scholarly journals The improvement of gamma irradiation resistance of superhydrophobic coating with MWCNTs

2018 ◽  
Vol 175 ◽  
pp. 01014
Author(s):  
Jing Zhang ◽  
Yan Zhang ◽  
Yujian Liu

A superhydrophobic coating with excellent water repellence and gamma irradiation resistance was obtained by multi-walled carbon nanotubes (MWCNTs) modification. The effects of MWCNTs on the mechanical behaviour, water contact angle (WCA) and self-cleaning properties of the coatings were investigated. After 1.23×107 rad dose of gamma irradiation, WCA of the coating without MWCNTs modification (EPPM0) decreases from 150° to 140° and the adhesion reduces from 5B to 4B, respectively. While the coating (EPPM3) with 3wt% MWCNTs modification remains high WCA (152°), excellent adhesion (5B) and hardness (6H). The results of dust removal test suggest that the coating still maintains self-cleaning property after high dose gamma irradiation.

2020 ◽  
Vol 20 (10) ◽  
pp. 6317-6325 ◽  
Author(s):  
Xueting Shi ◽  
Libin Zhao ◽  
Jing Wang ◽  
Libang Feng

This work reports a facile method for fabricating superhydrophobic surface on copper plate by AgNO3 treatment and dodecyl mercaptan modification. The as-prepared superhydrophobic copper plate presents hierarchical and rough morphology composed of nanosheets and nanoparticleformed matrix. Meanwhile, long alkyl chains are assembled onto the rough surface successfully. Consequently, the copper plate is endowed with excellent superhydrophobic performance with a water contact angle of 156.8° and a rolling angle of ca. 3°. Moreover, the superhydrophobicity has long-term durability and excellent stability. Grounded on the strong water repellence, the resultant superhydrophobic copper plate surface exhibits multi-functions. The excellent performance can be well explained by “Cushion effect” and Capillary phenomena. As a result, water and corrosive species can be prevented from contacting with the copper plate surface, and contaminants can be taken away easily by the rolling water droplets. Meanwhile, the icing process of water is delayed on the superhydrophobic surface. Therefore, the superhydrophobic copper is endued with enhanced corrosion resistance, excellent self-cleaning and anti-icing performance. We believe that this facile method provides a simple and cost-effective process to improve the properties of copper plate, and which may see practical application of the superhydrophobic materials.


2010 ◽  
Vol 434-435 ◽  
pp. 534-537
Author(s):  
Tao Li ◽  
Chang Song Liu ◽  
Qiang Zhang ◽  
Zhi Wen Li

Superhydrophobic surfaces, which have anti-adhesion and self-cleaning properties, were fabricated on Al substrates. The self-cleaning surface was prepared by two steps: firstly, a chemical solution method was used to create the surface roughness with disorderly veins micronanostructures. Secondly, fluoroalkylsilane was deposited on the rough surface to lower its surface energy. The combination of veins micronanostructures and fluoroalkylsilane modification gave the surface a superhydrophobicity with static water contact angle of 166° and sliding angle of smaller than 1°. Additionally, the surface showed a strong anti-adhesion with water and a satisfied self-cleaning property. Water droplets easily rolled off the surface and picked up dirt and debris with them. The surfaces obviously corresponded to Cassie (not Wenzel) -model. Air entrapped within the veins microstructures greatly increases the air/water interface, effectively preventing the penetration of water into the grooves, and finally exhibiting the self-cleaning property. The results will greatly extend Al substrates for specific functions such as water-repellence, self-cleaning and anti-fouling.


2020 ◽  
Vol 14 (2) ◽  
pp. 148-158 ◽  
Author(s):  
Sarah F. Jurak ◽  
◽  
Emil F. Jurak ◽  
Md. Nizam Uddin ◽  
Ramazan Asmatulu

