Temperature dependence of chlorine-35 N.Q.R. in 2,6-Dichlorophenol

1978 ◽  
Vol 31 (4) ◽  
pp. 791 ◽  
Author(s):  
R Chandramani ◽  
SP Basavaraju ◽  
N Devaraj
Keyword(s):  
Temperature Dependence ◽  
Room Temperature ◽  
Temperature Range ◽  
Temperature Coefficients ◽  
Brown's Method

Chlorine n.q.r, in 2,6-dichlorophenol has been investigated at temperatures from 77 K to room temperature. Two resonance lines due to chemically inequivalent sites have been observed throughout this temperature range. Torsional frequencies of the molecule have been calculated at temperatures from 77 to 300 K according to Bayer's theory and Brown's method. Also the temperature coefficients of the torsional frequencies have been calculated.

NQR and Crystal Structure of 4,5-Dichloroimidazole, C3H2N2Cl2

1992 ◽  
Vol 47 (1-2) ◽  
pp. 177-181 ◽  
Author(s):  
Shi-Qi Dou ◽  
Alarich Weiss
Keyword(s):  
Crystal Structure ◽  
Phase Transition ◽  
Temperature Dependence ◽  
Room Temperature ◽  
Unit Cell ◽  
Space Group ◽  
Temperature Range ◽  
Temperature Coefficients ◽  
Group D

AbstractThe two line 35Cl NQR spectrum of 4,5-dichloroimidazole was measured in the temperature range 77≦ T/K ≦ 389. The temperature dependence of the NQR frequencies conforms with the Bayer model and no phase transition is indicated in the curves v ( 35Cl)= f(T). Also the temperature coefficients of the 35Cl NQR frequencies are "normal". At 77 K the 35Cl NQR frequencies are 37.409 MHz and 36.172 MHz and at 389 K 35.758 MHz and 34.565 MHz. The compound crystallizes at room temperature with the tetragonal space group D44-P41212, Z = 8 molecules per unit cell; at 295 K : a = 684.2(5) pm, c = 2414.0(20) pm. The relations between the crystal structure and the NQR spectrum are discussed.

Temperature-dependence of 35Cl N.Q.R. in sodium chloroacetate

1976 ◽  
Vol 29 (11) ◽  
pp. 2363 ◽  
Author(s):  
R Chandramani ◽  
N Devaraj ◽  
VSS Sastry ◽  
J Ramakrishna
Keyword(s):  
Temperature Dependence ◽  
Temperature Coefficient ◽  
Room Temperature ◽  
Single Line ◽  
Temperature Range ◽  
Brown's Method

N.q.r. in sodium chloroacetate has been investigated at temperatures from 77 K to room temperature (c.300 K). A single line has been observed throughout this temperature range. Torsional frequencies of the molecule have been calculated in the above temperature range from Bayer's theory. Also the temperature coefficient of the torsional frequencies has been calculated by Brown's method.

scholarly journals PSEUDO-GAP FEATURES OF INTRINSIC TUNNELING IN (HgBr2)-Bi2212 SINGLE CRYSTALS

1999 ◽  
Vol 13 (29n31) ◽  
pp. 3758-3763 ◽  
Author(s):  
AUGUST YURGENS ◽  
DAG WINKLER ◽  
TORD CLAESON ◽  
SEONG-JU HWANG ◽  
JIN-HO CHOY
Keyword(s):  
Temperature Dependence ◽  
Single Crystals ◽  
Room Temperature ◽  
Unit Cell ◽  
Superconducting Gap ◽  
Axis Direction ◽  
Temperature Range ◽  
Dynamic Conductance

The c-axis tunneling properties of both pristine Bi2212 and its HgBr 2 intercalate have been measured in the temperature range 4.2-250 K. Lithographically patterned 7-10 unit-cell heigh mesa structures on the surfaces of these single crystals were investigated. Clear SIS-like tunneling curves for current applied in the c-axis direction have been observed. The dynamic conductance d I/ d V(V) shows both sharp peaks corresponding to a superconducting gap edge and a dip feature beyond the gap, followed by a wide maximum, which persists up to a room temperature. Shape of the temperature dependence of the c-axis resistance does not change after the intercalation suggesting that a coupling between CuO 2-bilayers has little effect on the pseudogap.

