scholarly journals Donor–acceptor–acceptor-type near-infrared fluorophores that contain dithienophosphole oxide and boryl groups: Effect of the boryl group on the nonradiative decay

2021 ◽  
Author(s):  
Yoshiaki Sugihara ◽  
Naoto Inai ◽  
Masayasu Taki ◽  
Thomas Baumgartner ◽  
Ryosuke Kawakami ◽  
...  

he use of donor–π–acceptor (D–π–A) skeletons is an effective strategy for the design of fluorophores with red-shifted emission. In particular, the use of amino and boryl moieties as the electron-donating...

2017 ◽  
Vol 5 (46) ◽  
pp. 12163-12171 ◽  
Author(s):  
Yinghui He ◽  
Jesse T. E. Quinn ◽  
Dongliang Hou ◽  
Jenner H.L. Ngai ◽  
Yuning Li

A novel small bandgap donor–acceptor polymer with a very small band gap of 0.95 eV shows promising photoresponse under near infrared light in phototransistors.


2018 ◽  
Vol 6 (6) ◽  
pp. 1407-1412 ◽  
Author(s):  
Yun Hu ◽  
Yi Yuan ◽  
Ying-Li Shi ◽  
Jiu-Dong Lin ◽  
Zuo-Quan Jiang ◽  
...  

A maximum EQE of 2.7% with an emission peak of 735 nm was achieved by employing a donor–acceptor type host 5-(4-(diphenylamino)phenyl)acenaphthylene-1,2-dione (ADO-TPA).


2020 ◽  
Vol 142 (27) ◽  
pp. 11857-11864 ◽  
Author(s):  
Kristin Klaue ◽  
Wenjie Han ◽  
Pauline Liesfeld ◽  
Fabian Berger ◽  
Yves Garmshausen ◽  
...  

2018 ◽  
Vol 42 (10) ◽  
pp. 531-534 ◽  
Author(s):  
Yangyang Wang ◽  
Mengna Li ◽  
Yufei Song ◽  
Ming Qin ◽  
Xuehui Li ◽  
...  

Two novel donor–π–acceptor-type dithienylethene derivatives, in which the triphenylamine group acts as electron donor and the formyl group functions as electron acceptor, have been developed. Their structures were confirmed by 1H NMR, 13C NMR and HRMS (ESI). Investigation of their photochromic properties indicated that they had good photochromic behaviour and excellent fatigue resistance on irradiation with UV or visible light. DFT calculations further validated these experimental results for photochromic behaviour. Moreover, these compounds can be utilised as versatile building blocks to construct novel near-infrared photochromic materials.


2020 ◽  
Vol 7 (18) ◽  
pp. 3752-3760
Author(s):  
Nicholas E. Sparks ◽  
Tharindu A. Ranathunge ◽  
Nuwan H. Attanayake ◽  
Phillip Brodgon ◽  
Jared H. Delcamp ◽  
...  

Crystals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 269 ◽  
Author(s):  
Rosita Diana ◽  
Ugo Caruso ◽  
Luigi Di Costanzo ◽  
Gelsomina Bakayoko ◽  
Barbara Panunzi

We developed a new benzodifuran derivative as the condensation product between 2,6-diamino-4-(4-nitrophenyl)benzo[1,2-b:4,5-b’]difuran-3,7-dicarboxylate and 3-hydroxy-2-naphthaldehyde. The intramolecular hydrogen-bond interactions in the terminal half-salen moieties produce a sterically encumbered highly conjugated main plane and a D-A-D (donor-acceptor-donor) T-shaped structure. The novel AIEgen (aggregation-induced enhanced emission generator) fulfils the requirement of RIR (restriction of intramolecular rotation) molecules. DR/NIR (deep red/near infrared) emission was recorded in solution and in the solid state, with a noteworthy photoluminescence quantum yield recorded on the neat crystals which undergo some mechanochromism. The crystal structure study of the probe from data collected at a synchrotron X-ray source shows a main aromatic plane π-stacked in a columnar arrangement.


2011 ◽  
Vol 32 (18) ◽  
pp. 1472-1477 ◽  
Author(s):  
Chuanjiang Qin ◽  
Yingying Fu ◽  
Chung-Hin Chui ◽  
Chi-Wai Kan ◽  
Zhiyuan Xie ◽  
...  

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