scholarly journals Fast 3D-lithium-ion diffusion and high electronic conductivity of Li2MnSiO4 surfaces for rechargeable lithium-ion batteries

RSC Advances ◽  
2021 ◽  
Vol 11 (16) ◽  
pp. 9721-9730
Author(s):  
Gamachis Sakata Gurmesa ◽  
Natei Ermias Benti ◽  
Mesfin Diro Chaka ◽  
Girum Ayalneh Tiruye ◽  
Qinfang Zhang ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Low Cost ◽  
Electronic Conductivity ◽  
Lithium Ion ◽  
Ion Diffusion ◽  
High Electronic Conductivity ◽  
Lithium Ion Diffusion ◽  
The Way

The DFT analysis revealed fast 3D-lithium-ion diffusion pathways and high electronic conductivity in the Li2MnSiO4 surface, and thus paving the way for designing and developing efficient and low-cost rechargeable lithium-ion batteries.

An electrolyte-phobic carbon nanotube current collector for high-voltage foldable lithium-ion batteries

2020 ◽  
Vol 8 (37) ◽  
pp. 19444-19453 ◽  
Author(s):  
Ke Wen Mu ◽  
Kai Xi Liu ◽  
Zhi Yong Wang ◽  
Shahid Zanman ◽  
Yan Hong Yin ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Lithium Ion Batteries ◽  
High Voltage ◽  
Lithium Ion ◽  
Current Collector ◽  
Ion Diffusion ◽  
Interface Modification ◽  
Lithium Ion Diffusion

Surface/interface modification is developed to tune the electrolyte wettability of a carbon nanotube current collector for controlling the lithium ion diffusion and achieving high voltage foldable lithium-ion batteries.

scholarly journals Novel synthesis and electrochemical investigations of ZnO/C composites for lithium-ion batteries

2021 ◽  
Author(s):  
E. Thauer ◽  
G. S. Zakharova ◽  
E. I. Andreikov ◽  
V. Adam ◽  
S. A. Wegener ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Electronic Conductivity ◽  
Lithium Ion ◽  
Nitrogen Atmosphere ◽  
Ex Situ ◽  
Ion Diffusion ◽  
Storage Mechanism ◽  
Treatment Conditions ◽  
One Step ◽  
First Time

AbstractFor the first time, ZnO/C composites were synthesized using zinc glycerolate as a precursor through one-step calcination under a nitrogen atmosphere. The effect of the heat treatment conditions on the structure, composition, morphology as well as on the electrochemical properties regarding application in lithium-ion batteries are investigated. The products obtained by calcination of the precursor in nitrogen at 400—800 °C consist of zinc oxide nanoparticles and amorphous carbon that is in-situ generated from organic components of the glycerolate precursor. When used as anode material for lithium-ion batteries, the as-prepared ZnO/C composite synthesized at a calcination temperature of 700 °C delivers initial discharge and charge capacities of 1061 and 671 mAh g−1 at a current rate of 100 mA g−1 and hence 1.5 times more than bare ZnO, which reaches only 749/439 mAh g−1. The native carbon improves the conductivity, allowing efficient electronic conductivity and Li-ion diffusion. By means of ex-situ XRD studies a two-step storage mechanism is proven.

scholarly journals Lithia-Based Nanocomposites Activated by Li2RuO3 for New Cathode Materials Rooted in the Oxygen Redox Reaction

2019 ◽  
Vol 14 (1) ◽  
Author(s):  
Byeong Gwan Lee ◽  
Yong Joon Park
Keyword(s):  
Lithium Ion Batteries ◽  
Cathode Materials ◽  
Redox Reaction ◽  
Electronic Conductivity ◽  
High Capacity ◽  
Lithium Ion ◽  
Xps Analysis ◽  
Cyclic Performance ◽  
Capacity Limit ◽  
High Electronic Conductivity

AbstractLithia-based materials are promising cathodes based on an anionic (oxygen) redox reaction for lithium ion batteries due to their high capacity and stable cyclic performance. In this study, the properties of a lithia-based cathode activated by Li2RuO3 were characterized. Ru-based oxides are expected to act as good catalysts because they can play a role in stabilizing the anion redox reaction. Their high electronic conductivity is also attractive because it can compensate for the low conductivity of lithia. The lithia/Li2RuO3 nanocomposites show stable cyclic performance until a capacity limit of 500 mAh g−1 is reached, which is below the theoretical capacity (897 mAh g−1) but superior to other lithia-based cathodes. In the XPS analysis, while the Ru 3d peaks in the spectra barely changed, peroxo-like (O2)n− species reversibly formed and dissociated during cycling. This clearly confirms that the capacity of the lithia/Li2RuO3 nanocomposites can mostly be attributed to the anionic (oxygen) redox reaction.

