The ameliorative effects of low-grade palygorskite on acidic soil

Soil Research ◽  
2020 ◽  
Vol 58 (4) ◽  
pp. 411
Author(s):  
Jin-Hua Yuan ◽  
Sheng-Zhe E ◽  
Zong-Xian Che

Mineral composition and alkaline properties of palygorskite (Pal), and its ameliorative effects on chemical properties of acid soil were investigated. Dolomite was the main form of alkali in Pal and the acid neutralisation capacity of Pal was 215 cmol kg–1. Incubation experiments indicated that Pal incorporation increased soil pH, cation exchange capacity, base saturation and exchangeable K+, Na+, Ca2+ and Mg2+ contents, and decreased the levels of exchangeable H+, Al3+ and acidity, over a 1-year period. The ameliorative mechanisms were the dissolution of major alkaline matter in Pal (i.e. dolomite), and the exchange between released Ca2+ and Mg2+ with H+ in acidic soil. Hence, Pal can be used as a moderate acidic soil amendment.

Author(s):  
C. V. Ogbenna ◽  
V. E. Osodeke

Aim: A pot experiment was carried out to determine the effect of sawdust ash and lime (Ca(OH)2) on soil characteristics and yield of sunflower in acidic soil of southeastern Nigeria. Study Design: The experiment was laid out in split-plot design, using sawdust ash (0, 1, 2, 3, 4 t ha-1) as the sub plot and lime (0, 0.5, 1.0, 1.5 t ha-1) as the main plot. Place and Duration of Study: Study was conducted outdoors at Michael Okpara University of Agriculture Umudike, Nigeria, during the 2010 planting season. Materials and Methods: Treatment combinations were applied to the 60 buckets containing soil, mixed thoroughly and watered adequately. After 1 week of treatment application, two sunflower seeds were planted and later thinned to one seedling per bucket. Plant growth and yield data were collected. Pre planting and post-harvest soil samples were collected and analyzed for soil properties. Results: Results showed that with the exception of organic carbon there was significant effect of treatments on all soil chemical properties. Lime and sawdust ash (SDA) as single and combined treatments significantly increased total nitrogen (P=0.05), available phosphorus (P<0.010), and base saturation (P<0.012). The interaction between SDA and lime significantly (P=0.05) increased total exchangeable bases and effective cation exchange capacity, while soil pH was significantly increased (P=0.05) by single applications. The increases in soil chemical properties led to significant positive response of the sunflower. With the exception of number of leaves, other plant parameters (Plant height, stem diameter, head weight, 50 seed weight, head diameter) had significant increases for sawdust ash alone at P=0.05. Correlation studies showed positive significant relationship between soil pH and sunflower yield. Conclusion: The study showed that sunflower performed best at the combination of 3 tha-1 SDA and 1.5 t ha-1 lime producing a mean head weight of 45.4 g.


2001 ◽  
Vol 2 (2) ◽  
pp. 8-17
Author(s):  
Suwarno . ◽  
Itsuo Goto ◽  
Hiroshi Masujima

Chemical properties of Pretreatment center slag (PTC-slag) were analyzed and compared to those of converter slag (C slag) and blast furnace slag (BF slag). PTC slag had a high EC value as well as citric acid soluble P and contained more Ca, Si, P, K, and Na but less Mg and Fe than C slag. Compared to BF slag, PTC slag contained more Fe, Ca, Mg, P, Mn, and Na but less Si, Al, and K. Although neutralizing value of PTC slag was lower than that of C slag, its ability to neutralize soilacidity was markedly higher. A pot experiment using Andisol from Tochigi Prefecture and komatsuna plant was carried outto evaluate PTC slag as liming material as well as P fertilizer. PTC slag, C slag, and dolomite were applied as liming materials and combined with super phosphate (SP). Addition of SP of 2.5 and 5.0% phosphate absorption coefficient (PAC) to PTC slag significantly improved the yield of komatsuna.This result, however, only apply for PTC slag adjusting soil pH to 6.5. Addit~ono f the same dosage of SP to PTC slag adjusting soil pH to 7.5 did not give significant effect. On the other hand, addition of SP of 2.5 and 5.0% PAC to C slag or dolomite significantly improved the yield for both C slag ordolomite adjusting. the soil pH to 6.5 and 7.5. Results of the experiment also indicated that P'TC slag and C slag significantly increased soil pH; exchangeable Ca, and Mg and improved available P, B, and Mn in Andisol. The magnitudes ofthese effects of the two slags, however, were difference. As compared to C slag and dolomite, PTC slag increased lower exchangeable Mg but higher available P. These results suggest that for acid soil amendment, PTC slag was better than dolomite and C slag due to the fact that this material supplymore P and B. Application of PTC slag as acid soil amendment will reduce the demand of P fertilizer, and even in high dosage can meet the P demand of komatsuna plant.


