Broadband absorption and photothermal conversion in titanium diboride

2020 ◽  
Author(s):  
Saju K. John ◽  
Aji A. Anappara
2020 ◽  
Vol 21 (12) ◽  
pp. 4224
Author(s):  
Wenxiu Yang ◽  
Yonggui Li ◽  
Long Feng ◽  
Yimiao Hou ◽  
Shuo Wang ◽  
...  

Photothermal conversion materials have attracted wide attention due to their efficient utilization of light energy. In this study, a (GO)/Bi2S3-PVDF/TPU composite nanofiber membrane was systematically developed, comprising GO/Bi2S3 nanoparticles (NPs) as a photothermal conversion component and PVDF/TPU composite nanofibers as the substrate. The GO/Bi2S3 NPs were synthesized in a one-step way and the PVDF/TPU nanofibers were obtained from a uniformly mixed co-solution by electrospinning. GO nanoparticles with excellent solar harvesting endow the GO/Bi2S3-PVDF/TPU membrane with favorable photothermal conversion. In addition, the introduction of Bi2S3 NPs further enhances the broadband absorption and photothermal conversion properties of the GO/Bi2S3-PVDF/TPU composite membrane due to its perfect broadband absorption performance and coordination with GO. Finally, the results show that the GO/Bi2S3-PVDF/TPU composite membrane has the highest light absorption rate (about 95%) in the wavelength range of 400–2500 nm. In the 300 s irradiation process, the temperature changes in the GO/Bi2S3-PVDF/TPU composite membrane were the most significant and rapid, and the equilibrium temperature of the same irradiation time was 81 °C. Due to the presence of TPU, the mechanical strength of the composite film was enhanced, which is beneficial for its operational performance. Besides this, the morphology, composition, and thermal property of the membranes were evaluated by corresponding test methods.


Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1872
Author(s):  
Buxiong Qi ◽  
Wenqiong Chen ◽  
Tiaoming Niu ◽  
Zhonglei Mei

A full-spectrum near-unity solar absorber has attracted substantial attention in recent years, and exhibited broad application prospects in solar thermal energy conversion. In this paper, an all-metal titanium (Ti) pyramid structured metamaterial absorber (MMA) is proposed to achieve broadband absorption from the near-infrared to ultraviolet, exhibiting efficient solar-selective absorption. The simulation results show that the average absorption rate in the wavelength range of 200–2620 nm reached more than 98.68%, and the solar irradiation absorption efficiency in the entire solar spectrum reached 98.27%. The photothermal conversion efficiency (PTCE) reached 95.88% in the entire solar spectrum at a temperature of 700 °C. In addition, the strong and broadband absorption of the MMA are due to the strong absorption of local surface plasmon polariton (LSPP), coupled results of multiple plasmons and the strong loss of the refractory titanium material itself. Additionally, the analysis of the results show that the MMA has wide-angle incidence and polarization insensitivity, and has a great processing accuracy tolerance. This broadband MMA paves the way for selective high-temperature photothermal conversion devices for solar energy harvesting and seawater desalination applications.


2018 ◽  
Author(s):  
Y. H. Kan ◽  
Changying Zhao ◽  
Zhuomin M. Zhang

2020 ◽  
Vol 59 (11) ◽  
pp. 110906
Author(s):  
Juan Shen ◽  
Yong Ren ◽  
Xinxin Zhu ◽  
Min Mao ◽  
Quan Zhou ◽  
...  

Molecules ◽  
2020 ◽  
Vol 25 (4) ◽  
pp. 781
Author(s):  
Ernesto Enríquez-Palacios ◽  
Teresa Arbeloa ◽  
Jorge Bañuelos ◽  
Claudia I. Bautista-Hernández ◽  
José G. Becerra-González ◽  
...  

Herein we report on a straightforward access method for boron dipyrromethene dyes (BODIPYs)-coumarin hybrids linked through their respective 8- and 6- positions, with wide functionalization of the coumarin fragment, using salicylaldehyde as a versatile building block. The computationally-assisted photophysical study unveils broadband absorption upon proper functionalization of the coumarin, as well as the key role of the conformational freedom of the coumarin appended at the meso position of the BODIPY. Such free motion almost suppresses the fluorescence signal, but enables us to apply these dyads as molecular rotors to monitor the surrounding microviscosity.


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