Variation in Australian populations of Halfordia kendack s.l. (Rutaceae): evidence from leaf essential oils

2004 ◽  
Vol 17 (6) ◽  
pp. 571 ◽  
Author(s):  
Paul I. Forster ◽  
Joseph J. Brophy ◽  
Robert J. Goldsack
Keyword(s):  
Essential Oils ◽  
Species Distribution ◽  
Methyl Eugenol ◽  
The Other ◽  
Oil Composition ◽  
Altitudinal Range ◽  
Leaf Oil ◽  
Variable Species ◽  
Low Altitude

The leaf oils of Halfordia kendack (Montrouz.) Guillaumin s.l. from locations throughout its range in Australia were investigated to ascertain if the disjunct nature of the species' distribution affected their composition and whether any variation detected supported the recognition of a second species (H. scleroxyla F.Muell.). While three groups of populations could be classified on the basis of leaf oil composition, these groups were not associated with geographic locality or altitudinal range and habitat. It was found that plants from low altitude sites in north Queensland all produced leaf oils that contained the aromatic ethers methyl eugenol and elemicin in variable amounts, included in an otherwise terpenoid oil. Plants from the other three areas examined; north Queensland montane sites, south-east Queensland low altitude and south-east Queensland montane sites, all produced leaf oils which were terpenoid in nature and contained no aromatic ethers. This lack of correlation in leaf oil composition with locality or habitat would lend support to the proposition that Halfordia exists in only one variable species in Australia.

scholarly journals Composition and Antimicrobial Activity of the Leaf and Twig Oils of Litsea Mushaensis and L. linii from Taiwan

2010 ◽  
Vol 5 (11) ◽  
pp. 1934578X1000501
Author(s):  
Chen-Lung Ho ◽  
Eugene I-Chen Wang ◽  
Yen-Hsueh Tseng ◽  
Pei-Chun Liao ◽  
Chien-Nan Lin ◽  
...  
Keyword(s):  
Antimicrobial Activity ◽  
Essential Oils ◽  
Wood Decay ◽  
The Other ◽  
Fungal Activity ◽  
Leaf Oil ◽  
Main Components

The hydrodistilled essential oils of the leaves and twigs of Litsea mushaensis and L. linii were analyzed. Sixty-nine and ninety compounds were identified in the leaf and twig oils, respectively, of L. mushaensis. The main components of the leaf oil were β-eudesmol (24.2%), τ-cadinol (10.2%), α-humulene (10.1%), α-pinene (9.7%), and trans-β-ocimene (6.5%), whereas the main components of the twig oil were trans-β-ocimene (19.5%), α-pinene (12.8%) and cis-β-ocimene (7.7%). With L. linii, 72 and 78 compounds were respectively identified in the leaf and twig oils. The main components of the leaf oil were β-selinene (15.7%), α-selinene (15.5%), β-caryophyllene (12.2%), α-humulene (7.2%), and δ-cadinene (5.6%), and of the twig oil trans-β-ocimene (20.8%), β-selinene (11.4%), α-cadinol (6.0%), δ-cadinene (5.8%), τ-cadinol (5.4%) and β-eudesmol (5.2%). L. mushaensis leaf oil was shown to have excellent antimicrobial and anti-wood-decay fungal activity, superior to the other oils.

scholarly journals Composition and Chemical Variability of Ivoirian Xylopia staudtii Leaf Oil

2015 ◽  
Vol 10 (6) ◽  
pp. 1934578X1501000
Author(s):  
Thierry Acafou Yapi ◽  
Jean Brice Boti ◽  
Antoine Coffy Ahibo ◽  
Sylvain Sutour ◽  
Ange Bighelli ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Nmr Spectroscopy ◽  
Essential Oils ◽  
Oil Composition ◽  
Chemical Variability ◽  
Germacrene D ◽  
Leaf Oil ◽  
Nmr Techniques ◽  
C Nmr

The chemical composition of a leaf oil sample from Ivoirian Xylopia staudtii Engler & Diels (Annonaceae) has been investigated by a combination of chromatographic [GC(RI)] and spectroscopic (GC-MS, 13C NMR) techniques. Thirty-five components that accounted for 91.8% of the whole composition have been identified. The oil composition was dominated by the furanoguaiadienes furanoguaia-1,4-diene (39.0%) and furanoguaia-1,3-diene (7.5%), and by germacrene D (17.5%). The composition of twelve other leaf oil samples demonstrated qualitative homogeneity, but quantitative variability. Indeed, the contents of the major components varied substantially: furanoguaia-1,4-diene (24.7–51.7%) and germacrene D (5.9–24.8%). The composition of X. staudtii leaf oil is close to that of X. rubescens leaf oil but varied drastically from those of the essential oils isolated from other Xylopia species. 13C NMR spectroscopy appeared as a powerful and complementary tool for analysis of sesquiterpene-rich essential oils.

