scholarly journals A modification of the arcsine–log calibration curve for analysing soil test value–relative yield relationships

2017 ◽  
Vol 68 (3) ◽  
pp. 297 ◽  
Author(s):  
Adrián A. Correndo ◽  
Fernando Salvagiotti ◽  
Fernando O. García ◽  
Flavio H. Gutiérrez-Boem

This article aims to discuss the arcsine–log calibration curve (ALCC) method designed for the Better Fertiliser Decisions for Cropping Systems (BFDC) to calibrate relationships between relative yield (RY) and soil test value (STV). Its main advantage lies in estimating confidence limits of the critical value (CSTV). Nevertheless, intervals for 95% confidence level are often too wide, and authors suggest a reduction in the confidence level to 70% in order to achieve narrower estimates. Still, this method can be further improved by modifying specific procedures. For this purpose, several datasets belonging to the BFDC were used. For any confidence level, estimates with the modified ALCC procedures were always more accurate than the original ALCC. The overestimation of confidence limits with the original ALCC was inversely related to the correlation coefficient of the dataset, which might allow a relatively simple and reliable correction of previous estimates. In addition, because the method is based on the correlation between STV and RY, the importance to test it for significance is emphasised in order to support the hypothesis of a relationship. Then, the modified ALCC approach could also allow a more reliable comparison of datasets by slopes of the bivariate linear relationship between transformed variables.


2013 ◽  
Vol 64 (5) ◽  
pp. 539 ◽  
Author(s):  
M. K. Conyers ◽  
M. J. Bell ◽  
N. S. Wilhelm ◽  
R. Bell ◽  
R. M. Norton ◽  
...  

Soil testing remains a most valuable tool for assessing the fertiliser requirement of crops. The relationship between soil tests (generally taken from surface soil) and relative yield (RY) response to fertiliser is subject to the influence of environment (e.g. water, temperature) and management (e.g. cultivation, sowing date). As such, the degree of precision is often low when the soil test calibration is based on a wide range of independent experiments on many soil types over many years by many different operators. Hence, the 90% RY target used in soil test interpretation is best described by a critical range (critical concentration and confidence interval) for a given soil test rather than a single critical value. The present Better Fertiliser Decisions for Crops (BFDC) National Database, and the BFDC Interrogator that interacts with the database, provide a great advance over traditional formats and experiment-specific critical values because it allows the use of filters to refine the critical range for specific agronomic conditions. However, as searches become more specific (region, soil type) the quantity of data available to estimate a critical range becomes more vulnerable to data paucity, to outliers, and to clusters of localised experiments. Hence, appropriate training of the users of this database will ensure that the strengths and limitations of the BFDC National Database and BFDC Interrogator are properly understood. Additionally, the lack of standardised metadata for sites within the database makes it generally impossible to isolate the effects on critical values of the specific management or environmental factors listed earlier, which are therefore best determined by specific studies. Finally, the database is dominated (60%) by responses of wheat to nitrogen and phosphorus, meaning that relatively few studies are available for responses by pulses (other than narrow leaf lupins) or oilseeds (other than canola), especially for potassium and sulfur. Moreover, limited data are available for current cropping systems and varieties. However, the identification of these gaps can now be used to focus future research on the crops, nutrients, soils, regions, and management practices where data are lacking. The value of metadata and the need for standardised protocols for nutrition experiments were key lessons.



2013 ◽  
Vol 64 (5) ◽  
pp. 424 ◽  
Author(s):  
G. Watmuff ◽  
D. J. Reuter ◽  
S. D. Speirs

During the past 50 years, 3800 field experiments yielding over 5200 treatment series were conducted in Australia examining yield responses to applied N, P, K, or S fertiliser applications to cereal, oilseed and pulse crops. The experiments all had accompanying soil test data. These data were entered into multiple Microsoft Access® database templates and then consolidated into a single national online MYSQL® database. A web application (named the BFDC Interrogator) was also developed to rapidly access the national database (BFDC National Database) and construct soil test calibrations between percentage of the maximum grain yield achieved (hereafter called percentage relative yield) and soil test values recorded for specified ranges of regional or national experiments. Search parameters were applied to define soil test calibrations. These included farming system (dryland or irrigated), year of experiment, soil type, crop type, soil test, depth of soil sampling and soil test units. Other data filters based on site metadata, such as method of nutrient placement, can be applied to enable more definitive calibrations. The calibrations are used to derive critical soil test values at 80, 90 and 95% relative crop yield with 95% confidence limits. However, the soil test criteria at 90% relative crop yield with 70% confidence limits have been chosen as the single calibration and reliability standard for all crops and soil tests. Corresponding yield increase (t/ha)–soil test relationships for an applied nutrient can also be accessed. The BFDC National Database and BFDC Interrogator can now be accessed online by trained, registered users. This paper describes the methodologies that underpinned the progressive development of this tool. Through the commitment of the grains and fertiliser industries, it is anticipated that the calibrations will be used to improve decision support systems used to generate fertiliser recommendations for Australian cropping industries.



