Single-Phase Proton- and Electron-Conducting Ag-Organic Coordination Polymers for Efficient CO2 Electroreduction

2022 ◽  
Author(s):  
Yingbing Zou ◽  
Tingting Zhan ◽  
Ying Yang ◽  
Zhiwen Fan ◽  
Yunbin Li ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Single Phase ◽  
Reduction Reaction ◽  
Metal Center ◽  
Co2 Electroreduction ◽  
Metal Organic

Here a single-phase proton- and electron-conducting metal-organic coordination polymer (MOCP) electrocatalyst for CO2 reduction reaction (CO2RR) was constructed by using Ag as the metal center and 1H-1,2,3-triazole (Tz) as ligand....

From an organic ligand to a metal–organic coordination polymer, and to a metal–organic coordination polymer–cocrystal composite: a continuous promotion of the proton conductivity of crystalline materials

CrystEngComm ◽  
2020 ◽  
Vol 22 (8) ◽  
pp. 1414-1424
Author(s):  
Xiaoqiang Liang ◽  
Tingting Cao ◽  
Li Wang ◽  
Changzheng Zheng ◽  
Yamei Zhao ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Proton Conductivity ◽  
Coordination Polymers ◽  
Organic Ligand ◽  
Organic Ligands ◽  
Crystalline Materials ◽  
Composite Formation ◽  
New Strategy ◽  
Metal Organic

A new strategy was proposed to increase proton conductivities in metal–organic coordination polymers (MOCPs) commencing from organic ligands, i.e. coordination inducement and MOCP–cocrystal composite formation.

Homochiral 3D coordination polymer with unprecedented three-directional helical topology from achiral precursor: synthesis, crystal structure, and luminescence properties of uranyl succinate metal–organic framework

2015 ◽  
Vol 44 (31) ◽  
pp. 13809-13813 ◽  
Author(s):  
Juan Wang ◽  
Zhen Wei ◽  
Fengwan Guo ◽  
Chenyang Li ◽  
Pengfei Zhu ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Coordination Polymers ◽  
Metal Organic Framework ◽  
Luminescence Properties ◽  
Precursor Synthesis ◽  
Metal Organic ◽  
Organic Framework

Synthesis, crystal structure and luminescence properties of uranyl chiral coordination polymers from achiral ligands.

scholarly journals An Fe(iii)-doped coordination polymer of Mn13-clusters with improved activity for the oxygen reduction reaction

2019 ◽  
Vol 48 (15) ◽  
pp. 4794-4797 ◽  
Author(s):  
Tian Wen ◽  
Wolfgang Schmitt ◽  
Lei Zhang
Keyword(s):  
Composite Materials ◽  
Coordination Polymer ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Coordination Polymers ◽  
Reduction Reaction ◽  
Porous Coordination Polymers ◽  
Orr Activity

Homogeneously distributed Fe(iii) dopants were introduced into porous coordination polymers of Mn13-clusters to form composite materials. The resulting Fe@Mn13-polymer exhibited efficient oxygen reduction reaction (ORR) activity.

Metal-organic frameworks derived carbon supported Cu-In bimetallic nanoparticles for highly selective CO2 electroreduction to CO

2021 ◽  
Author(s):  
Xia Ma ◽  
Jianjian Tian ◽  
Min Wang ◽  
Xixiong Jin ◽  
Meng Shen ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Bimetallic Catalysts ◽  
Bimetallic Nanoparticles ◽  
Metal Organic Frameworks ◽  
Co2 Reduction ◽  
Reduction Reaction ◽  
Co2 Electroreduction ◽  
Metal Organic ◽  
Co2 Reduction Reaction

Cu-based materials are promising electrocatalysts for CO2 reduction reaction (CO2RR). However, they still suffer intense hydrogen evolution, low selectivity and efficiency for CO2RR. In this work, Cu-In bimetallic catalysts for...

scholarly journals Heteroleptic LaIII Anilate/Dicarboxylate Based Neutral 3D-Coordination Polymers

Molecules ◽  
2021 ◽  
Vol 26 (9) ◽  
pp. 2486
Author(s):  
Olesya Y. Trofimova ◽  
Arina V. Maleeva ◽  
Irina V. Ershova ◽  
Anton V. Cherkasov ◽  
Georgy K. Fukin ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Coordination Polymer ◽  
Coordination Polymers ◽  
Spectral Characteristics ◽  
Metal Organic Frameworks ◽  
Chloranilic Acid ◽  
Synthetic Procedure ◽  
Anionic Ligands ◽  
Metal Organic ◽  
3D Framework

Three new 3D metal–organic frameworks of lanthanum based on mixed anionic ligands, [(La2(pQ)2(BDC)4)·4DMF]n, [(La2(pQ)2(DHBDC)4)·4DMF]n, [(La2(CA)2(BDC)4)·4DMF]n (pQ—dianion of 2,5-dihydroxy-3,6-di-tert-butyl-para-quinone, CA—dianion of chloranilic acid, BDC-1,4-benzenedicarboxylate, DHBDC-2,5-dihydroxy-1,4-benzenedicarboxylate and DMF-N,N′-dimethylformamide), were synthesized using solvothermal methodology. Coordination polymers demonstrate the rare xah or 4,6T187 topology of a 3D framework. The homoleptic 2D-coordination polymer [(La2(pQ)3)·4DMF]n was obtained as a by-product in the course of synthetic procedure optimization. The thermal stability, spectral characteristics and porosity of coordination polymers were investigated.