scholarly journals Chemical Composition and Insecticidal Properties of Essential Oils of Piper septuplinervium and P. subtomentosum (Piperaceae)

2014 ◽  
Vol 9 (10) ◽  
pp. 1934578X1400901
Author(s):  
Mónica Constanza Ávila Murillo ◽  
Luis Enrique Cuca Suarez ◽  
Jairo Alonso Cerón Salamanca
Keyword(s):  
Statistical Analysis ◽  
Essential Oils ◽  
Insecticidal Activity ◽  
Spodoptera Frugiperda ◽  
Insect Pests ◽  
Pearson Correlation ◽  
Oil Composition ◽  
Aerial Parts ◽  
Leaf Oil ◽  
Main Component

Essential oils of Piper subtomentosum (leaves and inflorescences) and Piper septuplinervium (aerial parts) were analyzed by GC-MS; sixty-three compounds were determined, representing 92.0%, 86.9 %, and 91.8 % of the total relative oil composition of the leaves, inflorescences, and aerial parts, respectively. The most abundant component in the aerial parts and inflorescence oils was α-pinene (27.3%, 21.0%, respectively), and δ-cadinene was the main component of the leaf oil. Insecticidal activity of the essential oils were determined on the Spodoptera frugiperda second instar larvae; the essential oil from the aerial parts of P. septuplinervium was the most active against insect pests (LC50= 9.4 μL/L of air). Statistical analysis by direct Pearson correlation showed that the insecticidal activity of the essential oils was primarily due to camphene and α- and β-pinene. The effect of the oils on the insect life cycle was also evaluated, and in some cases, a delay in growth and inhibition of the oviposition in the females were observed.

scholarly journals Essential oil Composition of Ficus Benjamina (Moraceae)and Irvingia Barteri (Irvingiaceae)

2012 ◽  
Vol 7 (12) ◽  
pp. 1934578X1200701 ◽  
Author(s):  
Isiaka A. Ogunwande ◽  
Razaq Jimoh ◽  
Adedoyin A. Ajetunmobi ◽  
Nudewhenu O. Avoseh ◽  
Guido Flamini
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Essential Oil ◽  
Essential Oils ◽  
Essential Oil Composition ◽  
Gas Chromatography Mass Spectrometry ◽  
Oil Composition ◽  
Ficus Benjamina ◽  
Germacrene D ◽  
Leaf Oil

Essential oils obtained by hydrodistillation of leaves of two Nigerian species were analyzed for their constituents by gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS). The leaf oil of Ficus benjamina L. (Moraceae), collected during the day, contained high contents of α-pinene (13.9%), abietadiene (9.7%), cis-α-bisabolene (8.2%) and germacrene-D-4-ol (8.4%), while the night sample was dominated by germacrene-D-4-ol (31.5%), 1,10-di- epi-cubenol (8.8%) and hexahydrofarnesylacetone (8.3%). This could be a possible indication of differences in emissions of volatiles by F. benjamina during the day and night. The main compounds of Irvingia barteri Hook. f. (Irvingiaceae) were β-caryophyllene (17.0%), (E)-α-ionone (10.0%), geranial (7.6%), (E)-β-ionone (6.6%) and β-gurjunene (5.1%).

scholarly journals Determination of Chemical Constituents of Leaf and Stem Essential Oils of Artemisia monosperma from Central Saudi Arabia

2012 ◽  
Vol 7 (8) ◽  
pp. 1934578X1200700 ◽  
Author(s):  
Merajuddin Khan ◽  
Ahmad A. Mousa ◽  
Kodakandla V. Syamasundar ◽  
Hamad Z. Alkhathlan
Keyword(s):  
Gas Chromatography ◽  
Saudi Arabia ◽  
Essential Oils ◽  
Literature Search ◽  
Chemical Constituents ◽  
Oil Composition ◽  
Desert Region ◽  
Leaf Oil ◽  
Qualitative Similarity

The leaf and stem essential oils of Artemisia monosperma from the desert region of central Saudi Arabia were analysed by gas chromatography-based techniques (GC–FID, GC–MS, Co-GC, LRI determination, database and literature search) using polar as well as non-polar columns, which resulted in the identification of 130 components, of which 81 were common to both oils. In the leaf oil 120 compounds were identified, while 91 were identified in the stem oil accounting for 98.4% and 99.7% of the oil composition, respectively. The major constituents of the leaf oil were β-pinene (50.3%), α-terpinolene (10.0%), limonene (5.4%) and α-pinene (4.6%), while the major constituents of the stem oil were β-pinene (36.7%), α-terpinolene (6.4%), limonene (4.8%), β-maaliene (3.7%), shyobunone (3.2%) and α-pinene (3.1%). The two oils showed an important qualitative similarity. However, some specific constituents (39 in the leaf oil and 10 in the stem oil) allow differentiation of the two essential oils.

