Comparison of oxidoreductive enzyme activities in three coal tar creosote-contaminated soils

Soil Research ◽  
2019 ◽  
Vol 57 (8) ◽  
pp. 814 ◽  
Author(s):  
Arkadiusz Telesiński ◽  
Teresa Krzyśko-Łupicka ◽  
Krystyna Cybulska ◽  
Barbara Pawłowska ◽  
Robert Biczak ◽  
...  
Keyword(s):  
Contaminated Soils ◽  
Sandy Loam ◽  
Coal Tar ◽  
Loamy Sand ◽  
Clay Loam ◽  
Oxidoreductase Activity ◽  
Sandy Clay Loam ◽  
Sandy Clay ◽  
Polycyclic Aromatic ◽  
Negative Effect

This study used laboratory experiments to compare the effects of coal tar creosote on the activity of oxidoreductive enzymes in sandy loam, loamy sand and sandy clay loam soils. Different amounts of coal tar creosote were added to soil samples as follows: 0 (control), 2, 10 or 50 g kg–1 dry matter. The activity of soil dehydrogenases (DHAs), o-diphenol oxidase (o-DPO), catalase (CAT), nitrate reductase (NR) and peroxidases (POX) was determined. Contamination of soil with coal tar creosote affected oxidoreductase activity. Oxidoreductive enzyme activity following soil contamination with coal tar creosote was in the following order: DHAs > CAT > NR > POX > o-DPO in loamy sand and in sandy loam; and DHAs > POX > CAT > NR > o-DPO in sandy clay loam. The index of soil oxidoreductive activity (IOx) introduced in this study confirms the negative effect of coal tar creosote on oxidoreductase activity in soil. DHAs were the most sensitive to the contamination of soil with coal tar creosote. Moreover, the greatest changes in oxidoreductase activities were observed in loamy sand. Knowledge of the mechanism underlying the effects of coal tar creosote on oxidoreductive processes may enable development of a method for the bioremediation of polycyclic aromatic hydrocarbon-contaminated soils.

Leaching and mobility of carbofuran from granular and alginate controlled release formulations

2000 ◽  
Vol 134 (4) ◽  
pp. 405-412 ◽  
Author(s):  
A. S. MAREI ◽  
H. R. SOLTAN ◽  
A. MOUSA ◽  
A. KHAMIS
Keyword(s):  
Controlled Release ◽  
Sandy Loam ◽  
Soil Column ◽  
Sandy Loam Soil ◽  
Flooded Soil ◽  
Clay Loam ◽  
Sandy Clay Loam ◽  
Sandy Clay ◽  
Controlled Release Formulations ◽  
Loam Soil

Controlled release (CR) formulations can significantly influence the fate of carbofuran in the environment. The influence of three alginate-encapsulated CR formulations compared with the granular formulation (G10%) on the mobility of carbofuran in sandy clay loam soil and sandy loam soil was investigated. In flooded soil the leaching potential of the three alginate controlled release formulations tested was decreased more than nine times (not more than 3%) compared with the G10% (28%). Most of the released carbofuran was confined to the top 0–5 cm of the soil column followed by the second 5–10 cm layer and the least was found in the fourth section (15–20 cm). The data obtained for a sandy loam soil irrigated by drip irrigation showed that the greatest proportion of carbofuran leached through the columns was from the G10% (52%) compared with 3–4% from CR formulations over a 30-day period. The carbofuran concentrations found in different soil depths showed similar trends to those for the flooded soil. Based on the residue levels recorded within the 20 cm depth, the relative retention ratio of carbofuran in sandy clay loam versus sandy loam soil was 1·2[ratio ]1 for the controlled release formulations and 1·9[ratio ]1 for the G10%.

Acetylene reduction by non-symbiotic bacteria in artificial soil aggregates amended with glucose

1974 ◽  
Vol 20 (6) ◽  
pp. 877-881 ◽  
Author(s):  
C. I. Mayfield ◽  
R. L. Aldworth
Keyword(s):  
Sandy Loam ◽  
Soil Aggregates ◽  
Peripheral Zone ◽  
Sandy Loam Soil ◽  
Artificial Soil ◽  
Clay Loam ◽  
Sandy Clay Loam ◽  
Sandy Clay ◽  
Loam Soil ◽  
Soil Activity

The C2H2-reduction assay was used to study the activity of non-symbiotic N2-fixing bacteria in glucose-amended artificial soil aggregates prepared from a sandy clay loam and a sandy loam soil. Anaerobic incubation under nitrogen resulted in significantly higher rates and greater total quantities of C2H2 reduction than did incubation in air. In the sandy clay loam soil activity under both incubation conditions was due to anaerobic N2-fixing bacteria, whereas in the sandy loam soil aerobic N2-fixing bacteria also proliferated in the aggregates. Direct observation of sectioned aggregates by fluorescence microscopy showed that peripheral zone 1 mm thick sup ported the growth of aerobic microorganisms. The anaerobic microsites in the interior of the aggregates were well protected since disruption procedures involving vigorous shaking with aerated water were required to allow O2 to penetrate and inhibit the anaerobic activity.

