scholarly journals Thorium and Uranium distribution in a passive system for mine water treatment

2019 ◽  
Vol 98 ◽  
pp. 09023
Author(s):  
Maria Isabel Prudêncio ◽  
Teresa Valente ◽  
Rosa Marques ◽  
Maria Amália Sequeira Braga ◽  
Jorge Pamplona

The abandoned Jales mining area is a sulphide-rich deposit (Northeast of Portugal). Acid mine drainage resulted from oxidation of sulphides is treated in a passive system with wetlands. The present work studies the thorium and uranium behaviour in the water and in the fine fractions of wetland soils throughout the passive treatment system. The evaluation of the efficiency of the all system was done determining metals concentration variation in the creek water upstream and downstream of the treated effluent discharge. The results point to higher efficiency to retain Th after summer than after winter. The opposite was found for uranium, which increases significantly in the creek water after summer and, in a lower extent, after winter. Also, Th and U have a tendency to increase in the fine fractions of the wetlands soils after summer, which can be explained by the longer water-soil contact/lower water dynamics. Nevertheless uranium has a much higher tendency to be in solution as revealed by a high concentration in the porewater of wetland soils. A relation of these actinides behaviour with the Fe and Mn distribution is not clear.

Author(s):  
Aliyeh Seifi ◽  
Mahdieh Hosseinjanizadeh ◽  
Hojjatolah Ranjbar ◽  
Mehdi Honarmand

Abstract The present research focuses to investigate the relationship between spectral and chemical characteristics of water samples in Darrehzar mine. In order to reach this aim the chemical characteristics of water were measured through pH, electrical conductivity (EC) and inductively coupled plasma mass spectrometry (ICP-MS) analysis. Furthermore, the visible near infrared (VNIR) and shortwave infrared (SWIR) spectra of water samples were measured by Analytical Spectral Devices (ASD) FieldSpec3 spectroradiometer and the relationships between spectral and chemical characteristics of water samples were calculated. Results of the pH and EC measurements showed that water with high acidity and EC values which indicates presence of acid drainage was located inside the mine. High concentration of copper, sulfur and iron at the samples could be related to copper mineralization and association with acid mine drainage. Results of spectroscopy revealed that second absorption feature (AF2) magnitude correlated significantly with pH (−0.599), EC (0.611) (p < 0.1) and total trace elements plus sulfur (0.822) (p < 0.05). The significant correlation of the AF2 magnitude with concentrations of S (0.854), Pb (0.914), Ni (0.836), Mn (0.834), Co (0.848) and AF3 with concentration of Fe (0.886) confirm that absorption feature magnitude increases by increasing metals concentrations in water.


Author(s):  
Erika Remešicová ◽  
Peter Andráš ◽  
Radmila Kučerová

The area of Sedem Žien tailing pond and the nearby Šobov hydroquartzite quarry affected by mining activity were investigated by geochemical and mineralogical methods to determine the contaminating chemical compounds and study their availability. Degradation of the hydrothermal base mineralisation (galena, sphalerite, pyrite, pyrrhotite and chalcopyrite) and of fine-grained pyrite oxidation, which forms impregnations in hydroquartzite produce Acid Mine Drainage (AMD). The area is acidified and the country components (soil, rock, water) are contaminated mainly by Pb, Zn and Fe. The tailing pond dam forming soils show acid pH (2.28–3.25), whereas the soil on the tailing pond surface is close neutral pH (7.26). The leaching availability of the metals from the soil is up to 75%. The AMD from the hydroquartzite quarry is in comparison with those percolating the tailing pond sediments very acid (pH 2.71) and contains high concentration of metals (Fe 311 mg.L-1, Zn 1690 µg.L-1, Cu 890 µg.L-1, Pb 126 µg.L-1).


Author(s):  
Z. I. Khazheeva ◽  
S. S. Sanzhanova

The Dzhida ore field in the Zakamensk district of Buryatia features high concentration of mineralization within a small area. The Dzhida deposit is composed of complex ore. The ore field contains commercial-value primary deposits: Pervomai stockwork of molybdenum, Kholtoson tungsten lode and Inkur stockwork of tungsten. The Modonkul river catchment basin lies inside the Dzhida ore field. A real threat to the town of Zakamensk is created by manmade sand-bulk (old) tailings and slurry dump. By now, the concentrated flow of natural and man-made sand enters the low terrace and floodplain of the Modonkul river in the form of a talus train. This study is focused on the influence of the mine drainage effluent and the Inkur tributary on the water chemistry in the Modonkul river. 80 water samples were taken from the surface layer 0-0.5 m thick at five stations. Physicochemical indices of water were measured at the water sampling points, and the water chemistry was analyzed in a laboratory. In the background conditions, cations and anions in the Modonkul water chemistry range in decreasing order as follows: Са2+ > Mg2+ > Na++К+ и HCO - > SO 2- > Cl-. In the zone of mixture of natural and mine process water, the chemistry changes: from hydrocarbonate to sulfate (anion), from calcium-magnesium to sodium-calcium (cation). Downstream the natural chemistry changes to the hydrocabonate-sulfate composition, with prevailing content of calcium in cations. Iron content of water lowers 3-4 times after influx of mine effluents, while the contents of Mn, Zn, Co and Cd grow and then decrease downstream.


