Catalytic performance and industrial test of HY zeolite for alkylation of naphthalene and α-tetradecene

As a synthetic lubricant with excellent properties, alkyl naphthalene is widely used in petrochemical and manufacturing industries. Alkyl naphthalene is formed by naphthalene and α-tetradecene under the action of alkylation...

Investigation on Hydraulic Fracturing and Cutting Roof Pressure Relief Technology for Underground Mines: A Case Study

Using hydraulic fracturing for cutting roof pressure is a critical technology to protect coal pillars. In this paper, based on the engineering background of 18506 working face in the Xiqu Coal Mine, using the methods of theoretical analysis, numerical simulation, and field measurement, a reasonable coal pillar width and practical parameters of hydraulic fracturing are given. The results show that roof cutting can significantly increase the stress in goaf and relieve the advanced pressure of the working face. Taking 18506 working face as the research object, the industrial test is carried out, and the surrounding rock control scheme of hydraulic fracturing and roof cutting is put forward, the mine pressure monitoring results show that the auxiliary roadway of 18506 working face reaches a stable state within 20 days, the deformation and damage degree of roadway surrounding rock are small, and the integrity of surrounding rock is improved.

Evaluating the Effect of MgO/Al2O3 Ratio on Thermal Behaviors and Structures of Blast Furnace Slag with Low Carbon Consumption

In order to clarify the effect of the MgO/Al2O3 ratio on the fluidity of a low-alumina blast furnace slag system, the influence law of slag fluidity with different MgO/Al2O3 ratios was studied based on the composition of blast furnace slag through a viscosity experiment and themodynamic software. By studying the effect of the MgO/Al2O3 ratio on the activation energy of viscous flow of slag combined with FT-IR, the effect of the MgO/Al2O3 ratio on the thermal-stability of low-aluminum slag was interpreted from the microstructure level. Results indicated that the viscosity and the melting temperature of slag both showed a gradual downward trend due to the increase of the MgO/Al2O3 ratio. Besides, the temperature stability of the low aluminum slag became more stable due to the depolymerization of the complex structure of slag. Considering the actual operating conditions of blast furnace, the MgO/Al2O3 ratio of slag was suggested to be controlled to 0.60 and the basicity to be no higher than 1.20 under the conditions of this investigation. Industrial test results showed that the coke rate could be saved as 3.49 kg/t when the MgO/Al2O3 ratio decreased from 0.70 to 0.58.

Development and Test of Rubber Wheel Full Hydraulic Drill in Coal Mine

In order to solve the problem of moving rig quickly and reducing labor intensity in the mine face with trackless transportation conditions, a solution of rubber wheel drill which meets the working conditions is put forward. The drilling rig adopts the configuration of double power and double system, the power comes from the engine when moving, to achieve walking, steering, braking and temporary stability, relocation and transfer of high efficiency and flexibility, the power comes from the motor when drilling, to achieve rotation, feed and auxiliary Angle adjustment, safe and pollution-free construction. After the assembly and debugging of the whole machine, ground simulation test and underground industrial test were carried out on the rig. The test results show that the rig has strong maneuverability, one person can complete the moving walking, the maximum walking speed is 20km/h, and the steering is flexible and the braking is safe. The maximum depth of drilling hole construction is 318m, the target area hit rate reaches 77.8%, the working performance is stable, the hydraulic system is stable, and all parameters meet the design requirements. The equipment provides new technical equipment for the mine drilling construction with trackless transportation conditions.

Accurate Perception of Rock Strata Movement for Environmental Protection in Coal Mining: Taking Thick and Hard Roof Cooperative Control as an Example

Accurate perception of the key stratum instability can improve the safety of coal mining and also provide a basis for alleviating overlying rock strata destruction and environmental disturbance. To efficiently evaluate the instability of the key stratum and its threat to safe mining and environmental protection, the fracture characteristics and weakening mechanisms were studied through physical simulation, theoretical analysis, and field measurement. A scheme and the parameters of confined blasting in water-filled deep hole presplit technology (CBWDHPT) for thick and hard roof (THR) weakening were proposed. Research studies showed that, after the THR fractured into large blocks, the subsequent sliding instability induced serious support-crushing accidents; however, increasing the support strength could only provide limited control. Confined water and infiltrated modified rock mass functioned as the transfer load medium of the explosives, and the CBWDHPT fully utilized high explosion energy to break rocks. Consequently, the collapse and filling of the immediate roof and low-positioned THR, as well as the timely cutting off the middle-positioned THR, could be realized, which alleviated the migration space of THR blocks, overlying strata destruction, and earth-surface step subsidence. Finally, the environmentally friendly strategy (including the CBWDHPT and hydraulic support optimization) for overlying rock strata protection was proposed. In the industrial test, the THR was broken into blocks of different sizes after utilizing the CBWDHPT, and the support working resistance was significantly decreased. It was concluded that the environmentally friendly strategy could effectively reduce the risk of overlying rock strata destruction.

