
Hydrothermal Route ◽  
Excitation Spectra ◽  
Red Phosphor ◽  
Red Phosphors ◽  
20 Nm

Red phosphor Sr2ZnSi2O7:Eu3+ nanoparticles with an average diameter of 20 nm were successfully synthesized via a low-temperature hydrothermal route in order to understand the underlying relationship between size and luminescent properties. The nanometer-sized particles result in a distinct improvement in chromaticity and a high quenching concentration. According to emission spectra, the relative intensity of the 5D0 → 7F2 to 5D0 → 7F1 transitions in nanometer-sized phosphors is higher than that of the corresponding bulk material. The better chromaticity results from the more distorted lattices and relatively lower crystal symmetry around the Eu3+ ions, which is ascribed to the large surface area due to the nanometer size of the phosphor. Moreover, the nanometer-sized Sr2ZnSi2O7:Eu3+ red phosphor exhibits a shorter fluorescent lifetime and a blue-shift in excitation spectra compared to that of its bulk counterpart. These results indicate that size-induced enhancement of luminescent properties is an efficient way to obtain red phosphors with better chromaticity.

The Effect of Charge Compensation on the Luminescence Behavior of Eu3+-Doped Perovskite CaZrO3 Red Phosphor

2018 ◽  
Vol 10 (5) ◽  
pp. 703-708 ◽  
Author(s):  
Yeon Woo Seo ◽  
Byung Kee Moon ◽  
Sung Heum Park ◽  
Jung Hyun Jeong ◽  
Kwang Ho Kim
Keyword(s):  
Charge Compensation ◽  
Red Phosphor ◽  
Luminescence Behavior
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