scholarly journals TEMPERATURE DEPENDENCE OF CONDUCTIVITYOF UREASE DOPED POLYPYRROLE MATERIAL

2021 ◽  
Vol 9 (6) ◽  
pp. 85-90
Author(s):  
Munish Pandey ◽  
Richa Badlani
Keyword(s):  
Infrared Spectroscopy ◽  
Temperature Dependence ◽  
Room Temperature ◽  
Chemical Oxidation ◽  
Oxidation Method ◽  
Temperature Range ◽  
The Matrix

In polymerization of was carried out in the presence of to synthesize – composites by chemical oxidation method. The / have been synthesized with various compositions (10, 15, 20, 25 and 30 ) of in in aquas medium at room temperature. The – composites were characterized by infrared spectroscopy (IR). The d.c. conductivity was studied in the temperature range from 40–100°C. The dimensions of in the matrix have a greater influence on the observed conductivity values.

Plastic Deformations in L10-Ordered Single Crystals with their c/a Ratios Less than Unity

2007 ◽  
Vol 561-565 ◽  
pp. 459-462
Author(s):  
Katsushi Tanaka ◽  
Hiromitsu Ide ◽  
Yoshinori Sumi ◽  
Kyosuke Kishida ◽  
Haruyuki Inui
Keyword(s):  
Shear Stress ◽  
Temperature Dependence ◽  
Single Crystals ◽  
Room Temperature ◽  
The Other ◽  
Compressive Deformation ◽  
Positive Temperature ◽  
Plastic Deformations ◽  
Temperature Range ◽  
Critical Resolved Shear Stress

Compressive deformation of L10-ordered single crystals of FePd whose c/a ratio less than unity have been investigated from room temperature to 823 K. The results show that the critical resolved shear stress (CRSS) for octahedral glide of ordinary dislocations is smaller than that of super-lattice dislocations in all the temperature range investigated, that is the opposite sense to the case of Ti-56 mol% Al. The CRSS for ordinary dislocations virtually independent to the temperature. On the other hand, the CRSS for super dislocations exhibits a weak positive temperature dependence from room temperature up to 573 K and decreases in higher temperatures.

Temperature Dependence of the Diffusion of 1,2-Dichloroethane, 1,1,1-Trichloroethane, Trichloroethylene, and Tetrachloroethylene in Air

1971 ◽  
Vol 49 (11) ◽  
pp. 1965-1967 ◽  
Author(s):  
Harry Watts
Keyword(s):  
Temperature Dependence ◽  
Diffusion Coefficients ◽  
Room Temperature ◽  
Evaporation Method ◽  
Temperature Range ◽  
Boiling Points ◽  
Rate Of Evaporation

The diffusion coefficients in air of 1,1-dichloroethane, 1,1,1-trichloroethane, trichloroethylene, and tetrachloroethylene have been measured over a temperature range from room temperature to close to their boiling points by a rate of evaporation method.

Temperature dependence of piezoelectric properties of 0.67 Pb(Mg1/3Nb2/3)O3–0.33 PbTiO3 single crystals

2003 ◽  
Vol 18 (2) ◽  
pp. 537-541 ◽  
Author(s):  
Ping-chu Wang ◽  
Xiao-ming Pan ◽  
Dong-lin Li ◽  
Yuan-wei Song ◽  
Hao-su Luo ◽  
...  
Keyword(s):  
Phase Transition ◽  
Transition Temperature ◽  
Temperature Dependence ◽  
Single Crystals ◽  
Phase Transition Temperature ◽  
Room Temperature ◽  
Piezoelectric Properties ◽  
Device Design ◽  
Temperature Range ◽  
Approach Zero

Piezoelectric properties k33 and d33 of 0.67 Pb(Mg1/3Nb2/3)O3–0.33 PbTiO3 single crystals grown by a modified Bridgman method were measured in the temperature range of 20–150 °C. Recoverability of the properties after the samples were heated to 110 °C, above the ferroelectric–ferroelectric (F–F) phase transition temperature of the composition, was found. From 20 to approximately 80 °C, k33 increases slightly, while d33 is almost doubled. Between approximately 90 and 100 °C, k33 decreases sharply to roughly a level of PZT-5 ceramics and d33 decreases to about 700 pC/N. They increase again with further increase of temperature; at 140 °C they attain 0.74 and approximately 1300 pC/N, respectively, and then decrease quickly and approach zero at about 150 °C. When heating to 110 °C followed by cooling to room temperature, the property decay is small. After more than one dozen heating–cooling cycles, k33 and d33 tend to be stable at 0.89 and approximately 1220 pC/N, respectively. The results might be helpful for device design and applications of PMN–PT single crystals.

