Carbon-silica composites with nanoporous structures were synthesized for the adsorption of volatile organic compounds (VOCs), taking tetraethyl orthosilicate (TEOS) as the silicon source and activated carbon powder as the carbon source. The preparation conditions were as follows: the pH of the reaction system was 5.5, the hydrophobic modification time was 50 h, and the dosage of activated carbon was 2 wt%. Infrared spectrum analysis showed that the activated carbon was dispersed in the pores of aerogel to form the carbon-silica composites material. The static adsorption experiments, dynamic adsorption-desorption experiments, and regeneration experiments show that the prepared carbon-silica composites have microporous and mesoporous structures, the adsorption capacity for n-hexane is better than that of conventional hydrophobic silica gel, and the desorption performance is better than that of activated carbon. It still has a high retention rate of adsorption capacity after multiple adsorption-desorption cycles. The prepared carbon-silica composites material has good industrial application prospects in oil vapor recovery, providing a new alternative for solving organic waste gas pollution.
Adsorption–Desorption Rate of Nonpolar Volatile Organic Compounds onto Activated Carbon Exemplified by C6H6 and CCl4