Soil Research ◽  
2014 ◽  
Vol 52 (5) ◽  
pp. 453 ◽  
Author(s):  
Yajun Hao ◽  
Qingrui Chang ◽  
Linhai Li ◽  
Xiaorong Wei

Understanding the relationships among soil properties and, in turn, their relationships with landform, land use and soil type is essential for assessing soil quality and soil productivity. In this study, we examined the differences in the chemical properties and enzymatic activities of soils in a variety of landforms (plateau land, sloping land, terraced land and gully bottoms), land uses (woodland, grassland, cropland and orchard) and soil types (Chernozems, Cambisols and Regosols) in a gully watershed on the Loess Plateau, China. In total, 202 samples of surface soil (0–20 cm) were collected from different representative landscape units of the watershed. The chemical properties and enzymatic activities of the soils were measured. The results showed that chemical properties and enzymatic activities of the soils were all significantly influenced by landform, land use and soil type. There were interactive effects between landform and soil type. Soil pH varied the least, while invertase activity varied the most with landscape conditions. Soil pH, cation exchange capacity, organic carbon and total nitrogen contents, and enzymatic activities were all highest on plateau land and lowest on terraced land. Soil organic carbon and total nitrogen contents and alkaline phosphatase and invertase activities were higher in Chernozems than in Regosols, but the opposite trend was noted for pH, cation exchange capacity and catalase activity. Significantly higher values for most soil properties or enzymatic activities occurred in combinations including plateau land, Chernozems or Regosols. Soil pH was significantly lower in woodland soils than for other land uses, whereas the other properties had higher values in grassland and woodland soils than in orchard soils. The results from this study indicate the roles of landform, land use and soil type on the spatial patterns of chemical properties and enzymatic activities of soils and suggest that crops and orchards should be arranged on plateau land, and grasses and woodland on terraced and sloping land, respectively, for better economic and ecological efficiency in the area.


Author(s):  
Hermann C. de Albuquerque ◽  
Geraldo R. Zuba Junio ◽  
Regynaldo A. Sampaio ◽  
Luiz A. Fernandes ◽  
Fabiano B. S. Prates ◽  
...  

ABSTRACTThis study aimed to evaluate the residual effect of sewage sludge fertilization on yield and nutrition of sunflower in its second cycle. The experiment was carried out from April to August 2012. The treatments consisted of four doses of sewage sludge (0, 10, 20 and 30 t ha-1, dry basis) applied in the first cycle of sunflower, distributed in a randomized block design, with six replicates. Sunflower stem diameter, plant height, capitulum diameter and yield increased with the increment in sewage sludge doses, with maximum values observed with the dose of 30 t ha-1. The contents of calcium and magnesium in the soil, pH, sum of bases, effective and potential cation exchange capacity and base saturation increased, while potential acidity and the contents of manganese and iron in the leaves decreased, with the increment in the residual doses of sewage sludge. There was a reduction in yield and growth characteristics of sunflower in the second cycle; thus, additional fertilization with sewage sludge is recommended in each new cycle.


