Sulfur forms in bulk soils and alkaline soil extracts of tropical mountain ecosystems in northern Thailand

Soil Research ◽  
2002 ◽  
Vol 40 (1) ◽  
pp. 161 ◽  
Author(s):  
A. Möller ◽  
K. Kaiser ◽  
N. Kanchanakool ◽  
C. Anecksamphant ◽  
W. Jirasuktaveekul ◽  
...  

Sulfur, besides phosphorus, is crucial for the nutrition of plants on tropical soils. Its availability is closely related to the turnover of soil organic matter. To get a better insight into transformation of soil S forms during the decomposition of organic matter, we studied inorganic and organic S pools in bulk samples and alkaline extracts of soils under different land uses representative of the tropical highlands of northern Thailand. Samples were taken from a cabbage cultivation, a Pinus reforestation, a secondary forest, and a primary forest. Total S ranged from 483 549 mg/kg in the subsoil to 1909 376 mg/kg in the organic layers, which is relatively high for tropical soils. The major S component in soil was organic S, comprising 75–99% of total S. Organic S was significantly correlated with total S, organic C, and total N, indicating that there is a close relationship between C, N, and S cycling in soil. C-bonded S was the predominant form in the topsoils (35–99% of total S) but its presence decreased with soil depth. The maximum concentrations of ester SO4-S were found in the A horizons (128 49 mg/kg), whereas the concentrations of inorganic SO4-S were small in all horizons. Compared with the forest site, the cabbage cultivation site was strongly depleted in S. C-bonded S was more depleted than ester SO4-S. A comparison of the S forms in NaOH extracts with S forms in bulk soil and C forms as indicated by 13C-NMR spectroscopy showed (i) that the extracts were very representative of soil organic S fractions and (ii) that ester SO4-S was mainly associated with O-substituted aliphatic C. In contrast, C-bonded S seemed to be connected to more-or-less all C binding types. transformation of soil organic matter, sulfate.

Soil Research ◽  
2018 ◽  
Vol 56 (8) ◽  
pp. 820 ◽  
Author(s):  
K. A. Conrad ◽  
R. C. Dalal ◽  
D. E. Allen ◽  
R. Fujinuma ◽  
Neal W. Menzies

Quantifying the size and turnover of physically uncomplexed soil organic matter (SOM) is crucial for the understanding of nutrient cycling and storage of soil organic carbon (SOC). However, the C and nitrogen (N) dynamics of SOM fractions in leucaena (Leucaena leucocephala)–grass pastures remains unclear. We assessed the potential of leucaena to sequester labile, free light fraction (fLF) C and N in soil by estimating the origin, quantity and vertical distribution of physically unprotected SOM. The soil from a chronosequence of seasonally grazed leucaena stands (0–40 years) was sampled to a depth of 0.2m and soil and fLF were analysed for organic C, N and δ13C and δ15N. On average, the fLF formed 20% of SOC and 14% of total N stocks in the upper 0.1m of soil from leucaena rows and showed a peak of fLF-C and fLF-N stocks in the 22-year-stand. The fLF δ13C and fLF δ15N values indicated that leucaena produced 37% of fLF-C and 28% of fLF-N in the upper 0.1m of soil from leucaena rows. Irrespective of pasture type or soil depth, the majority of fLF-C originated from the accompanying C4 pasture-grass species. This study suggests that fLF-C and fLF-N, the labile SOM, can form a significant portion of total SOM, especially in leucaena–grass pastures.


2010 ◽  
Vol 34 (3) ◽  
pp. 907-916 ◽  
Author(s):  
Cícero Célio de Figueiredo ◽  
Dimas Vital Siqueira Resck ◽  
Marco Aurélio Carbone Carneiro

Soil organic matter can be analyzed on the basis of the different fractions. Changes in the levels of organic matter, caused by land use, can be better understood by alterations in the different compartments. The aim of this study was to evaluate the effect of different management systems on the labile and stable organic matter of a dystrophic Red Latosol (Oxisol). The following properties were determined: total organic C and total N (TOC and TN), particulate organic C and particulate N (POC and PN), organic C and N mineral-associated (MOC and NM) and particulate organic C associated with aggregate classes (POCA). Eight treatments were used: seven with soil management systems and one with native Cerrado as a reference. The experiment was designed to study the dynamics of systems of tillage and crop rotation, alternating in time and space. The experimental design was a randomized block design with three replications. The soil samples were collected from five depths: 0-5, 5-10, 10-20, 20-30 and 30-40 cm. Changes in organic C by land use occurred mainly in the fraction of particulate organic matter (> 53 mm). Proper management of grazing promoted increased levels of particulate organic matter by association with larger aggregates (2-8 mm), demonstrating the importance of the formation of this aggregate class for C protection in pasture.