2002 ◽  
Vol 42 (2) ◽  
pp. 149 ◽  
Author(s):  
M. D. A. Bolland ◽  
W. J. Cox ◽  
B. J. Codling

Dairy and beef pastures in the high (>800 mm annual average) rainfall areas of south-western Australia, based on subterranean clover (Trifolium subterraneum) and annual ryegrass (Lolium rigidum), grow on acidic to neutral deep (>40 cm) sands, up to 40 cm sand over loam or clay, or where loam or clay occur at the surface. Potassium deficiency is common, particularly for the sandy soils, requiring regular applications of fertiliser potassium for profitable pasture production. A large study was undertaken to assess 6 soil-test procedures, and tissue testing of dried herbage, as predictors of when fertiliser potassium was required for these pastures. The 100 field experiments, each conducted for 1 year, measured dried-herbage production separately for clover and ryegrass in response to applied fertiliser potassium (potassium chloride). Significant (P<0.05) increases in yield to applied potassium (yield response) were obtained in 42 experiments for clover and 6 experiments for ryegrass, indicating that grass roots were more able to access potassium from the soil than clover roots. When percentage of the maximum (relative) yield was related to soil-test potassium values for the top 10 cm of soil, the best relationships were obtained for the exchangeable (1 mol/L NH4Cl) and Colwell (0.5 mol/L NaHCO3-extracted) soil-test procedures for potassium. Both procedures accounted for about 42% of the variation for clover, 15% for ryegrass, and 32% for clover + grass. The Colwell procedure for the top 10 cm of soil is now the standard soil-test method for potassium used in Western Australia. No increases in clover yields to applied potassium were obtained for Colwell potassium at >100 mg/kg soil. There was always a clover-yield increase to applied potassium for Colwell potassium at <30 mg/kg soil. Corresponding potassium concentrations for ryegrass were >50 and <30 mg/kg soil. At potassium concentrations 30–100 mg/kg soil for clover and 30–50 mg/kg soil for ryegrass, the Colwell procedure did not reliably predict yield response, because from nil to large yield responses to applied potassium occurred. The Colwell procedure appears to extract the most labile potassium in the soil, including soluble potassium in soil solution and potassium balancing negative charge sites on soil constituents. In some soils, Colwell potassium was low indicating deficiency, yet plant roots may have accessed potassum deeper in the soil profile. Where the Colwell procedure does not reliably predict soil potassium status, tissue testing may help. The relationship between relative yield and tissue-test potassium varied markedly for different harvests in each year of the experiments, and for different experiments. For clover, the concentration of potassium in dried herbage that was related to 90% of the maximum, potassium non-limiting yield (critical potassium) was at the concentration of about 15 g/kg dried herbage for plants up to 8 weeks old, and at <10 g/kg dried herbage for plants older than 10–12 weeks. For ryegrass, there were insufficient data to provide reliable estimates of critical potassium.



2014 ◽  
Vol 955-959 ◽  
pp. 1376-1379 ◽  
Author(s):  
Dan Wu ◽  
Kai Xiao Zhang

This paper researched the linear relationship between UV absorbance and concentrations of nitrobenzene. It used the UV-1700 UV/VIS spectroscopy to get the absorbance diagram and analyze it. Then it calculated the absorbance of maximum absorption peak and the absorbance integration in a wavelength interval. There is a linear relationship between absorbance and concentration, the correlation coefficient is 0.981 of the maximum absorption peaks and the concentrations, and the largest correlation coefficient between concentrations and the integration of absorbance is 0.995 with the wavelength interval of 235-245 nm, which is between the two absorption peaks of 210 nm and 270 nm. Therefore, it’s a good way to use integration of absorbance in the middle of two absorption peaks to measure the concentration of nitrobenzene, which is more accurate and reliable.