Chemical Characterization of the Essential Oils of Eucalyptus.grandis×Eucalyptus.urophylla Hybrids and Six Pure Eucalyptus species Grown in Guangxi (China)

2014 ◽  
Vol 1033-1034 ◽  
pp. 200-208
Author(s):  
Feng Lai Lu ◽  
Yue Yuan Chen ◽  
Jiao Hong Wei ◽  
Yong Lin Huang ◽  
Dian Peng Li ◽  
...  
Keyword(s):  
Essential Oils ◽  
Chemical Characterization ◽  
Hierarchical Cluster ◽  
The Other ◽  
Eucalyptus Species ◽  
Oil Composition ◽  
Pure Species ◽  
Species Analysis ◽  
Total Oil

Hydrodistillation of the fresh leaves of E.grandis×E.urophylla hybrids and pure species E.grandis, E.urophylla, E.pellita, E.camaldulensis, E. dunni, and E.saligna collected from the trees grown in Guangxi Huangmian Forest (China), afforded essential oils in yields varying from 0.24±0.15% to 5.36±0.28%, according to the species. Analysis by GC (FID) and GC/MS allowed the identification of 67 compounds, representing 82.55% to 91.03% of the total oil composition. The dominant compounds were 1,8-cineole in E.saligna, E.urophylla, E.grandis×E.urophylla, E.grandis, E.pellita and E. dunni (67.48, 57.12, 48.21, 23.64, 20.34, 20.22%), p-Cymene in E.camaldulensis,E. dunni and E.grandis(21.32, 14.74, 13.38%), α-pinene in E.grandis and E.grandis×E.urophylla (21.77, 15.55%), α-terpinene in E. dunni and E.grandis (17.96, 9.35%), α-terpineol in E.pellita and E.saligna (19.24,11.54%), respectively. Hierarchical Cluster Analysis separated the characterized essential oils into two groups, each constituting a chemotype. E.grandis×E.urophylla and E.urophylla were classified in the same group, while E.grandis in the other.

scholarly journals Zingiber vuquangensis and Z. castaneum: Two Newly Discovered Species from Vietnam and Their Essential Oil Constituents

2018 ◽  
Vol 13 (6) ◽  
pp. 1934578X1801300 ◽  
Author(s):  
Le T. Huong ◽  
Trinh T. Huong ◽  
Nguyen T. T. Huong ◽  
Dao T. M. Chau ◽  
Ly N. Sam ◽  
...  
Keyword(s):  
Essential Oil ◽  
Essential Oils ◽  
National Park ◽  
Chemical Constituents ◽  
The Other ◽  
Bornyl Acetate ◽  
First Report ◽  
Antimicrobial Effects ◽  
Leaf Oil ◽  
Fruit Oil

The chemical constituents of essential oils obtained by hydrodistillation from Zingiber vuquangensis Lý N.S., Lê T.H., Trịnh T. H., Nguyễn V.H., Đỗ N.Đ. and Zingiber castaneum Škorničk. & Q.B. Nguyễn collected from Vu Quang National Park, Hà Tĩnh Province, Vietnam were analysed by GC and GC-MS. β-Pinene (24.7% and 26.1%) and β-caryophyllene (12.3% and 13.9%) were the main constituents in the leaf oil and stem oil of Zingiber vuquangensis. On the other hand the root oil contained bornyl acetate (20.9%), zerumbone (14.1%) and α-humulene (9.6%) while β-pinene (19.6%), 1,8-cineole (15.6%), α-pinene (10.3%) and β-caryophyllene (10.4%) were the significant compounds of the fruit oil. The leaf oil Zingiber castaneum was dominated by β-pinene (30.6%), α-pinene (9.5%), β-caryophyllene (9.4%) and bicycloelemene (9.1%). The compounds occurring in higher quantity in the stem oil were β-caryophyllene (14.7%), δ-cadinene (9.8%), bicycloelemene (8.4%) and α-cubebene (7.8%). However, camphene (15.1%), 1,8-cineole (13.6%), linalool (11.3%) and δ-3-carene (8.5%) were the main compounds of the root oil while ( E)-nerolidol (23.2%), ( Z)-9-octadecenamide (17.3%) and β-caryophyllene (10.8%) were the main constituents of the fruit oil. The essential oil did not exhibit noticeable antimicrobial effects. This is the first report on the volatile compositions of Z. vuquangensis and Z. castaneum.

scholarly journals Constituents of Essential Oils from the Leaf and Flower of Plumeria alba Grown in Nigeria