2014 ◽  
Vol 4 ◽  
Author(s):  
Verónica Asensio Fandiño ◽  
Flora A. Vega ◽  
Rubén Forján ◽  
Emma F. Covelo

The sorption capacity for Ni, Pb and Zn of mine tailings soil with and without reclamation treatment (tree planting and waste amendment) was evaluated using the batch adsorption technique. It is important to determine the capacity of waste-amended soils to retain Ni, Pb and Zn, as the sludges used usually have high concentrations of these metals. The results obtained in the present study showed that the untreated mine tailings soil had a low capacity for Ni, Pb and Zn retention. The sorption capacity for Pb increased significantly in all of the treated soils, without any significant differences between them. The treatment that most increased the sorption capacity for Ni and Zn was planting with trees and amending with waste simultaneously, as this increased the concentration of both organic and inorganic carbon, exchangeable calcium, soil pH and effective cation exchange capacity


2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
Fikeremareyam Chulo ◽  
Fanuel Laekemariam ◽  
Alemayehu Kiflu

Understanding the nutrient dynamics in acid soil is fundamental to carry out proper management. The study was conducted to investigate phosphorus (P) pools and selected properties under different rates of lime for acid nitisols of Farawocha, Southern Ethiopia. Four lime rates incubated for a month in three replications were tested. The lime rates were 0 t/ha (0%), 5.25 t/ha (50%), 10.5 t/ha (100%), and 15.75 t/ha (150%). Lime requirement (LR) for 100% was calculated targeting soil pH of 6.5. Data on the P pools such as soluble P (P-sol) and bounded forms of P with iron (Fe-P), aluminum (Al-P), calcium (Ca-P), organic part (Org-P), residual P (Res-P), and total of P fractions were measured. In addition, changes in soil chemical properties such as pH, exchangeable acidity, calcium (Ca), magnesium (Mg), sulfur (S), iron (Fe), copper (Cu), boron (B), zinc (Zn), and manganese (Mn) were analyzed. The result showed that total P was 357.5 mg/kg. Compared to nontreated soil, liming at a rate of 15.75 t/ha significantly improved P-sol (34.2%, r2 = 0.88), Ca-P (61.6%, r2 = 0.92), and Res-P (195%, r2 = 0.94); however, it reduced Fe-P (58.5%, r2 = −0.83), Al-P (71%, r2 = −0.97), and Org-P (19.1%, r2 = 0.93). Overall, the P-associated fractions in the soil, regardless of the lime rates, were in the order of Org_P > Res_P > Fe_P > Ca_P > Al_P > P-sol. Liming raised soil pH by 2.1 units (4.5 to 6.6) over nonlimed soil, whereas it reduced exchangeable acidity from 4.18 to 0.23 meq/100 g soil. Available P, Ca, Mg, S, Cu, Zn, and B contents were significantly improved with lime application. However, liming reduced Fe and Mn contents. In conclusion, these findings showed that liming facilitated the release of P from various pools, modified pH and exchangeable acidity, and resulted in beneficial changes for most of the soil chemical properties.


1969 ◽  
Vol 69 (3) ◽  
pp. 357-365
Author(s):  
Edmundo Rivera ◽  
José Rodríguez ◽  
Fernando Abruña

The effect of acidity factors of two Ultisols and one Oxisol on yield and foliar composition of tomatoes was determined. Yields were not markedly reduced by acidity in the Ultisols until pH dropped to around 4.6 with 45% Al saturation of the cation exchange capacity (CEC), and no yield was produced at about pH 4.1 and 80% Al saturation. In the Oxisol, tomato yields dropped steadily from 39.7 t/ha, when there was no exchangeable AI, to 17.5 t/ha at the highest level of acidity, pH 4.4 and 43% AI saturation. In all soils, yields were closely correlated with soil pH, exchangeable Al and Ca and Al/Ca.


