scholarly journals Study of the nickel-phosphorus coating structural-phase states

2020 ◽  
Vol 329 ◽  
pp. 02017
Author(s):  
Igor Shcherbakov
Keyword(s):  
Structural Phase ◽  
Chemical Deposition ◽  
The State ◽  
Surface Layers ◽  
Volume Changes ◽  
Coating Surface ◽  
Phosphorus Containing ◽  
Maximum Stability

The results of modeling a composite nickel-phosphorus coating obtained by chemical deposition are presented. The state of structural-phase disordering of the coating surface is considered. The analysis of possible structural states in the surface layers of the coating is carried out. A graph of Me atoms volume changes in phosphorus-containing compounds MexPy(Ме – Fe, Cr, Ni) and the maximum stability temperature NixPyis plotted depending on the composition. The idealized images of the projections of tetragonal and trigonal phosphorus-containing phases structures are constructed.

MACHINERY OPERATIONAL PROPERTY CONTROL DURING DIAMOND-ABRASIVE FINISHING USING ACTIVE SOTS

2020 ◽  
Vol 2020 (9) ◽  
pp. 13-17
Author(s):  
Yuriy Ryzhov ◽  
Svetlana Abramova
Keyword(s):  
Corrosion Inhibitors ◽  
Tribological Behavior ◽  
Surface Layers ◽  
Physical Chemical ◽  
Abrasive Finishing ◽  
Alloying Additives ◽  
Phosphorus Containing ◽  
Micro Emulsion ◽  
Property Control ◽  
Diamond Abrasive

There is carried out a number of experiments with the purpose of analyzing SOTS impact upon both finishing productivity, and physical-chemical state and tribological behavior of surfaces machined, and also a possibility for creation according to the results of the investigations carried out a relatively universal micro-emulsion SOTS based on existing in the Ukraine the line of oils, PAV, corrosion inhibitors, alloying additives etc. As SOTS samples there were used both well-known compouds, for example, Camix, Nope Right (USA), and carbamide having in its structure boron, boron-phosphorus-containing additive, water-solvable phosphate, tributyl phosphate (oil-solvable), concentrate SOTS tribol, having in its structure compounds of boron, nitrogen and phosphorous; ethylic ether of fatty acids; methyl ether of colza oil; Sarkozyl-O having in its structure easily-decomposable chlorine compounds. From the results obtained it is possible to draw a conclusion that during finishing in the environment of water-compatible SOTS an important role in the formation of the properties of the surface worked is played by hydrocarbon components and additives which contribute to the formation of the thinnest surface layers modified with carbon and oxygen.

scholarly journals STRUCTURAL AND PHASE CHANGES OF THE SURFACE LAYERS OF HEATRESISTANT MULTICOMPONENT COATING OF ION-PLASMA COATING Ni-Cr-Al-Y AFTER MODIFICATION BY HIGH-CURRENT ELECTRON BEAMS MICROSECOND DURATION

2020 ◽  
Vol 17 (34) ◽  
pp. 459-468
Author(s):  
Oksana A BYTSENKO ◽  
Igor G STESHENKO ◽  
Vladimir A PANOV ◽  
Victor V TISHKOV ◽  
Alexey B MARKOV
Keyword(s):  
Electron Beams ◽  
Structural Phase ◽  
Plasma Coating ◽  
Phase Changes ◽  
High Current ◽  
Surface Layers ◽  
Heat Resistant ◽  
Ion Plasma ◽  
Current Electron ◽  
High Current Electron

The development of aerospace engineering and mechanical engineering directly depends on the development of new metal materials and advanced technologies. The problem of creating materials and their types of processing to increase the level of operational properties is relevant in connection with the complication and tightening of working conditions of modern technologies. One of the most important tasks of contemporary aircraft construction is to increase the operational properties of the surface layer. The purpose of the article is to elucidate the effect of high-current electron beams of microsecond duration on changes in the surface layers of the heat-resistant multicomponent ion-plasma coating Ni-Cr-Al-Y under various conditions. Using a complex of metallophysical research methods, the physicochemical and structural-phase states of the surface layer were studied before and after modification of the samples. These samples were coated with heat-resistant condensed ion-plasma coatings of three different compositions using nine high-current electron beams in 9 modes with different values of electron energy and number of pulses in the selected interval of electron energy. An analysis of the structural phase changes occurring during modification was carried out. Cylindrical samples of targets made of heat-resistant nickel alloy ZhS36 coated with ion-plasma condensed multicomponent coating SDP-2 + VSDP-16. These samples were used according to serial technology, both with subsequent modification using highcurrent electron beams and without modification. It was found that chromium in the initial state is unevenly distributed: chromium is present in the particles; the matrix is depleted in chromium. The research results can be useful for scientists to study the properties of heat-resistant multicomponent ion-plasma coatings Ni-Cr-Al-Y and the effect of high-current electron beams on it, as well as for the manufacture of more heat-resistant materials in aerospace engineering and mechanical engineering.