Effect of Commonly used Turfgrass Herbicides on Bermudagrass (Cynodon dactylon) Root Growth

Weed Science ◽  
1993 ◽  
Vol 41 (4) ◽  
pp. 641-647 ◽  
Author(s):  
Frederick M. Fishel ◽  
G. Euel Coats
Keyword(s):  
Root Growth ◽  
Sandy Loam ◽  
Sandy Loam Soil ◽  
Root Weight ◽  
Clay Loam ◽  
Soil Layers ◽  
Sandy Clay Loam ◽  
Fine Sandy Loam ◽  
Sandy Clay ◽  
Loam Soil

Experiments were conducted in 1990 and 1991 to determine bioavailability of PRE herbicides at three soil profile depths and two soil types in established common bermudagrass sods. Prodiamine and oryzalin reduced ‘Tifgreen’ bermudagrass root growth in the 5- to 7.5-cm layer of a Bosket very fine sandy loam soil at 2 and 4 wk after treatment in 1991. These herbicides decreased bermudagrass root weight in both the Bosket and Marietta sandy clay loam both years in samples taken from the 2.5- to 5-cm depth layer. In the 0- to 2.5-cm soil layer, all herbicides reduced root weight in 1990. In a bioassay, prodiamine caused decreased Tifgreen bermudagrass root growth at concentrations as low as 4 ppb by wt in the very fine sandy loam soil, while 8 ppb was necessary in the sandy clay loam soil. Prodiamine was detected in the very fine sandy loam at 4 wk after treatment at all depths in 1991 (65, 45, and 39 ppb in the 0- to 2.5-, 2.5- to 5-, and 5- to 7.5-cm soil layers, respectively). Oryzalin was also detected at all depths in 1991 when sampled at 2 and 4 wk after treatment in the very fine sandy loam. Pendimethalin was present in concentrations of 38, 39, and 37 ppb in the sandy clay loam at 2 wk after treatment in the 0- to 2.5-, 2.5- to 5-, and the 5- to 7.5-cm soil layers, respectively. Pendimethalin was also detected in the very fine sandy loam at 2 wk after treatment at concentrations of 55, 69, and 36 ppb in the 0- to 2.5-, 2.5- to 5-, and 5- to 7.5-cm soil layers, respectively.

scholarly journals Experiments on the Heaving Force of Freezing Soil

1977 ◽  
Vol 19 (81) ◽  
pp. 674-675
Author(s):  
Seiiti Kinosita
Keyword(s):  
Water Supply ◽  
Soil Type ◽  
Sandy Loam ◽  
List Type ◽  
Clay Loam ◽  
Sandy Clay Loam ◽  
Soil Particles ◽  
Freezing Soil ◽  
Sandy Clay ◽  
Soil Block

Abstract Frost heaving of soil is accompanied by a force which often causes severe damage to structures. It was suggested by Everett that this so-called “heaving force" can be attributed to the coexistence of ice and water in micropores among soil particles which characterize the soil type and can be computed thermodynamically. However, the actual heaving force changes in a complicated manner depending on various factors including freezing speed, constraining condition for a soil block, and, of course, soil type. Measurements of heaving force were carried out on various soil samples (sand, sandy loam, sandy clay loam, and two kinds of clays) under various freezing conditions: freezing speed in a range from 0.10 cm/h to 0.35 cm/h, presence or absence of water supply, complete or loose axial constraint applied to a soil block. In each experiment, soil was packed in a cylindrical container with a diameter of 11 cm and a height of 10 cm. A disk was placed on top of the soil contained in the container to constrain the sample either rigidly (a complete axial constraint) or less rigidly through a spring (a loose axial constraint). Main results of the measurements were as follows: (1) Under complete axial constraint, the heaving force decreased with decrease in the freezing speed and with the increase in the size of soil particles (from 6 bars to 1 bar for clay; from 4 bars to 1 bar for sandy clay loam; from 4 bars to 0.8 bar for sandy loam; from 1.5 bars to 0.6 bar for sand). (2) Without the constraint, the heave amount was almost independent of the freezing speed when there was no water supply (8 mm for clay; 6.5 mm for sandy clay loam; 3.5 mm for sandy loam; 1 mm for sand). (3) The heaving force decreased very rapidly with the loosening of the axial constraint by weakening the spring. The results indicate that it is practical to treat the heaving force phenomenologically as a kind of resistive force exerted by freezing soil on a container holding the soil. Because of a volumetric increase due to the transformation of water into ice at the freezing front, both unfrozen and frozen parts of the soil suffer some strain if the soil is somehow constrained by the container. The strains cause stresses which appear as the heaving force. A formula for the heaving force is given in which both the frozen and the unfrozen soil are treated as viscoelastic bodies.