Soil Research ◽  
2012 ◽  
Vol 50 (7) ◽  
pp. 570 ◽  
Author(s):  
Jin-Hua Yuan ◽  
Ren-Kou Xu

The chemical compositions of biochars from ten crop residues generated at 350°C and their effects on chemical properties of acid soils from tropical and subtropical China were investigated. There was greater alkalinity and contents of base cations in the biochars from legume residues than from non-legume residues. Carbonates and organic anions of carboxyl and phenolic groups were the main forms of alkalis in the biochars, and their relative contributions to biochar alkalinity varied with crop residues. Incubation experiments indicated that biochar incorporation increased soil pH and soil exchangeable base cations and decreased soil exchangeable acidity. There were greater increases in soil pH and soil exchangeable base cations, and a greater decrease in soil exchangeable acidity, for biochars from legume than from non-legume residues. The biochars did not increase the cation exchange capacity (CEC) of soils with relatively high initial CEC but did increase the CEC of soils with relatively low initial CEC at an addition level of 1%. The incorporation of biochars from crop residues not only corrected soil acidity but also increased contents of potassium, magnesium, and calcium in these acid soils from tropical and subtropical regions and thus improved soil fertility.


1977 ◽  
Vol 57 (3) ◽  
pp. 233-247 ◽  
Author(s):  
ROGER W. BARIL ◽  
THI SEN TRAN

Correlations were made among chemical criteria used for taxonomic soil classificaton. The compared tests were: oxalate Δ (Fe + Al), pyrophosphate-extractable (Fe + Al), oxalate-extractable Al, pH-dependent cation exchange capacity (ΔCEC), ratios of pyrophosphate-extractable (Fe + Al) over clay or over dithionite-extractable (Fe + Al), and finally soil pH measured in 1 M NaF. Significant correlations were found among various measured parameters. However, no single test was found to be reliable as a single criterion when applied to the taxonomic classification of Quebec soils. The two chemical tests, pyrophosphate-extractable (Fe + Al) and its ratio over clay, combined with morphologic criteria appeared useful for classifying Quebec Podzols. A few soils, which presented discrepancies from chemical criteria were found difficult to classify, thus suggesting the possibility of establishing new sub-groups in the Canadain soil taxonomic classification system.


Molecules ◽  
2019 ◽  
Vol 24 (16) ◽  
pp. 3015
Author(s):  
Fethi Kooli ◽  
Souad Rakass ◽  
Yan Liu ◽  
Mostafa Abboudi ◽  
Hicham Oudghiri Hassani ◽  
...  

The effect of the counteranion of hexadecyltrimethylammonium salts on the physico-chemical properties of organoclays was investigated, using a selected natural clay mineral with a cation exchange capacity of 95 meq/100 g. The uptake amount of C16 cations was dependent on the hexadecyltrimethylammonium (C16) salt solution used, the organoclay prepared from C16Br salt solution exhibited a value of 1. 05 mmole/g higher than those prepared from C16Cl and C16OH salt solutions. The basal spacing of these organoclays was in the range of 1.81 nm to 2.10 nm, indicating a similar orientation of the intercalated surfactants, and could indicated that the excess amount of surfactants, above the cation exchange capacity of 0.95 meq/g could be adsorbed on the external surface of the clay mineral sheets. These organoclays were found to be stable in neutral, acidic, and basic media. The thermal stability of these organoclays was carried out using thermogravimetric analysis and in-situ X-ray diffraction (XRD) techniques. The decomposition of the surfactant occurred at a maximum temperature of 240 °C, accompanied with a decrease of the basal spacing value close to 1.42 nm. The application of these organoclays was investigated to remove an acidic dye, eosin. The removal amount was related to the initial used concentrations, the amount of the surfactants contents, and to the preheated temperatures of the organoclays. The removal was found to be endothermic process with a maximum amount of 55 mg of eosin/g of organoclay. The value decreased to 25 mg/g, when the intercalated surfactants were decomposed. The reuse of these organoclays was limited to four regeneration recycles with a reduction of 20 to 30%. However, noticeable reduction between 35% to 50% of the initial efficiency, was achieved after the fifth cycle, depending of the used organoclays.


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