Soil Research ◽  
1993 ◽  
Vol 31 (4) ◽  
pp. 481 ◽  
Author(s):  
MR Carter ◽  
WJ Parton ◽  
IC Rowland ◽  
JE Schultz ◽  
GR Steed

Maintenance and improvement of soil organic matter levels is an important concern in dryland farming systems of temperate regions. The Century soil organic matter model was used to simulate changes in soil organic C and total N under long-term wheat (Triticum aestivum L.) and pasture rotations at five sites in southern Australia. Average declines in soil organic C and total N of 14 and 10%, respectively, in continuous and wheat-fallow systems over a 10 to 20 year period were closely simulated by the model at each site. Additions of N fertilizer (80 kg N ha-1), which prevented soil organic matter decline in continuous wheat systems, was also well represented by the model. Trends in soil organic matter under long-term legume pasture were not adequately simulated by the model, probably due to the 'annual' nature of subterranean clover (Trifolium subterranean L.) in dry seasons and subsequent changes in the ratio of live to dead plant biomass and shoot to root ratios. Overall, the study emphasizes the importance of adequate total plant C production to prevent a decline in soil organic C.


1981 ◽  
Vol 61 (3) ◽  
pp. 517-519 ◽  
Author(s):  
M. SCHNITZER ◽  
L. E. LOWE ◽  
J. F. DORMAAR ◽  
Y. MARTEL

In a recent cooperative study, in which four laboratories participated, organic matter in a large number of Canadian soil samples was characterized by relatively simple methods. As result of this work we are proposing a procedure for the extraction, separation and characterization of soil organic matter. The procedure includes determinations of organic C and total N in initial soils, followed by the isolation from the soils of humic and fulvic acids. Total C and N and E4/E6 ratios are then determined in the latter fractions. From these data, proportions of extractable soil-C and soil-N and HA/FA ratios are computed.


Agronomy ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 1054 ◽  
Author(s):  
Yining Niu ◽  
Zhuzhu Luo ◽  
Liqun Cai ◽  
Jeffrey A. Coulter ◽  
Yaoquan Zhang ◽  
...  

Cropping systems are structured to maximize crop yields and increase sustainability in agricultural production. A field study was conducted to investigate different long-term cropping systems on soil organic matter and microbial communities. The cropping systems studied were: (i) a 14-year continuous alfalfa (Medicago sativa L.) (CA), (ii) a 9-year alfalfa removed and rotated with 4–5 years continuous annual crops (spring wheat (Triticum aestivum L.), maize (Zea mays L.), potato (Solanum tuberosum L.), and millet (Panicum miliaceum L.)), and (iii) a 5-year field fallow after alfalfa. Results showed that continued annual crops decreased total organic C and labile organic C by 10 to 20% and 17 to 34% in the topsoil (0–30 cm), and by 15 to 35% and 20 to 46% in the subsoil (30–60 cm), respectively, compared with CA. Similar trends were found in soil total N concentration, which decreased by 7 to 20% in the topsoil. Highest microbial biomass C was found in CA. Shannon-Wiener diversity and substrate richness of soil microbes measured by Biolog EcoPlates was significantly affected by cropping system with CA exhibiting a higher degree of soil microbial functional diversity in the topsoil, while the lowest values were found in the alfalfa-potato system. The higher soil organic matter content and functional diversity of soil microbe in CA indicates that soil nutrition and microbial activity did not limit alfalfa development and growth in the dryland area. The lower microbial activity and functional diversity observed in the potato field indicates the importance of crop selection in cropping systems.


1995 ◽  
Vol 35 (7) ◽  
pp. 903 ◽  
Author(s):  
RC Dalal ◽  
WM Strong ◽  
EJ Weston ◽  
JE Cooper ◽  
KJ Lehane ◽  
...  