scholarly journals Interactions Among Peanut Cultivars, Herbicide Sequences, and A Systemic Insecticide1

1976 ◽  
Vol 3 (2) ◽  
pp. 56-62 ◽  
Author(s):  
E. W. Hauser ◽  
G. A. Buchanan ◽  
W. J. Ethredge ◽  
M. D. Jellum ◽  
S. R. Cecil
Keyword(s):  
Sandy Loam ◽  
Weather Conditions ◽  
Soil Types ◽  
Clay Loam ◽  
Systemic Insecticide ◽  
Soil Series ◽  
Sandy Clay Loam ◽  
Sandy Clay ◽  
Peanut Cultivars ◽  
Genetic And Environmental Factors

Abstract Soil type and weather conditions influenced interactions among peanut cultivars (Florunner, GK 3, and Tifspan), herbicide sequences, and a systemic insecticide (disulfoton). Disulfoton interacted more frequently with cultivars than did herbicides. More interactions occurred in 1974 than in 1973. When peanut yields from the eight studies (on four soil series) were averaged, disulfoton significantly increased peanut yields, especially on Greenville sandy clay loam. On all soil types, except Dothan sandy loam, an insecticide x cultivar interaction occurred at least once accompanied by consistent and significant increases in the yield of Florunner treated with disulfoton. Disulfoton increased yields of Tifspan twice but did not change significantly the yields of GK 3. When compared to a hand-weeded check, herbicides did not decrease average yields significantly unless the sequence terminated with multiple postemergence treatments. Herbicides interacted with cultivars in two of eight experiments, once on Greenville sandy clay loam and once on Tifton sandy loam. In general, GK 3 reacted more to herbicide sequences than did Florunner. Least affected by herbicides was the cultivar Tifspan. An herbicide x insecticide interaction occurred only once (on Dothan sandy loam) when disulfoton increased yields with either the no herbicide treatment or when benefin-vernolate was applied. In general, genetic and environmental factors influenced organoleptic quality and the fatty acid composition of peanut oil much more than did the herbicide or insecticide treatments.

scholarly journals S-index and soybean root growth in different soil textural classes

2016 ◽  
Vol 20 (4) ◽  
pp. 329-336
Author(s):  
Pedro D. de Oliveira ◽  
Michel K. Sato ◽  
Sueli Rodrigues ◽  
Herdjania V. de Lima
Keyword(s):  
Root Growth ◽  
Bulk Density ◽  
Sandy Loam ◽  
Soil Bulk Density ◽  
Physical Parameters ◽  
Clay Loam ◽  
Sandy Clay Loam ◽  
Soybean Root ◽  
Sandy Clay ◽  
Limiting Values

ABSTRACT This study tested the hypothesis that the limiting values of S-index, proposed in the literature can not be used to determine the degradation condition of soils under soybean cultivation in the state of Pará, Brazil. The objective was to determine limiting values of S-index using soil physical attributes and validate it with soybean root growth, in soils with different textural classes. For the experimental design, the following treatments were established: five compaction levels for sandy loam and sandy clay loam soils and three levels for clayey and very clayey soils. The following physical parameters were analysed: particle-size distribution, soil bulk density, critical soil bulk density, degree of compaction, soil-water retention curve, S-index and relative root length of soybean. The limiting values of S-index varied according to soil textural class and were equal to 0.037, 0.020 and 0.056 for sandy loam, sandy clay loam and clay, respectively. The S-index does not apply to soils with clay content > 71%, because it does not vary with the degree of compaction of the soil or the root growth of the evaluated crop.

scholarly journals Experiments on the Heaving Force of Freezing Soil

1977 ◽  
Vol 19 (81) ◽  
pp. 674-675
Author(s):  
Seiiti Kinosita
Keyword(s):  
Water Supply ◽  
Soil Type ◽  
Sandy Loam ◽  
List Type ◽  
Clay Loam ◽  
Sandy Clay Loam ◽  
Soil Particles ◽  
Freezing Soil ◽  
Sandy Clay ◽  
Soil Block