Because of their repellent, corrosion-mitigating, anti-icing, and self-cleaning properties, superhydrophobic coatings have numerous applications from windshields to textiles. A superhydrophobic coating is defined as one having a water contact angle (WCA) greater than 150° with a surface sliding angle less than 10°, and very low hysteresis between the advancing and receding angles. Its surface exhibits the so-called “lotus leaf effect,” whereby water bounces and balls up on contact. Here, water droplets run off readily, taking along dirt and dust for a self-cleaning effect that keeps the surface dry. The chemical composition of a surface affects the WCA, which can rise to 120°, but to achieve a WCA greater than 150°, which is considered superhydrophobic, an additional micro- and nanostructural component is needed. This functional hierarchical micro- and nanomorphology is exhibited in nature by plants and insects. A superhydrophobic coating on metallic substrates promises to provide corrosion mitigation by blocking oxygen and electrolytes, which are needed for the initiation of corrosion at the surface and interface. The methods used for preparing functional superhydrophobic coatings include sol-gel processing, layer-by-layer assembly, etching, lithography, chemical and electrochemical depositions, chemical vapor deposition, electrospinning, hydrothermal synthesis, and one-pot reactions. In this work, some research studies conducted to develop robust and durable superhydrophobic coatings are discussed in detail and analyzed for possible corrosion mitigation on the surfaces of metals and alloys. Scientists, engineers, students, and other participants in automotive, aircraft, energy, defense, electronics, and other industries will benefit greatly from this work.


2020 ◽  
Vol 12 (5) ◽  
pp. 676-684 ◽  
Author(s):  
Guo-Qiang Xi ◽  
Jun-Feng Li ◽  
Hui Deng ◽  
Ming-Guo Ma

Superhydrophobic surfaces have received enormous attention thanking to their potential applications in the areas of anti-icing, anti-contamination, and oil/water separation. Herein, we have successfully prepared superhydrophobic surfaces, which were synthesized by using the polydimethylsiloxane (PDMS) as adhesive and the magnesium palmitate (Mg-P) were evently coated to form roughness on the surfaces of glass, textile, stainless steel mesh, and paper. The as-fabricated superhydrophobic surfaces possessed excellent water-resistance, self-cleaning properties, durability, and robustness. Remarkably, in the actual oil/water separation, the water contact angle and oil collection efficiency of the superhydrophobic mesh were still more than 150° and 91% even after separation over 10 cycles, respectively. Thus, the superhydrophobic coating has applications potential in self-cleaning, anti-contamination, and oil/water separation fields.


2013 ◽  
Vol 750-752 ◽  
pp. 123-126
Author(s):  
Nan Ting Zhou ◽  
Xiang Bin Shi ◽  
Xiao Juan Sun ◽  
Wei Du ◽  
Lan Yao ◽  
...  

Effect of functionalized multi-walled carbon nanotubes (MWCNT) on the interfacial properties of ramie fiber/polylactic acid (PLA) matrix was studied. Ramie fibers were respectively covered by the pristine MWCNT, carboxyl functionalized MWCNT and hydroxide functionalized MWCNT through the simple dip coating method. Scanning electron microscopy (SEM) results showed that all kinds of MWCNT were distributed on the fiber surface at random with some aggregations. Compared to the pristine MWCNT coated fibers with a water contact angle of 84.5 degree, the functionalized MWCNT coating made the fiber surface more hydrophobic. Polarization microscopy indicated that the functional MWCNT could provide the nucleation to form the intact crystalline structure of PLA on the fiber surface. Micro-bond tests showed that the coating of MWCNT on the fiber surface had no significant effect on the interfacial shear strength (IFSS).


Nanomaterials ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 2269
Author(s):  
Jungryeong Chae ◽  
Taeuk Lim ◽  
Hao Cheng ◽  
Wonsuk Jung

The effect of changes in non-solvent coagulation bath temperature on surface properties such as morphology and hydrophilicity were investigated in multi-walled carbon nanotubes (MWCNTs) and graphene oxide (GO)-based polyvinylidene fluoride (PVDF) membranes. The properties of pores (size, shape, and number) as well as membrane hydrophilicity were investigated using field emission scanning electron microscopy, Raman spectroscopy, optical microscopy, water contact angle, and water flux. Results showed that the pore size increased with an increase in coagulation temperature. The hydrophilic functional groups of the added carbon materials increased the solvent and non-solvent diffusion rate, which significantly increased the number of pores by 700% as compared to pure PVDF. Additionally, these functional groups changed the hydrophobic properties of pure PVDF into hydrophilic properties.


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