Janus silver/ternary silver halide nanostructures as plasmonic photocatalysts boost the conversion of CO2 to acetaldehyde

Nanoscale ◽  
2021 ◽  
Author(s):  
Henglei Jia ◽  
Yanrong Dou ◽  
Yuanyuan Yang ◽  
Fan Li ◽  
Chun-Yang Zhang
Keyword(s):  
Carbon Dioxide ◽  
Silver Halide ◽  
Liquid Product ◽  
Reduction Process ◽  
Coupling Reaction ◽  
Electron Reduction ◽  
Carbon Dioxide Co2

Photocatalytic conversion of carbon dioxide (CO2) to liquid product acetaldehyde (CH3CHO) remains a great challenge due to the involvement of complex 10-electron reduction process and sluggish C–C coupling reaction. Herein,...

scholarly journals A Binuclear Cobalt Complex for Molecular CO2 Electrocatalysis

2021 ◽  
Author(s):  
Antoine Bohn ◽  
Juan José Moreno ◽  
Pierre Thuéry ◽  
Marc Robert ◽  
Orestes Rivada Wheelaghan
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Saturated Calomel Electrode ◽  
Cobalt Complex ◽  
Reduction Process ◽  
Inert Atmosphere ◽  
Electrochemical Studies ◽  
Electron Reduction ◽  
Carbon Dioxide Co2 ◽  
Reduction Of Co2

A pyrazole–based ligand substituted with terpyridine groups at the 3 and 5positions has been synthesized to form the dinuclear cobalt complex 1, that electrocatalytically reduces carbon dioxide (CO2) to carbon monoxide (CO) in the presence of Brønsted acids in DMF. Chemical, electrochemical and UV–vis spectro–electrochemical studies under inert atmosphere indicate a single 2 electron reduction process of complex 1 at first, followed by a 1 electron reduction at the ligand. Infrared spectro–electrochemical studies under CO2 and CO atmosphere allowed us to identify a reduced CO–containing dicobalt complex which results from the electroreduction of CO2. In the presence of trifluoroethanol (TFE), electrocatalytic studies revealed single–site mechanism with up to 94 % selectivity towards CO formation when 1.47 M TFE were present, at –1.35 V vs Saturated Calomel Electrode in DMF (0.39 V overpotential). The low faradaic efficiencies obtained (<50%) are attributed to the generation of CO–containing species formed during the electrocatalytic process, which inhibit the reduction of CO2.

scholarly journals Transforming Plastic Waste into Porous Carbon for Capturing Carbon Dioxide: A Review

Energies ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 8421
Author(s):  
Farihahusnah Hussin ◽  
Mohamed Kheireddine Aroua ◽  
Mohd Azlan Kassim ◽  
Umi Fazara Md. Ali
Keyword(s):  
Carbon Dioxide ◽  
Liquid Product ◽  
Plastic Waste ◽  
Future Perspective ◽  
Waste Generation ◽  
Pyrolysis Products ◽  
Plastic Wastes ◽  
Negative Impacts ◽  
Indiscriminate Disposal ◽  
Carbon Dioxide Co2

Plastic waste generation has increased dramatically every day. Indiscriminate disposal of plastic wastes can lead to several negative impacts on the environment, such as a significant increase in greenhouse gas emissions and water pollution. Therefore, it is wise to think of other alternatives to reduce plastic wastes without affecting the environment, including converting them into valuable products using effective methods such as pyrolysis. Products from the pyrolysis process encompassing of liquid, gas, and solid residues (char) can be turned into beneficial products, as the liquid product can be used as a commercial fuel and char can function as an excellent adsorbent. The char produced from plastic wastes could be modified to enhance carbon dioxide (CO2) adsorption performance. Therefore, this review attempts to compile relevant knowledge on the potential of adsorbents derived from waste plastic to capture CO2. This review was performed in accordance with PRISMA guidelines. The plastic-waste-derived activated carbon, as an adsorbent, could provide a promising method to solve the two environmental issues (CO2 emission and solid management) simultaneously. In addition, the future perspective on char derived from waste plastics is highlighted.

Photochemical hydrogen production based on HCOOH/CO2 cycle promoted by pentanuclear cobalt complex

2022 ◽  
Author(s):  
Takuya Akai ◽  
Mio Kondo ◽  
Yutaka Saga ◽  
Shigeyuki Masaoka
Keyword(s):  
Carbon Dioxide ◽  
Hydrogen Production ◽  
Formic Acid ◽  
Ambient Temperature ◽  
Cobalt Complex ◽  
Catalytic Cycle ◽  
Electron Reduction ◽  
Carbon Dioxide Co2

The first catalytic cycle for hydrogen production based on the photochemical two-electron reduction of carbon dioxide (CO2) and the dehydrogenation of formic acid at ambient temperature was demonstrated using a...

scholarly journals Understanding the Photo- and Electro-Carboxylation of o-Methylbenzophenone with Carbon Dioxide

Catalysts ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 664
Author(s):  
Keyi Tian ◽  
Ruonan Chen ◽  
Jiafang Xu ◽  
Ge Yang ◽  
Xintong Xu ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Density Functional ◽  
Radical Reaction ◽  
Diels Alder ◽  
Synthesis Methods ◽  
One Pot ◽  
Polycarboxylic Acids ◽  
Electro Catalysis ◽  
Electron Reduction ◽  
Carbon Dioxide Co2

