scholarly journals Evaluation Method of Emulsion Using Chemical Oxygen Demand

2021 ◽  
Vol 333 ◽  
pp. 11009
Author(s):  
Kaiki Amagu ◽  
Riho Okajima ◽  
Moe Shimizu ◽  
Makoto Nishimoto ◽  
Kazuhito Nagayama ◽  
...  

The “gas–liquid two-phases mixed flow” mechanism that fine bubble generation uses rapidly swirling water, which shear gas and making small bubbles in water. Based on this mechanism, sending liquid such as oil into the swirling water instead of gas and it able to be emulsified. At present, evaluation methods for emulsions are using particle size distribution and dispersion stability. However, the emulsion with bad separation behavior has a problem to catch only some dispersed oil particles and use them as a whole evaluation. In this study we examined emulsion evaluated by chemical oxygen demand (COD) to express numerical evaluation including the oil particles that cannot be dispersed. Using three emulsions of only one oil, an anionic and a nonionic emulsifier were mixed and added to the oil, an anionic and another kind of the nonionic emulsifier were mixed and added to the oil. It was confirmed that COD decreased and type of only one oil was the most evaporate. These results lead to the conclusion that the performance of the emulsion could be expressed numerically, including the oil particles which could not be dispersed. We also directly analyzed evaporate components and compared them with COD results.

2014 ◽  
Vol 13 (1) ◽  
pp. 43-50 ◽  
Author(s):  
Ghasem Najafpour Darzi ◽  
Reza Katal ◽  
Hossein Zare ◽  
Seyed Omid Rastegar ◽  
Poorya Mavaddat

2018 ◽  
Vol 69 (10) ◽  
pp. 2940-2952 ◽  
Author(s):  
Martina Zelenakova ◽  
Pavol Purcz ◽  
Radu Daniel Pintilii ◽  
Peter Blistan ◽  
Petr Hlustik ◽  
...  

Evaluating trends in water quality indicators is a crucial issue in integrated water resource management in any country. In this study eight chemical and physical water quality indicators were analysed in seven river profiles in the River Laborec in eastern Slovakia. The analysed water quality parameters were biochemical oxygen demand (BOD5), chemical oxygen demand (CODCr), pH, temperature (t), ammonium nitrogen (NH4+-N), nitrite nitrogen (NO2--N), nitrate nitrogen (NO3--N), and total phosphorus (TP). Data from the monitored indicators were provided by the Ko�ice branch of the Slovakian Water Management Company, over a period of 15 years from 1999 to 2013. Mann�Kendall non-parametric statistical test was used for the trend analysis. Biochemical and chemical oxygen demand, ammonium and nitrite nitrogen content exhibit decreasing trends in the River Laborec. Decreasing agricultural activity in the area has had a significant impact on the trends in these parameters. However, NO2--N was the significant parameter of water quality because it mostly exceeds the limit value set in Slovak legislation, Regulation No. 269/2010 Coll. In addition, water temperature revealed an increasing trend which could be caused by global increase in air temperature. These results indicate that human activity significantly impacts the water quality.


1978 ◽  
Vol 5 (1) ◽  
pp. 83-97 ◽  
Author(s):  
Robert D. Cameron

The use of cheap, locally available peat as a treatment method for landfill leachate was investigated by passing leachate through plexiglass columns filled with an amorphous-granular peat. Preliminary adjustment of pH showed that reducing pH to 4.8 dramatically reduced adsorption. Increasing the pH to 8.4, metal removal was increased owing to filtration of precipitated metals. The best adsorption of metals occurred at the 'natural' pH of 7.1. Manganese was found to be the limiting pollutant. At the 0.05 mg/ℓ maximum acceptable manganese concentration 94% of the total metals were removed, requiring 159 kg of peat per 1000 ℓ of leachate.Resting the peat for 1 month did significantly increase removal capacity.Desorption of some contaminants occurred when water was percolated through the peat. The desorption test effluent was not toxic to fish although iron, lead and COD (chemical oxygen demand) exceeded acceptable values.Chemical pretreatment using lime and ferric chloride achieved significant iron, manganese and calcium removals. Chemical pretreatment followed by peat adsorption offered no advantage other than reducing toxicity to fish.Peat treatment alone was effective in reducing concentrations to a level that was non-toxic to fish.


2019 ◽  
Vol 17 (1) ◽  
pp. 1017-1025
Author(s):  
Mohamed Réda Arhoutane ◽  
Muna Shueai Yahya ◽  
Miloud El Karbane ◽  
Kacem El Kacemi

AbstractIn the context of environmental protection, where there is a need to develop effective operations for carrying out appropriate treatment of polluted water by pharmaceuticals. Therefore, the present study aims at evaluating the degradation for gentamicin through electro-Fenton (EF) operation, through taking into consideration the effect of several parameters of experimental in the process, namely, the concentration of initial gentamicin, the applied current and the Fe+2 (II) quantities. The (EF) operation employed involves a carbon-felt as cathode and platinum as anode at pH 3. Studies for the gentamicin kinetics is monitored by HPLC giving a pseudo-first order reaction following by a chemical oxygen demand, with a reached degree of mineralization 96% after of four hours of treatment through current 100 mA/cm2 with 0.1 mM of Fe+2. We find that the degradation for molecule of gentamicin is accompanied by an augmentation of the biodegradability, assesse through the Biochemical Oxygen Demand (BOD5) on chemical oxygen demand (COD) ratio, that augmentation from 0 to 0.41 before treatment after 30 min for EF treatment, showing that there is potential for conjugation of the EF process and the biological process. Furthermore, the by-products have been identified on the basis of HPLC-MS/MS results.


Water ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 21
Author(s):  
Ilaria Piccoli ◽  
Giuseppe Virga ◽  
Carmelo Maucieri ◽  
Maurizio Borin

Constructed wetlands (CWs) represent a green technology for digestate liquid fraction (DLF) treatment. However, previous research has warned about their performance when treating wastewater with high suspended solid and organic loads. In addition, the high NH4-N concentration typical of this wastewater can compromise vegetation establishment and activity. In view of this, a digestate pretreatment is needed. This study aimed to test the performance of filters filled with recovery materials, such as brick and refractory material, for DLF pretreatment. The effect on DLF physical (electrical conductivity, pH, dissolved oxygen, and temperature) and chemical (total nitrogen, ammonia–nitrogen, nitrate–nitrogen, total phosphorus, soluble phosphorus, and chemical oxygen demand) characteristics was monitored during eight weekly cycles. The effect of filtration on total nitrogen and ammonia–nitrogen removal began after about one month of loading, suggesting that an activation period is necessary for bacteria. For effective N removal, the presence of multiple digestate recirculations per day through the filters appears mandatory to guarantee the alternation of nitrification and denitrification conditions. For P removal, filling material particle size appeared to be more important than its composition. Unclear performances were observed considering chemical oxygen demand. Further studies on filling media and microbial community interactions, and the long-term efficiency of filters, are desirable.


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