2014 ◽  
Vol 9 (11) ◽  
pp. 1934578X1400901 ◽  
Author(s):  
Oladipupo A. Lawal ◽  
Isiaka A. Ogunwande ◽  
Andy R. Opoku
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Chemical Analysis ◽  
Essential Oil ◽  
Essential Oils ◽  
The Other ◽  
Caryophyllene Oxide ◽  
First Report ◽  
Leaf Oil ◽  
Phenyl Acetaldehyde

This paper reports on the compounds identified in the leaf and flower essential oils obtained by hydrodistillation of Plumeria alba L. (Apocynaceae) grown in Nigeria. The chemical analysis of the essential oils was achieved by means of gas chromatography (GC) and gas chromatography coupled with mass spectrometry (GC-MS). Linalool (13.2%), n-nonanal (9.6%), phenyl acetaldehyde (8.5%), neryl acetone (5.3%) and n-decanal (5.1%) were the main constituents of the leaf oil. On the other hand, the flower oil comprised mainly of limonene (9.1%), linalool (7.9%), α-cedrene (8.0%), caryophyllene oxide (7.9%) and ( E, E)-α-farnesene (6.6%). This is the first report on the essential oil constituents of P. alba.

scholarly journals Constituents of Cajanus Cajan (L.) Millsp., Moringa Oleifera Lam., Heliotropium Indicum L. and Bidens Pilosa L. from Nigeria

2009 ◽  
Vol 4 (4) ◽  
pp. 1934578X0900400 ◽  
Author(s):  
Akinola O. Ogunbinu ◽  
Guido Flamini ◽  
Pier L. Cioni ◽  
Muritala A. Adebayo ◽  
Isiaka A. Ogunwande
Keyword(s):  
Essential Oils ◽  
Cajanus Cajan ◽  
Moringa Oleifera ◽  
The Other ◽  
Caryophyllene Oxide ◽  
Bidens Pilosa ◽  
Hexahydrofarnesyl Acetone ◽  
Leaf Oil ◽  
Heliotropium Indicum ◽  
Moringa Oleifera Lam

The essential oils of four plant species from Nigeria have been extracted by hydrodistillation and analyzed by GC and GC-MS. The oils of Cajanus cajan were comprised of sesquiterpenes (92.5%, 81.2% and 94.3% respectively in the leaves, stem and seeds). The major compounds identified were α-himachalene (9.0-11.5%), β-himachalene (8.0-11.0%), γ-himachalene (6.9-8.1%), α-humulene (7.1-8.7%) and α-copaene (4.5-5.6%). However, monoterpenoid compounds (81.8%) dominated the oil of Moringa oleifera with an abundance of α-phellandrene (25.2%) and p-cymene (24.9%). On the other hand, aldehydes (52.8%) occurred in the highest amount in Heliotropium indicum, represented by phenylacetaldehyde (22.2%), ( E)-2-nonenal (8.3%) and (E, Z)-2-nonadienal (6.1%), with a significant quantity of hexahydrofarnesylacetone (8.4%). The leaf and stem oils of Bidens pilosa were dominated by sesquiterpenes (82.3% and 59.3%, respectively). The main compounds in the leaf oil were caryophyllene oxide (37.0%), β-caryophyllene (10.5%) and humulene oxide (6.0%), while the stem oils had an abundance of hexahydrofarnesyl acetone (13.4%), δ-cadinene (12.0%) and caryophyllene oxide (11.0%). The observed chemical patterns differ considerably from previous investigations.

scholarly journals Essential oil composition of Ocimum basilicum L. and Ocimum minimum L. in Turkey

2011 ◽  
Vol 20 (No. 6) ◽  
pp. 223-228 ◽  
Author(s):  
M. Özcan ◽  
J.-C. Chalchat
Keyword(s):  
Essential Oil ◽  
Essential Oils ◽  
Volatile Oil ◽  
Essential Oil Composition ◽  
Ocimum Basilicum ◽  
Methyl Eugenol ◽  
Geranyl Acetate ◽  
Oil Composition ◽  
Main Components

The constituents of essential oils isolated by hydrodistillation of the overground parts of Ocimum basilicum L. and Ocimum minimum L. from Turkey were examined by GC-MS. A total of 49 and 41 components, respectively, were identified accounting for 88.1% and 74.4% of the oils of O. basilicum and O. minimum, respectively. The oil of O. basilicum contained, as main components, methyl eugenol (78.02%), α-cubebene (6.17%), nerol (0.83%) and ε-muurolene (0.74%). Major compounds in the volatile oil of O. minimum were geranyl acetate (69.48%), terpinen-4-ol (2.35%) and octan-3-yl-acetate (0.72%). The essential oil of O. basilicum was characterised by its high content of methyl eugenol (78.02%), whereas the most important essential oil constituent of O. minimum was geranyl acetate (69.48%).    

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