Electrically conductive Covalent Organic Frameworks: Bridging the Fields of Organic Metals and 2D Materials

Author(s):  
Manuel Souto ◽  
Dmitrii Perepichka

The discovery of organic metals in 1970s opened the door to the design of electrical devices based on traditionally inert (insulating) organic materials. More recently, demonstration of record-high charge mobility...

ChemInform ◽  
2010 ◽  
Vol 41 (17) ◽  
Author(s):  
Linjun Wang ◽  
Guangjun Nan ◽  
Xiaodi Yang ◽  
Qian Peng ◽  
Qikai Li ◽  
...  

2010 ◽  
Vol 39 (2) ◽  
pp. 423-434 ◽  
Author(s):  
Linjun Wang ◽  
Guangjun Nan ◽  
Xiaodi Yang ◽  
Qian Peng ◽  
Qikai Li ◽  
...  

2006 ◽  
Vol 128 (29) ◽  
pp. 9304-9305 ◽  
Author(s):  
Hong Meng ◽  
Fangping Sun ◽  
Marc B. Goldfinger ◽  
Feng Gao ◽  
David J. Londono ◽  
...  

Author(s):  
Michael Greaves ◽  
Mana Mende ◽  
Jiacheng Wang ◽  
Wenji Yang ◽  
Suelen Barg

AbstractAmong 2D materials, MXenes (especially their most studied member, titanium carbide) present a unique opportunity for application via colloidal processing, as they are electrically conductive and chemically active, whilst still being easily dispersed in water. And since the first systematic study of colloidal MXene rheology was published in 2018 (Rheological Characteristics of 2D Titanium Carbide (MXene) Dispersions: A Guide for Processing MXenes by Akuzum, et al.), numerous works have presented small amounts of rheological data which together contribute to a deeper understanding of the topic. This work reviews the published rheological data on all MXene-containing formulations, including liquid crystals, mixtures and non-aqueous colloids, which have been used in processes such as stamping, patterning, 2D and 3D printing. An empirical model of aqueous titanium carbide viscosity has been developed, and recommendations are made to help researchers more effectively present their data for future rheological analysis. Graphic abstract


2016 ◽  
Vol 129 (3) ◽  
pp. 740-745 ◽  
Author(s):  
Mengyun Chen ◽  
Yang Zhao ◽  
Lijia Yan ◽  
Shuai Yang ◽  
Yanan Zhu ◽  
...  

2011 ◽  
Vol 7 (8) ◽  
pp. 2556-2567 ◽  
Author(s):  
Choongkeun Lee ◽  
Robert Waterland ◽  
Karl Sohlberg

2011 ◽  
Vol 123 (32) ◽  
pp. 7537-7540 ◽  
Author(s):  
Eva M. García-Frutos ◽  
Upendra K. Pandey ◽  
Roberto Termine ◽  
Ana Omenat ◽  
Joaquín Barberá ◽  
...  

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Wiel H. Evers ◽  
Juleon M. Schins ◽  
Michiel Aerts ◽  
Aditya Kulkarni ◽  
Pierre Capiod ◽  
...  

2020 ◽  
Author(s):  
Maryam Reisjalali ◽  
Jose Javier Burgos Marmol ◽  
Alessandro Troisi

High performing organic semiconducting polymers show great potentials for use in electronic devices which is greatly dependent on the material crystallinity and packing. A series of short oligomers of the diketopyrrolopyrrole (DPP)-based materials that have shown to have high charge mobility are studied to understand the local structuring at atomic level for these materials. The simulations show that the tendency for this material class to form aggregates is driven by the interaction between DPP fragments, but this is modulated by the other conjugated fragments of the materials which afect the rigidity of the polymer and the ability to form aggregates of larger size.<br>


Nanomedicine ◽  
2020 ◽  
Vol 15 (21) ◽  
pp. 2041-2052
Author(s):  
Zhongjian Xie ◽  
Ruitao Lu ◽  
Yao Zhu ◽  
Minhua Peng ◽  
Taojian Fan ◽  
...  

Aim: The present study aims to apply the facile liquid-phase exfoliation (LPE) strategy to fabricate 2D organic materials and thus to broaden the family of biocompatible and multifunctional 2D materials. Materials & methods: 2D material-organic melanin and cellulose nanosheets were synthesized from black sesame hull using LPE. Photoluminescence and photothermal properties of the nanosheets were assessed, as well as stability and cell killing ability. Results: The prepared 2D nanoplatform exhibited broad and multiple photoluminescent emission bands. It also demonstrated efficient photothermal cancer therapy with excellent biocompatibility. Conclusion: The present study could open an avenue in exfoliating organic materials using the LPE strategy. This could make the fabrication of multifunctional 2D organic materials more efficient and broaden the family of biocompatible 2D nanomaterials.


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