AbstractFrost heaving of soil is accompanied by a force which often causes severe damage to structures. It was suggested by Everett that this so-called “heaving force" can be attributed to the coexistence of ice and water in micropores among soil particles which characterize the soil type and can be computed thermodynamically. However, the actual heaving force changes in a complicated manner depending on various factors including freezing speed, constraining condition for a soil block, and, of course, soil type.Measurements of heaving force were carried out on various soil samples (sand, sandy loam, sandy clay loam, and two kinds of clays) under various freezing conditions: freezing speed in a range from 0.10 cm/h to 0.35 cm/h, presence or absence of water supply, complete or loose axial constraint applied to a soil block. In each experiment, soil was packed in a cylindrical container with a diameter of 11 cm and a height of 10 cm. A disk was placed on top of the soil contained in the container to constrain the sample either rigidly (a complete axial constraint) or less rigidly through a spring (a loose axial constraint). Main results of the measurements were as follows: (1)Under complete axial constraint, the heaving force decreased with decrease in the freezing speed and with the increase in the size of soil particles (from 6 bars to 1 bar for clay; from 4 bars to 1 bar for sandy clay loam; from 4 bars to 0.8 bar for sandy loam; from 1.5 bars to 0.6 bar for sand).(2)Without the constraint, the heave amount was almost independent of the freezing speed when there was no water supply (8 mm for clay; 6.5 mm for sandy clay loam; 3.5 mm for sandy loam; 1 mm for sand).(3)The heaving force decreased very rapidly with the loosening of the axial constraint by weakening the spring.The results indicate that it is practical to treat the heaving force phenomenologically as a kind of resistive force exerted by freezing soil on a container holding the soil. Because of a volumetric increase due to the transformation of water into ice at the freezing front, both unfrozen and frozen parts of the soil suffer some strain if the soil is somehow constrained by the container. The strains cause stresses which appear as the heaving force. A formula for the heaving force is given in which both the frozen and the unfrozen soil are treated as viscoelastic bodies.

Changes in soil pH and exchangeable calcium in two liming experiments on contrasting soils over 12 years

1977 ◽  
Vol 89 (1) ◽  
pp. 81-86 ◽  
Author(s):  
J. Bolton
Keyword(s):  
Soil Ph ◽  
Empirical Relationship ◽  
Loamy Sand ◽  
First Year ◽  
Clay Loam ◽  
Sandy Clay Loam ◽  
Exchangeable Calcium ◽  
Sandy Clay ◽  
Four Levels

SummarySoils were analysed from two long-term liming experiments on a sandy-clay loam at Rothamsted and a loamy sand at Woburn. Plots given four levels of limestone factorially combined with phosphate and potassium fertilizers (with magnesium subplots in 1974) were cropped with beans, barley, potatoes and oats from 1963 to 1974.The smallest limestone applications (5 t CaCO3/ha) increased soil pH the following year to values predicted by lime-requirement determinations using a standard advisory method. The larger limestone applications (10 and 20 t/ha) increased pH proportionally less. Soil pH decreased after the first year with 5 t/ha in both experiments but increased at the 20 t/ha rate for 6 years in the sandy-clay loam and for 3 years in the loamy sand before starting to decline.Exchangeable calcium (soluble in N ammonium acetate) decreased at approximately linear rates in all plots of both experiments from the first year. Slopes of the regressions were smaller at low than at higher rates of liming, depending primarily on the average pH. Rates of CaCO3 losses from the surface 23 cm of soil ranged from 225 to 823 kg/ha per year at Rothamsted and from 307 to 852 kg/ha per year at Woburn.Observed rates of Ca loss were compared with an empirical relationship suggested by Gasser (1973) between annual Ca losses and soil pH under average rainfall conditions and estimates based on a model system.

Microbial Degradation of Flurtamone in Three Georgia Soils

Weed Science ◽  
1991 ◽  
Vol 39 (2) ◽  
pp. 270-274 ◽  
Author(s):  
Thomas C. Mueller ◽  
Philip A. Banks ◽  
William C. Steen
Keyword(s):  
Dissipation Rate ◽  
Degradation Kinetics ◽  
Loamy Sand ◽  
Microbial Populations ◽  
Clay Loam ◽  
Order Process ◽  
Sandy Clay Loam ◽  
First Order ◽  
Sandy Clay ◽  
Enhanced Degradation

Degradation of flurtamone in a Greenville sandy clay loam, a Cecil loam, and a Dothan loamy sand with 0, 1, or 2 yr of previous flurtamone field use was evaluated under controlled conditions. Soil sterilization by autoclaving significantly reduced flurtamone dissipation rate in all soils. Enhanced degradation of flurtamone was observed in a Greenville sandy clay loam after 1 yr of previous flurtamone field use and in a Cecil loam after 2 yr of previous flurtamone field use. No enhancement of flurtamone degradation was observed in a Dothan loamy sand. Flurtamone degradation kinetics in these studies was described as a first-order process. Microbial populations in each soil showed no major changes in total bacterial numbers due to preexposure to flurtamone in the field.

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