The lack of understanding of the radical reaction mechanism of Carbon dioxide (CO2) in photo- and electro-catalysis results in the development of such applications far behind the traditional synthesis methods. Using methylbenzophenone as the model, we clarify and compare the photo-enolization/Diels−Alder (PEDA) mechanism for photo-carboxylation and the two-step single-electron reduction pathway for electro-carboxylation with CO2 through careful control experiments. The regioselective carboxylation products, o-acylphenylacetic acid and α-hydroxycarboxylic acid are obtained, respectively, in photo- and electro-chemistry systems. On the basis of understanding the mechanism, a one-pot step-by-step dicarboxylation of o-methylbenzophenone is designed and conducted. Both the experimental results and related density functional theory (DFT) calculation verify the feasibility of the possible pathway in which electro-carboxylation is conducted right after photo-carboxylation in one vessel. This synthesis approach may provide a mild, eco-friendly strategy for the production of polycarboxylic acids in industry.

PERANCANGAN PROTEKSI KEBAKARAN OTOMATIS PADA KAPAL BERBASIS ARDUINO

2018 ◽  
Vol 1 (2) ◽  
pp. 1-8
Author(s):  
Dody Hidayat
Keyword(s):  
Carbon Dioxide ◽  
Fire Extinguisher ◽  
Carbon Dioxide Co2

Kebakaran dapat terjadi dimana saja salah satunya dapat terjadi di alat transportasi air yakni kapal. Kebakaran selalu menyebabkan hal-hal yang tidak diinginkan baik kerugian material maupun ancaman keselamatan jiwa manusia. Seiring dari kejadian tersebut musibah kecelakaan kapal yang disebabkan oleh bahaya kebakaran sangatlah mungkin terjadi. Salah satu yang dapat mencegah kejadian kebakaran pada kapal haruslah dapat mendeteksi dini kebakaran tersebut. Untuk mendeteksi dini terjadinya kebakaran dikapal maka dirancanglah sebuah alat proteksi kebakaran otomatisberbasis adruino. Dimana Arduino merupakan board yang memiliki sebuah mikrokontroller sebagai  otak kendali sistem. Sistem otomatisasi atau controller tidak akan terlepas dengan apa yang disebut  dengan ‘sensor’. Sensor adalah sebuah alat untuk mendeteksi atau mengukut sesuatu yang digunakan untuk mengubah variasi mekanis, magnetis, panas, sinar dan kimia menjadi tegangan dan arus listrik. sistem yang dirancang ini dilengkapi dengan beberapa sensor diantaranya adalah sensor apiUV-Tron R2868, sensor asap MQ-2 dan kemudian sensor suhuDS18B20. Mikrokontroller sebagai pengendali akan merespon input yang berupa sensor tersebut ketika data yang dibaca oleh sensor mendeteksikebakaran diantaranya mendeteksi adanya asap, kemudian api dan suhu. Sebagai output dari sistem berupa racun api (fire extinguisher)dimana kandungan yang ada pada racun api tersebut berupa Dry Chemical Powder dan Carbon Dioxide (CO2) yang fungsinya digunakan untuk memadamkan api serta dilengkapi buzzer sebagai alarm peringatan jika terjadi kebakaran. 

The Prenatal Development Effects of Carbon Dioxide (CO2) Exposure in Rats (Rattus Norvegicus)

2012 ◽  
Author(s):  
William R. Howard ◽  
Brian Wong ◽  
Michelle Okolica ◽  
Kimberly S. Bynum ◽  
R. A. James
Keyword(s):  
Carbon Dioxide ◽  
Rattus Norvegicus ◽  
Prenatal Development ◽  
Carbon Dioxide Co2

Physiology of Intraluminal Administration of Carbon Dioxide as a Contrast Medium

2020 ◽  
Vol 25 (44) ◽  
pp. 4656-4661 ◽  
Author(s):  
Nikolaos Patelis ◽  
Mikes Doulaptsis ◽  
Stylianos Kykalos ◽  
Eleftherios Spartalis ◽  
Anastasios Maskanakis ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Contrast Agent ◽  
20Th Century ◽  
English Literature ◽  
Human Organism ◽  
Digital Subtraction ◽  
Extensive Search ◽  
Iodinated Contrast ◽  
Iodinated Contrast Agent ◽  
Carbon Dioxide Co2

Background: Carbon dioxide (CO2) exists in nature around us. In the middle of the 20th century, the intraluminal injection of CO2 demonstrated similar results to those of Digital Subtraction Angiography (DSA) with an iodinated contrast agent (ICA). Since then, the technology behind CO2 DSA has developed significantly. Objective: The aim of this study is to inform physicians about the unique properties of CO2 and its physiology after intraluminal injection. Methods: An extensive search for English literature on the properties of CO2 and the physiology of intraluminal administration was conducted using Pubmed. Results: There is sufficient literature on the properties of CO2 and the physiology of CO2 DSA. A review of this literature explains what happens to the human organism after the injection of CO2. Conclusions: There is enough evidence that CO2 DSA is both effective, diagnostic and safe, but the properties of CO2 should be taken under consideration as complications occur, although rarely.

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