Management practices involving legume leys, grain legumes, and no-tillage and stubble retention, along with nitrogen (N) fertiliser application for wheat cropping, were examined for their effectiveness in increasing soil organic matter (0-10 cm depth) from 1986 to 1993 in a field experiment on a Vertisol at Warra, Queensland. The treatments were (i) grass + legume leys (purple pigeon grass, Setaria incrassata; Rhodes grass, Chloris gayana; lucerne, Medicago sativa; annual medics, M. scutellata and M. truncatula) of 4 years duration followed by continuous wheat; (ii) 2-year rotation of annual medics and wheat (Triticum aestivum cv. Hartog); (iii) 2-year rotation of lucerne and wheat; (iv) 2-year rotation of chickpea (Cicer arietinum cv. Barwon) and wheat; (v) no-tillage (NT) wheat; and (vi) conventional tillage (CT) wheat. Fertiliser N as urea was applied to both NT wheat and CT wheat at 0,25, and 75 kg N/ha. year. The CT wheat also received N at 12.5 and 25kg N/ha. year. After 4 years, soil organic carbon (C) concentration under grass + legume leys increased by 20% (650 kg C/ha. year) relative to that under continuous CT wheat. Soil total N increased by 11, 18, and 22% after 2, 3, and 4 years, respectively, under grass + legume leys relative to continuous CT wheat. These increases in soil organic matter were mostly confined to the 0-2.5 cm layer. After the start of wheat cropping, organic C and total N levels declined steadily but were still higher than under CT wheat and higher than initial values in December 1985. Although 2-year rotations of lucerne-wheat and medic-wheat had a small effect on soil organic C, soil total N concentrations were higher than in the chickpea-wheat rotation and continuous CT wheat from November 1990 to November 1992. Soil under chickpea-wheat rotation had organic C and total N concentrations similar to continuous CT wheat, although from the former, about 70 kg/ha. year of extra N was removed in the grain from 1989 to 1993. No-tillage practice had a small effect on soil organic C, although total N concentration was higher than under CT wheat in November 1993. These effects were mainly confined to the surface 0-2.5 cm depth. The C to N ratio was only affected in soil under grass + legume leys, and no-tillage treatments. These data show that restoration of soil organic matter in Vertisol requires grass + legume leys, primarily due to increased root biomass, although soil total N can be enhanced by including legume leys for longer duration in cropping systems in the semi-arid and subtropical environment.


1974 ◽  
Vol 54 (3) ◽  
pp. 309-315 ◽  
Author(s):  
J. R. BETTANY ◽  
J. W. B. STEWART ◽  
E. H. HALSTEAD

Growth chamber and laboratory studies of four selected soils differing in C:N:S ratios and the percentage of total S present as HI-reducible S in the soil organic matter showed that: (1) the yield response of alfalfa to applied S occurred when the 0.01 M CaCl2-extractable soil SO4—S was less than 3.3 μg/g, (2) mineralization of soil organic S was unaffected by the addition of 25 μg S/g to the soils, and (3) the amount of S mineralized was not directly related to the quantity of total S, HI-S or the percentage of total S present as Hi-reducible S. It was noted that the largest amount of S mineralized occurred from the soil with the lowest C:N:S ratios.


Soil Research ◽  
2000 ◽  
Vol 38 (2) ◽  
pp. 345 ◽  
Author(s):  
G. D. Schwenke ◽  
D. R. Mulligan ◽  
L. C. Bell

At Weipa, in Queensland, Australia, sown tree and shrub species sometimes fail to establish on bauxite-mined land, possibly because surface-soil organic matter declines during soil stripping and replacement. We devised 2 field experiments to investigate the links between soil rehabilitation operations, organic matter decline, and revegetation failure. Experiment 1 compared two routinely practiced operations, dual-strip (DS) and stockpile soil, with double-pass (DP), an alternative method, and subsoil only, an occasional result of the DS operation. Other treatments included variations in stripping-time, ripping-time, fertiliser rate, and cultivation. Dilution of topsoil with subsoil, low-grade bauxite, and ironstone accounted for the 46% decline of surface-soil (0–10 cm) organic C in DS compared with pre-strip soil. In contrast, organic C in the surface-soil (0–10 cm) of DP plots (25.0 t/ha) closely resembled the pre-strip area (28.6 t/ha). However, profile (0–60 cm) organic C did not differ between DS (91.5 t/ha), DP (107 t/ha), and pre-strip soil (89.9 t/ha). Eighteen months after plots were sown with native vegetation, surface-soil (0–10 cm) organic C had declined by an average of 9% across all plots. In Experiment 2, we measured the potential for post-rehabilitation decline of organic matter in hand-stripped and replaced soil columns that simulated the DS operation. Soils were incubated in situ without organic inputs. After 1 year’s incubation, organic C had declined by up to 26% and microbial biomass C by up to 61%. The difference in organic C decline between vegetated replaced soils (Expt 1) and bare replaced soils (Expt 2) showed that organic inputs affect levels of organic matter more than soil disturbance. Where topsoil was replaced at the top of the profile (DP) and not ploughed, inputs from volunteer native grasses balanced oxidation losses and organic C levels did not decline.