RV SONNE Fahrtbericht/Cruise Report SO268 - Assessing the Impacts of Nodule Mining on the Deep-sea Environment: NoduleMonitoring, Manzanillo (Mexico) – Vancouver (Canada), 17.02. – 27.05.2019

Cruise SO268 is fully integrated into the second phase of the European collaborative JPI-Oceans project MiningImpact and is designed to assess the environmental impacts of deep-sea mining of polymetallic nodules in the Clarion-Clipperton Fracture Zone (CCZ). In particular, the cruise aimed at conducting an independent scientific monitoring of the first industrial test of a pre-protoype nodule collector by the Belgian company DEME-GSR. The work includes collecting the required baseline data in the designated trial and reference sites in the Belgian and German contract areas, a quantification of the spatial and temporal spread of the produced sediment plume during the trials as well as a first assessment of the generated environmental impacts. However, during SO268 Leg 1 DEME-GSR informed us that the collector trials would not take place as scheduled due to unresolvable technical problems. Thus, we adjusted our work plan accordingly by implementing our backup plan. This involved conducting a small-scale sediment plume experiment with a small chain dredge to quantify the spatial and temporal dispersal of the suspended sediment particles, their concentration in the plume as well as the spatial footprint and thickness of the deposited sediment blanket on the seabed.

Modeling CO2, H2S, COS, and CH3SH Simultaneous Removal Using Aqueous Sulfolane–MDEA Solution

In this study, a rate-based absorption model coupled with an improved thermodynamic model was developed to characterize the removal of acid components (CO2 and H2S) and organic sulfur (COS and CH3SH) from natural gas with an aqueous sulfolane–MDEA solution. First, the accuracy of the thermodynamic model was validated by comparing the calculated partial pressure of CO2, H2S, and CH3SH with those of the experimental data reported in the literature. Then, the industrial test data were employed to validate the absorption model and the simulation results agreed well with the experimental data. The average relative errors of the removal rates of CO2, COS, and CH3SH are 3.3%, 3.0%, 4.1%, respectively. Based on the validated coupled model, the total mass transfer coefficient and mass transfer resistance of each solute component at different column positions were analyzed. The effects of the gas–liquid ratio, overflow weir height, and absorption pressure on the absorption performance of each component were studied, and the influence of the acid component concentration in the feed gas on the removal efficiency of methyl mercaptan (CH3SH) was also discussed. It is found that the improved absorption model can better characterize the absorption performance and be conducive to the optimal design of the absorber column.

Application of Presplitting Blasting Technology in Surrounding Rock Control of Gob-Side Entry Retaining with Hard Roof: A Case Study

Through the analysis of the mining situation and geological data of Qidong mine and working face, the key factors affecting the roof cutting and pressure relief roadway retention along the goaf are defined. Combined with numerical simulation and field test, the reasonable parameters of combined presplitting blasting of deep hole and shallow hole in hard roof are determined, and the roof cutting effect is tested through field observation and borehole peeping. The comprehensive control measures for the surrounding rock of 7135 roadway with roof cutting and pressure relief and gob retaining are formulated, including safety assurance technical measures, such as advanced precrack and seam cutting, roof reinforcement and support, gangue retaining protection beside the roadway, lagging temporary support, and on-site industrial test monitoring scheme. Aiming at the hard rock roof, the “deep hole + shallow hole” presplitting blasting roof cutting technology is developed, and the economic and reasonable blasting parameters are determined. The drilling peep results show that the implementation effect of presplitting blasting technology is good. The results showed that deep holes and shallow holes with small spacing and parallel to each other shall be arranged on the planned seam line. The peeping results show that the crack formation rate in the charging section exceeds 85% in the process of deep hole blasting. In shallow hole blasting, the crack formation rate of charging section is more than 90%.

Deformation Mechanism and Surrounding Rock Control in High-Stress Soft Rock Roadway: A Case Study

Stability control for soft and broken surrounding rock of roadways is one important segment of mining support. Taking 1412 Roadway of a mine in Guizhou province as a research background, this paper studies the large deformation of surrounding rock and the failure of bolts and cables. The deformation and failure mechanism are analyzed by related theoretical analysis and field survey. Then, the feasibility of the composite controlling scheme, bolts and cables + grouting + steel tube concrete support, is verified by theoretical analysis, numerical simulation, and industrial test. Following results can be obtained: main reasons leading to the deformation of surrounding rock and the failure of cables and blots in the roadway are low strength and poor self-stability of surrounding rock, complex stress environment, low support resistance, and lack of reinforced support in crucial supporting sites; the control scheme can reduce the surrounding rock deformation by 40%, which meets the requirements of field application so that this practice can provide some guidance for other similar projects.