scholarly journals Changes in structural-phase state and physicochemical properties of tungsten-free TIC-TiNi hard alloys after various types of ion-beam treatment

2021 ◽  
pp. 5-9
Author(s):  
V. V. Akimov ◽  
◽  
A. M. Badamshin ◽  
S. N. Nesov ◽  
S. N. Povoroznyuk ◽  
...  
Keyword(s):  
Physicochemical Properties ◽  
Phase State ◽  
Ion Beam ◽  
Structural Phase ◽  
Experimental Methods ◽  
Hard Alloys ◽  
Surface Layers ◽  
Initial State ◽  
Structural Phase State ◽  
Ion Beam Treatment

Using experimental methods of analysis, the morphology, elemental composition and chemical state of hard alloys of the «TiC-TiNi» system in the initial state and after various types of ion-beam treatment have been investigated. It is found that the effect of a continuous ion beam leads to an increase in the microhardness of the investigated alloys by 10–12 %. When samples are irradiated with a pulsed ion beam, as a result of destruction of surface layers, the microhardness value decreases by 20 %, as a result of which this type of modification is not preferable for alloys of the TiC-TiNi system

Effect of diamond dressing on the state of the surface layers of high-speed steel cutting tools

1972 ◽  
Vol 4 (6) ◽  
pp. 516-518
Author(s):  
V. Ya. Bulanov ◽  
A. P. Shevel ◽  
P. A. Yudkovskii
Keyword(s):  
High Speed ◽  
Cutting Tools ◽  
High Speed Steel ◽  
The State ◽  
Surface Layers ◽  
Steel Cutting

Features of damage and modification of surface layers of Al and its alloys by powerful energy flows in a plasma focus device

2021 ◽  
Vol 9 ◽  
pp. 34-52
Author(s):  
V. N. Pimenov ◽  
◽  
S.A. Maslyaev ◽  
Keyword(s):  
Surface Layer ◽  
Plasma Focus ◽  
Phase State ◽  
Structural Phase ◽  
Pulsed Laser ◽  
Plasma Focus Device ◽  
Deuterium Plasma ◽  
Surface Layers ◽  
Pulsed Laser Radiation ◽  
Structural Phase State

The results of the analysis of damageability and modification of the structural-phase state of the surface layers of aluminum and its alloys by powerful flows of fast high-energy ions and high-temperature plasma in Plasma focus devices, as well as using pulsed laser radiation. Pure Al, an alloy of the Al – Mg – Li system, a duralumin alloy, and a composition of a ceramic coating Al2O3 on an Al substrate are considered. It is shown that in the regime of Al irradiation with a power density of q ≈ 106 – 107 W/cm2 in the nano- and microsecond range of pulse durations, ultrafast crystallization of melted surface layer occurs with the formation of a wavy surface relief and the structural fragments of sub-microcrystalline and nanoscale size. After the action of deuterium plasma flows on a duralumin alloy tube located along the axis of the Plasma focus device a modification of the structural-phase state of the alloy is observed: the initial two-phase state of an αAl-solid solution of copper in aluminum and inclusions of the second phase of CuAl2 became fine-grained and single-phase due to the dissolution of CuAl2 particles in the melt. Irradiation of an alloy of the Al – Mg – Li system containing (wt %) 2 % Li and 5 % Mg at q = 5·106 W/cm2, t = 50 – 100 ns after four pulsed impacts of fast ions and deuterium plasma led to the modification the structural-phase state of the surface layer of the alloy, associated with an increase in the content of magnesium oxide and a decrease in the crystal lattice parameter of the Al-based solid solution. The formation of spherical cavities due to the evaporation of lithium into the internal micropores of the surface layer was also found. The low damage and structural stability of Al2O3 ceramics on an Al substrate under beam-plasma impacts in plasma focus device with a radiation power density q ≤ 108 – 109 W/cm2 in the nano- and microsecond range of pulse duration is noted. At the same time, the Al2O3/Al composition was unstable to pulsed laser radiation in the free-running mode (q = 105 – 106 W/cm2, t = 0.7 ms) and Q-switch mode (q = 107 – 108 W/cm2, t = 80 ns). In both cases the coating peeled off from the substrate.