2012 ◽  
Vol 610-613 ◽  
pp. 3252-3256
Author(s):  
Mei Qin Chen ◽  
Feng Ji Wu

Acid mine drainage (AMD) has properties of extreme acidification, quantities of sulfate and elevated levels of soluble heavy metals. It was a widespread environmental problem that caused adverse effects to the qualities of ground water and surface water. In the past decades, most of investigations were focused on the heavy metals as their toxicities for human and animals. As another main constitution of AMD, sulfate ion is nontoxic, yet high concentration of sulfate ion can cause many problems such as soil acidification, metal corrosion and health problems. More attention should be paid on the sulfate ion when people focus on the AMD. In the paper, sulfate removal mechanisms include adsorption, precipitation, co-precipitation and biological reduction were analyzed and summarized. Meanwhile, the remediation technologies, especially the applications of them in China were also presented and discussed.


2021 ◽  
Vol 23 ◽  
pp. 318-331
Author(s):  
Aleksandra Czajkowska ◽  
Łukasz Gawor

In the paper there is presented an evaluation of variability of surface water quality (reservoirs and watercourses), on the area of degraded post-mining area in Bytom. The physicochemical analysis of water and compared with archival data obtained in 2009 and 2014. There were done analysis of following parameters: reaction, total content of substances dissolved in water, water hardness and the content of: Cl-, SO42-, HCO3-, Ca2+, Mg2+, K+, Na+, NH4+, NO3-, NO2-, PO4- ions as well as Fe and Mn. The examined surface waters were characterised by high content of solutes. Anions were dominated by chlorides, the sodium proved to be the dominating cation, the examined water samples were characterised by high concentration of sulphates. In all analyzed reservoirs, permissible concentrations of chlorides and sulphates were exceeded. In all sample points there was observed a decrease of pH value in long term period, the concentration of chlorides lowered, however concentrations of sulphates increased in the majority of sampling points.


2020 ◽  
Vol 15 (3) ◽  
pp. 580-597
Author(s):  
I. O. Ntwampe

Abstract A series of experiments was conducted using 200 mL of acid mine drainage (AMD) collected from Krugersdorp, South Africa, to determine turbid materials removal efficiency of a combination of bentonite clay, Fe or Al salt and MgCO3. The sample was poured into five 500 mL glass beakers using bentonite clay, FeCl3, AlCl3 and MgCO3 dosage respectively. The samples were treated in jar test at rapid and slow mixing, allowed to settle for 1 hour, then the pH, conductivity, total suspended solids (TSS), dissolved oxygen (DO) and oxidation reduction potential (ORP) were measured (exp A). A second and third similar sets of experiments were conducted with a combination of bentonite clay and MgCO3 (flocculent) dosage (exp B), and FeCl3 with slow mixing only (exp C). Experimental results revealed that the pH of treated effluent with bentonite clay does not exhibit significant increasing trend because of insignificant hydrolysis, whereas the pH of samples with FeCl3, AlCl3 and MgCO3 exhibit a slight decreasing trend, showing a low rate of hydrolysis. The DO and ORP of treated effluent does not show a significant changing trend compared to the untreated AMD sample. Residual TSS of the AMD samples treated with a flocculent is lower than the samples treated with bentonite clay, FeCl, AlCl3 and MgCO3. Residual turbidity of the samples with rapid mixing is identical to that of the corresponding samples with slow mixing. TSS removal efficiency of a flocculent is higher compared to other reagents. The results show that synthetic flocculent is an ideal replacement for inorganic coagulants. The scanning electron microscopy (SEM) micrographs exhibit slides with dense-sponge like flocs showing high adsorption capacity.


2014 ◽  
Vol 919-921 ◽  
pp. 2149-2152
Author(s):  
Ya Feng Li ◽  
Chun Fei Wei

Using microwave-ferrous sulfate modified activated carbon adsorption manner to remove the high concentration of phosphorus in wastewater. The power of microwavethe concentration of ferrous sulfate and reaction time on phosphorus removal were studied. When the power of microwave was 425W,the concentration of ferrous sulfate was 0.1mol/L,reaction time was 50 min,the removal rate of TP reaches 95.67%,the treated effluent TP can be dropped to 0.48mg/L,the TP can reaches the first effluent standard of TP in the comprehensive wastewater discharge standard (GB8978-1996).Microwave-ferrous sulfate modified activated carbon is adapted to treat high concentration phosphorus in the wastewater.


2014 ◽  
Vol 675-677 ◽  
pp. 1385-1394
Author(s):  
Cheng Rong Jiang ◽  
Liu Yang ◽  
Hao Xie ◽  
Hua Yi Huang ◽  
De Ke Sun

In combination with the geological conditions of Tie'er mining area in Tangshan coal mining, this paper not only analyzes the evolution of overlying strata structure in stope and the development law of overlying strata separation, also proposes a new continuous grouting technology with large flow and high concentration slurry. The industrial test showed that, when the grout-mining ratio of the whole mining area is 25.3%, the reducing subsidence ratio is 51.5%, the effect of reducing the surface subsidence is good. According to the chemical analysis of water quality ingredients of slurry, the test result showed, heavy metals contents in fly-ash slurry water do not exceed the standard, which has no bad effect on the fissure water in the bedrock.


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