Effects of modified clinoptilolite on phosphorus mobilisation and potassium or ammonium release in Ferrosols
An investigation was conducted to study effects of the potassium and ammonium saturated clinoptilolite on P availability in Ferrosols. The adsorption and desorption of phosphorus were determined by shaking 2.5 g soil with 0, 0.5, and 2.5 g clinoptilolite at 0.31 or 1.25 mg P/g soil in 50 mL solution for a total of 72 h (24 h for clinoptilolite and 48 h for phosphate). The nutrient concentrations in supernatants were measured by spectrophotometry. Results showed phosphorus solubility was significantly increased with clinoptilolite addition. Increasing the amount of clinoptilolite enhanced the concentration of P up to 6.85 and 41.29 mg/L at 0.31 and 1.25 mg P/g soil, respectively. Correspondingly, the amount of potassium and ammonium released from the clinoptilolite were up to 63.69 and 12.20 mg/L at 0.31 mg P/g soil, and 107.42 and 29.94 mg/L at 1.25 mg P/g soil. Nutrient concentrations in the treatments in which clinoptilolite was added before P were greater than that in the treatments in which P was added prior to clinoptilolite. The results also suggest that potassium and ammonium saturated clinoptilolite can increase P solubility while providing K and NH4 to the soil, a concurrent positive effect for plant growth.