1999 ◽  
Vol 79 (1) ◽  
pp. 103-109 ◽  
Author(s):  
F. Courchesne ◽  
J.-F. Laberge ◽  
A. Dufresne

The role of soil organic matter (OM) on SO4 retention was investigated by comparing OM content, SO4 retention, and the distribution of Fe, Al and Si compounds in OM-poor (Grands-Jardins, PGJ) and OM-rich (Hermine, HER) Podzols from Québec, Canada. At both sites, four pedons were sampled by horizon; soil pH in H2O, organic C, phosphate-extractable SO4 and, sodium pyrophosphate, acid ammonium oxalate and dithionite-citrate-bicarbonate (DCB) extractable Fe, Al and Si were measured for each mineral horizon. The mineralogy of the clay (<2 µm) and fine silt (2–20 µm) fractions of selected horizons was determined by X-ray diffraction (XRD) and infrared spectroscopy (IR). Weighted mean organic C and pyrophosphate extractable Fe and Al contents were significantly higher in the HER than in the PGJ sola, while the PGJ soils were richer in amorphous inorganic Al. No trends were observed for inorganic Fe compounds. Chemical dissolution and IR allowed the identification of short-range ordered aluminosilicates, probably allophane, in the OM-poor and slightly acidic to neutral PGJ soils. These materials were absent from the OM-rich and acidic HER soils. Phosphate extractions showed that the weighted mean native SO4 content was five times higher in the PGJ than in the HER soil. Finally, native SO4 was strongly related to inorganic Fe, Al and Si (associated with allophane) at PGJ but only to inorganic Fe at HER. These results indicate that OM indirectly affects SO4 sorption through the influence organic substances exerts on the nature and distribution of pedogenic Fe, Al and Si compounds, such as allophane, in Podzolic profiles. Key words: Organic matter, sulfate, imogolite, allophane, silica, Podzol


HortScience ◽  
2017 ◽  
Vol 52 (6) ◽  
pp. 896-904 ◽  
Author(s):  
Rebecca J. Long ◽  
Rebecca N. Brown ◽  
José A. Amador

Using organic wastes as agricultural amendments is a productive alternative to disposal in landfills, providing nutrients for plant growth and carbon to build soil organic matter. Despite these benefits, a large fraction of organic waste is sent to landfills. Obstacles to the adoption of wastes as sources of plant nutrients include questions about harmful effects to crops or soils and the wastes’ ability to produce satisfactory yields. We compared six organic waste amendments with a mineral fertilizer control (CN) to determine effects on soil quality, soil fertility, crop quality, and crop yield in 2013 and 2014. Waste amendments were applied at a rate sufficient to supply 10,000 kg organic C/ha over two seasons, and mineral fertilizer was applied to control plots to provide 112 kg-N/ha/yr. The experiment was laid out in a randomized block design with four replicates and three crops: sweet corn (Zea mays L. cv. Applause, Brocade, and Montauk), butternut squash (Cucurbita moschata Duchesne cv. JWS 6823), and potatoes (Solanum tuberosum L. cv. Eva). Amendment with biosolids/yard waste cocompost (BS), dehydrated restaurant food waste (FW), gelatin manufacturing waste (GW), multisource compost (MS), paper fiber/chicken manure blend (PF), and yard waste compost (YW) did not have a negative impact on soil moisture, bulk density, electrical conductivity (EC), or the concentration of heavy metals in soil or plant tissue. Our results indicate potential uses for waste amendments including significantly raising soil pH (MS) and increasing soil organic matter [OM (YW and BS)]. The carbon-to-nitrogen ratio (C:N) of waste amendments was not a reliable predictor of soil inorganic N levels, and only some wastes increased potentially mineralizable nitrogen (PMN) levels relative to the control. Plots amended with BS, FW, and GW produced yields of sweet corn, butternut squash, and potatoes comparable with the control, whereas plots amended with YW, PF, and MS produced lower yields of sweet corn, squash, or both, although yields for potatoes were comparable with the control. In addition, the marketability of potatoes from PF plots was significantly better than that of the control in 2014. None of the wastes evaluated in this study had negative impacts on soil properties, some provided benefits to soil quality, and all produced comparable yields for at least one crop. Our results suggest that all six wastes have potential to be used as sources of plant nutrients.


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