Study of the Influence of Technological Factors on the Surface Structure of Aluminum 6000 Series Alloys Ingots

2020 ◽  
Vol 299 ◽  
pp. 938-942
Author(s):  
Leonid Moiseevich Gurevich ◽  
Dmitri Pronichev ◽  
Aleksey Serov
Keyword(s):  
Chemical Composition ◽  
Oxide Film ◽  
Surface Structure ◽  
The State ◽  
Ingot Surface ◽  
Surface Layers ◽  
Technological Factors ◽  
Light Color

The structure and chemical composition of the surface layers of aluminum 6000-series alloys after crystallization and homogenization annealing at 580 °C were investigated. It is shown that the state of the surface significantly depends on the presence of impurities in the coolant of the crystallizer, which deteriorate the continuity of the oxide film, which leads to the formation of light color of individual parts of the ingot surface.

Gradient Structures and Internal Stress Fields in Surface Layers of Products Made of Steel 0.35C-1Cr-1Mn-1Si after Turning

2014 ◽  
Vol 1013 ◽  
pp. 170-175 ◽  
Author(s):  
Aleksandr Smirnov ◽  
Nikolai Ababkov ◽  
Aleksandra Glinka
Keyword(s):  
Heat Treatment ◽  
Internal Stress ◽  
Structural Phase ◽  
Nondestructive Method ◽  
Stress Fields ◽  
Surface Layers ◽  
Acoustic Characteristics ◽  
Phase Condition ◽  
Internal Stress Field

The effect of different cutting (mechanical heat treatment) on the structural-phase condition and the internal stress field in the surface layers of the product is considered in the article. The regularities of acoustic characteristics depending on the parameters of the structure and stress for the development of nondestructive method for assessing the quality of the surface layer are identified

Formation of Nano-Sized Structural-Phase States in Surface Layers of a Cermet Alloy and the Influence of the States on the Tool Life of Cermet Plates in Metal Cutting

2015 ◽  
Vol 770 ◽  
pp. 144-150
Author(s):  
V.E. Ovcharenko ◽  
Yuriy F. Ivanov ◽  
A.A. Mohovikov ◽  
A.S. Ignatyev ◽  
Yu Baohai ◽  
...  
Keyword(s):  
Surface Layer ◽  
Tool Life ◽  
Metal Cutting ◽  
Structural Phase ◽  
High Energy ◽  
High Energy Electron ◽  
Surface Layers ◽  
Discharge Plasmas ◽  
Profound Influence ◽  
Cermet Alloy

A comparative analysis of the surface-layer microstructure of a tungsten-based cermet alloy modified with pulsed high-energy electron beams generated by gas-discharge plasmas and of the tool life of metal-cutting plates prepared from this alloy is performed. The choice of a plasma-forming gas providing for the emission of electrons out of the plasma-filled cathode is shown to have a profound influence both on the formation process of nanosized structural-phase states in the surface layer of the cermet alloy and on the tool life of the metal-cutting plates prepared from this alloy.

Destruction of Epoxy Coatings under the Influence of Climatic Factors

2013 ◽  
Vol 199 ◽  
pp. 581-586 ◽  
Author(s):  
Danuta Kotnarowska
Keyword(s):  
Surface Roughness ◽  
Environmental Factors ◽  
Climatic Factors ◽  
Incidence Angle ◽  
Surface Layers ◽  
Coating Structure ◽  
Epoxy Coatings ◽  
Coating Surface ◽  
Light Incidence Angle ◽  
Structure Destruction

The paper presents investigation results of climatic as well as environmental factors influence on surface state of three-layer epoxy coatings. A three-year investigation documented substantial destruction of coating surface layers. In particular, a significant increase of aged coating surface roughness, evaluated on the basis of Ra and Rz parameters, was observed. Studies made with SEM corroborated a delamination as well as pigment and filler crumbling from surface layers of coatings. In the final period of ageing craters and superficial cracks appeared in the coating structure. Destruction of aged coating surfaces contributed to their gloss loss by over 98% (for light incidence angle α = 60o) decreasing in this way coating decorative properties.

scholarly journals Structural-Phase State of Surface Layers of Cu–39Zn–1Pb Brass After High-Frequency Impact Treatment in Liquid Nitrogen

2019 ◽  
Vol 41 (12) ◽  
pp. 1611-1629 ◽  
Author(s):  
M. O. Vasylyev ◽  
◽  
B. M. Mordyuk ◽  
S. M. Voloshko ◽  
A. P. Burmak ◽  
...  
Keyword(s):  
Liquid Nitrogen ◽  
High Frequency ◽  
Phase State ◽  
Structural Phase ◽  
Surface Layers ◽  
Structural Phase State
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