Reactions with half-lives of several years
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The gas-phase thermal decomposition of dimethyldiazirine, (CH3)2CN2, at very slow rates has been investigated using precision gas-volumetric techniques previously applied to second virial coefficient studies. At 50-70� the first-order kinetics correspond to half-lives about 0.3-3.0 years. The present results, together with data obtained by other workers using conventional apparatus at 124-174�, fit a single log rate-reciprocal temperature activation energy equation.
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1949 ◽
Vol 198
(1053)
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pp. 285-292
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1992 ◽
Vol 73
(5)
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pp. 1939-1945
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1947 ◽
Vol 25b
(2)
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pp. 135-150
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