Ti3C2Tx-Based Electrodes with Enhanced Pseudocapacitance for High-Performance Lithium-ion Batteries

NANO ◽  
2020 ◽  
Vol 15 (04) ◽  
pp. 2050051
Author(s):  
Rudong Zheng ◽  
Lili Wu ◽  
Jiabao Zhao ◽  
Chuncheng Zhu ◽  
Hong Gao
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Kinetic Mechanism ◽  
Ion Diffusion ◽  
Two Samples ◽  
New Type ◽  
Current Densities ◽  
Lithium Ion Diffusion

Ti3C2Tx, a new type of two-dimensional material, is a prospective anode material in lithium-ion batteries (LIBs) for its low lithium-ion diffusion barrier, high conductivity and many other excellent properties. In this paper, multilayer Ti3C2Tx and delaminated Ti3C2Tx samples are prepared by etching Ti3AlC2 powder with HF and [Formula: see text], respectively. We explore the application of the two samples in LIBs, and analyze their electrochemical behavior and kinetic mechanism. At the current densities of 0.1[Formula: see text]A[Formula: see text]g[Formula: see text], the delaminated Ti3C2Tx electrode delivered higher capacities of 255[Formula: see text]mAh[Formula: see text]g[Formula: see text] than multilayer Ti3C2Tx electrode (100[Formula: see text]mAh[Formula: see text]g[Formula: see text]). Even after 1000 cycles, the specific capacity of the delaminated Ti3C2Tx is still up to 205[Formula: see text]mAh[Formula: see text]g[Formula: see text] at 1[Formula: see text]A[Formula: see text]g[Formula: see text]. This work proves the great potential of the delaminated Ti3C2Tx for lithium-ion storage.

The Effect of Sintering Temperature on Electronic Conductivity of LiFeGdPO4/C as a Lithium-Ion Battery Cathode

2021 ◽  
Vol 1028 ◽  
pp. 138-143
Author(s):  
Iman Rahayu ◽  
Anggi Suprabawati ◽  
Vina M. Puspitasari ◽  
Sahrul Hidayat ◽  
Atiek Rostika Noviyanti
Keyword(s):  
Lithium Ion Battery ◽  
Reduction Method ◽  
Sintering Temperature ◽  
Electronic Conductivity ◽  
Lithium Ion ◽  
Particle Growth ◽  
Ion Diffusion ◽  
A Value ◽  
High Theoretical Capacity ◽  
Lithium Ion Diffusion

Lithium ion batteries with LiFePO4 cathode have become the focus of research because they are eco-friendly, stable, high average voltage (3.5 V), and high theoretical capacity (170 mAh/g). However, LiFePO4 has disadvantages such as low electrical conductivity (~10-9 S/cm) and low lithium ion diffusion coefficient (~10-14-10-15 cm2/s) that can inhibit its application as a lithium ion battery cathode material. To increase the electronic conductivity of LiFePO4, it can be done by adding carbon as a coating material, then doping gadolinium metal ions because it has a radius similar to Fe, and increasing sintering temperature. Optimizing the sintering temperature can control particle growth and research was study the sintering temperature of the electronic conductivity of LiFeGdPO4/C and obtain the optimum sintering temperature at LiFeGdPO4/C. The carbothermal reduction method used in synthesis, with a variation of sintering temperature of 800°C, 830°C, 850°C, 870°C, and 900°C using reagents LiH2PO4, Fe2O3, Gd2O3, and carbon black. Furthermore the samples were characterized using XRD, SEM-EDS, and four-point probes. The results of the study were expected to increase the conductivity of LiFePO4. The results show the effect of sintering temperature can increase the electronic conductivity of LiFeGdPO4/C. Samples with a sintering temperature 850°C have the highest conductivity among all temperature variations with a value of 1.11 × 10-5 S cm-1.

A kinetic model for diffusion and chemical reaction of silicon anode lithiation in lithium ion batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (27) ◽  
pp. 22383-22388 ◽  
Author(s):  
Zhoucan Xie ◽  
Zengsheng Ma ◽  
Yan Wang ◽  
Yichun Zhou ◽  
Chunsheng Lu
Keyword(s):  
Kinetic Model ◽  
Lithium Ion Batteries ◽  
Chemical Reaction ◽  
Crystalline Silicon ◽  
Lithium Ion ◽  
Silicon Anode ◽  
Ion Diffusion ◽  
Lithium Ion Diffusion

In this paper, a kinetic model is proposed that combines lithium ion diffusion through a lithiated phase with chemical reaction at the interface between lithiated amorphous and crystalline silicon.

scholarly journals Li2SnO3 as a Cathode Material for Lithium-ion Batteries: Defects, Lithium Ion Diffusion and Dopants

2018 ◽  
Vol 8 (1) ◽  
Author(s):  
Navaratnarajah Kuganathan ◽  
Apostolos Kordatos ◽  
Alexander Chroneos
Keyword(s):  
Cathode Material ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Ion Diffusion ◽  
Lithium Ion Diffusion

scholarly journals Synthesis of Ni@NiSn Composite with High Lithium‐Ion Diffusion Coefficient for Fast‐Charging Lithium‐Ion Batteries

2019 ◽  
Vol 4 (3) ◽  
pp. 1900073 ◽  
Author(s):  
Hong Zhao ◽  
Junxin Chen ◽  
Weiwei Wei ◽  
Shanming Ke ◽  
Xierong Zeng ◽  
...  
Keyword(s):  
Diffusion Coefficient ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Ion Diffusion ◽  
Fast Charging ◽  
Lithium Ion Diffusion
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