Erbium Implantation in Silicon: A Way Towards Si-Based Optoelectronics

1993 ◽  
Vol 316 ◽  
Author(s):  
F. Priolo ◽  
G. Franzó ◽  
S. Coffa ◽  
A. Polman ◽  
V. Bellani ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Recent Work ◽  
Luminescence Intensity ◽  
Room Temperature ◽  
Temperature Range ◽  
Excitation Processes ◽  
Co Doped ◽  
Electro Luminescence

ABSTRACTIn this paper our recent work on erbium implantation for optical doping of silicon is reviewed. It is shown that O co-implantation plays a key role both in providing Er with the appropriate chemical surrounding and in allowing the incorporation of high Er concentrations in thick Si layers without the formation of twins and/or precipitates. The luminescence intensity in Er and O co-implanted samples shows a much weaker temperature dependence (a decrease by a factor of 30 from 77K to 300K) than in samples without O (a decrease by 3 orders of magnitude in the same temperature range). This allowed us to observe room temperature photo- and electro-luminescence in Er and O co-doped samples. The temperature dependence of the luminescence in these samples has been determined to be due to non-radiative de-excitation processes. These data are reported and discussed.

scholarly journals Evaluation of Magnetostriction of the Single-Variant Ni-Mn-Ga Martensite

2009 ◽  
Vol 635 ◽  
pp. 131-136 ◽  
Author(s):  
Victor A. L'vov ◽  
Ilya Glavatskyy ◽  
Nadiya Glavatska
Keyword(s):  
Elastic Modulus ◽  
Martensitic Transformation ◽  
Temperature Dependence ◽  
Electric Conductivity ◽  
Phase Stability ◽  
Room Temperature ◽  
Landau Theory ◽  
Magnetostrictive Material ◽  
Temperature Range ◽  
Shear Elastic Modulus

The temperature dependence of ordinary magnetostriction of the axially compressed Ni–Mn–Ga alloy with the low values of shear elastic modulus C'(T) ~ 1 – 10 GPa has been evaluated theoretically in the framework of Landau theory. The computations showed that the compression with 50 MPa stress reduces the ordinary magnetostriction by factor 3 at room temperature. Nevertheless, the magnetostriction of compressed alloy exceeds the value of 10–4 in the whole temperature range of martensitic phase stability, strongly depends on the temperature in the vicinity of martensitic transformation (MT), and is practically constant well below MT temperature. Therefore, the purposeful search for the alloy with the low value of shear elastic modulus and high MT temperature (well above 300 K) may result in the discovery of good magnetostrictive material. This material will posses the temperature-independent magnetostriction value about of 10–4 –10–3 and rather low electric conductivity enabling the technical applications of this material in dynamic regimes.

Temperature dependence of the shape of the cellodextrins in aqueous solution

1967 ◽  
Vol 45 (20) ◽  
pp. 2363-2367 ◽  
Author(s):  
M. Ihnat ◽  
D. A. I. Goring
Keyword(s):  
Aqueous Solution ◽  
Temperature Dependence ◽  
Computational Methods ◽  
Negative Temperature ◽  
Temperature Range ◽  
Temperature Coefficients ◽  
Increasing Temperature

Intrinsic viscosities of the cellodextrins, cellobiose to cellohexaose, were measured in aqueous solution at temperatures from 25 to 70 °C. Axial ratios were determined using the Einstein–Simha viscosity relation and the computational methods developed previously. The results showed that the oligomers are fully extended over this temperature range and that the negative temperature coefficients of the intrinsic viscosities are caused by the dehydration of the molecules with increasing temperature.

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