Turn-on fluorescence detection of ciprofloxacin in tablets based on lanthanide coordination polymer nanoparticles

RSC Advances ◽  
2016 ◽  
Vol 6 (103) ◽  
pp. 100743-100747 ◽  
Author(s):  
Baoxia Liu ◽  
Yankai Huang ◽  
Qi Shen ◽  
Xu Zhu ◽  
Yuanqiang Hao ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Fluorescence Detection ◽  
Coordination Polymers ◽  
Polymer Nanoparticles ◽  
Functional Nanomaterials ◽  
Turn On ◽  
New Family ◽  
Lanthanide Coordination Polymer ◽  
Metal Organic

Metal–organic coordination polymers (MOCPs) have emerged as a new family of functional nanomaterials.

scholarly journals Investigation of Adsorption Capacity of Metal-Organic Polymers

2021 ◽  
Vol 15 ◽  
pp. 1443-1449
Author(s):  
S. N. Vakhneev ◽  
Yan Naing Min
Keyword(s):  
Drug Delivery ◽  
Coordination Polymer ◽  
Adsorption Capacity ◽  
Coordination Polymers ◽  
Hybrid Material ◽  
Functional Materials ◽  
Practical Application ◽  
Muconic Acid ◽  
Metal Organic ◽  
Ph Range

In this work, we studied a biocompatible hybrid material based on iron (III) and muconic acid oxoclusters. It has been shown that coordination polymers are a promising class as functional materials for various purposes (as sorbents, catalysts, conductors, storage materials, etc.). The adsorption capacity of the obtained adsorbent for removing dyes from the prepared solution was in the following order: CR> MB> MV. From the results of the study, we can conclude that the dye Congo red is best suited for adsorption by the coordination polymer. The maximum absorption of the dye on organometallic coordination polymers occurs in the pH range 5 - 7 with adsorption of ~ 90%, which is important for the potential practical application of such coordination polymers as carriers for drug delivery.

scholarly journals Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013)

2013 ◽  
Vol 85 (8) ◽  
pp. 1715-1724 ◽  
Author(s):  
Stuart R. Batten ◽  
Neil R. Champness ◽  
Xiao-Ming Chen ◽  
Javier Garcia-Martinez ◽  
Susumu Kitagawa ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
General Term ◽  
Coordination Networks ◽  
Physical Measurements ◽  
And Topology ◽  
Metal Organic ◽  
Per Se

A set of terms, definitions, and recommendations is provided for use in the classification of coordination polymers, networks, and metal–organic frameworks (MOFs). A hierarchical terminology is recommended in which the most general term is coordination polymer. Coordination networks are a subset of coordination polymers and MOFs a further subset of coordination networks. One of the criteria an MOF needs to fulfill is that it contains potential voids, but no physical measurements of porosity or other properties are demanded per se. The use of topology and topology descriptors to enhance the description of crystal structures of MOFs and 3D-coordination polymers is furthermore strongly recommended.

scholarly journals Mechanochemical Access to Elusive Metal Diphosphinate Coordination Polymer

Crystals ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 283 ◽  
Author(s):  
Andrea Ienco ◽  
Giulia Tuci ◽  
Annalisa Guerri ◽  
Ferdinando Costantino
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Crystalline Form ◽  
Framework Structure ◽  
Open Framework ◽  
Metal Organic ◽  
Two Phases ◽  
Bridge Length ◽  
Open Framework Structure

Several binary metal diphosphinate compounds (ML) have been reported for diphosphinate bonded by a single methylene fragment. In case of longer bridges, binary products are difficult to isolate in crystalline form. Here, using a solvent assisted mechano-chemistry synthesis, we report two new ML crystalline phases, one hydrated and one anhydrous. The hydrated phase is a 2D coordination polymer with an open framework structure. Its network displays a new topology for coordination polymers and metal organic frameworks. The thermal behavior of the two phases has been studied. Finally, the importance of the bridge length is discussed in view of known metal diphosphinate compounds.

Substrate templated synthesis of single-phase and uniform Zr-porphyrin-based metal–organic frameworks

2020 ◽  
Vol 7 (1) ◽  
pp. 221-231
Author(s):  
Seong Won Hong ◽  
Ju Won Paik ◽  
Dongju Seo ◽  
Jae-Min Oh ◽  
Young Kyu Jeong ◽  
...  
Keyword(s):  
Chemical Bath Deposition ◽  
Single Phase ◽  
Metal Organic Frameworks ◽  
Templated Synthesis ◽  
Pore Structures ◽  
Phase Pure ◽  
Metal Organic ◽  
Cbd Method

We successfully demonstrate that the chemical bath deposition (CBD) method is a versatile method for synthesizing phase-pure and uniform MOFs by controlling their nucleation stages and pore structures.

Sign in / Sign up

Export Citation Format

Share Document