2017 ◽  
Vol 65 (2) ◽  
pp. 163-165
Author(s):  
MK Hasan ◽  
MA Hossain ◽  
A Sultana ◽  
M Shoeb ◽  
N Nahar

Diclofenac is a common and randomly used pharmaceutical product, was evaluated for its active ingredient by UV-Vis spectrophotometer at 282 nm. Diclofenac sodium of 50 mg dose of seven different companies of Bangladesh was extracted from the tablets, cleaned up and the active ingredient was evaluated. Evaluation was carried out with respect to calibration curve of standard diclofenac sodium. Amount of diclofenac in 50 mg tablets of seven different companies were found to be in the range of 47.91 ± 0.90 to 58.52 ± 0.41 mg. Recovery experiments were done by spiking excipient of the medicine at two different concentration levels with 5-7 replicate studies. Correlation coefficient (r2) was found to be 0.9974 and the recovery was103.39 ± 3.93 to 107.96 ± 3.56 % for the drug. Dhaka Univ. J. Sci. 65(2): 163-165, 2017 (July)



2021 ◽  
pp. 54-58
Author(s):  
E. G. Vinokurov ◽  
T. F. Burukhina ◽  
I. S. Kuroshev

The distribution of coatings by the frequency of their application during surface treatment by electrochemical methods is considered. This is important not only for understanding the structure of the electrochemical surface treatment sector, but also for identifying priority areas of scientific and technical research. Nonparametric statistical methods show the uniformity of samples and reveal the relationship between the number of enterprises that sell a certain type of coating, i.e. the frequency of applying a certain type of coating in different countries (USA, Japan, Italy, France, Germany, Great Britain, Spain, Canada, Mexico, Russia, South Africa). The results of testing the hypothesis of a close relationship between the ranks of coatings showed that a significant correlation was found between the distribution of coatings by the frequency of their application (implementation) among all countries. For example, when comparing the United States and Canada, the rank correlation coefficient is 0.62 (the lowest value obtained), which is greater than the calculated critical value of 0.56; when comparing Italy and Spain, the correlation coefficient takes the highest value of 0.97, which is greater than the critical value of 0.19. The results obtained allowed us to use this data to compile a generalized rating of the frequency of use of all coatings based on data from different countries. Based on the analysis, metal coatings can be arranged in a row according to the descending frequency of their application: Cr > Ni > Zn > Cu > Cd. The results of the ranking of coatings showed that the most commonly used electrochemical methods for surface treatment are metal coatings with chromium and nickel, and among the inorganic non – metallic coatings-oxide and then phosphate, which allows us to highlight the research devoted to the application of these coatings as priority areas of scientific and technical research.



2015 ◽  
Vol 43 (2) ◽  
pp. 355-360 ◽  
Author(s):  
Dogan ISIK ◽  
Adem AKCA ◽  
Emine KAYA ALTOP ◽  
Nihat TURSUN ◽  
Husrev MENNAN

Accurate assessment of crop-weed control period is an essential part for planning an effective weed management for cropping systems. Field experiments were conducted during the seasonal growing periods of potato in 2012 and 2013 in Kayseri, Turkey to assess critical period for weed control (CPWC) in potato. A four parameter log-logistic model was used to assist in monitoring and analysing two sets of related, relative crop yield. Data was obtained during the periods of increased weed interference and as a comparison, during weed-free periods. In both years, the relative yield of potato decreased with a longer period of weed-interference whereas increased with increasing length of weed free period. In 2012, the CPWC ranged from 112 to 1014 GDD (Growing Degree Days) which corresponded to 8 to 66 days after crop emergence (DAE) and between 135-958 GDD (10 to 63 DAE) in the following year based on a 5% acceptable yield loss. Weed-free conditions needed to be established as early as the first week after crop emergence and maintained as late as ten weeks after crop emergence to avoid more than 5% yield loss in the potato. The results suggest that CPWC could well assist potato producers to significantly reduce the expense of their weed management programs as well as improving its efficacy.



Age determinations on a portion of the total crushed rock, and on the felspar fraction of each of four widely separated samples of the red granite from the Bushveld complex are reported. A single determination from the separated biotite of one sample was made. These nine determinations lead to a mean age of 2.41 x 10 9 years [ t 1/2 = 6.3 x 10 10 years] or 1.92 x 10 9 years [ t 1/2 = 5.0 x 10 10 years]. There are no variations between individual determinations that are significant at the 99% confidence level. For the unweighted mean age the 99% confidence limits are ± 0.13 x 10 9 years. Despite the low enrichment of 87 Sr the ‘total rock ’ method shows 99% confidence limits of ± 0.22 x 10 9 years for the mean of four determinations.



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