Mining disturbance alters phosphorus fractions in northern Australian soils

Soil Research ◽  
2000 ◽  
Vol 38 (2) ◽  
pp. 411 ◽  
Author(s):  
Terrence A. Short ◽  
Neal W. Menzies ◽  
David R. Mulligan
Keyword(s):  
Soil Phosphorus ◽  
Native Forest ◽  
P Fractions ◽  
Bauxite Mining ◽  
Soil P ◽  
Soil Fractions ◽  
Eucalypt Forest ◽  
Extractable P ◽  
Mining Disturbance ◽  
Undisturbed Soils

The brown kandosol soils at Weipa, North Queensland, contain little soil phosphorus (P). Plant-available fractions (considered in this study to include resin, hydroxide, and dilute acid extractable P) approximate 85 ˜g P/g, or 70% of total soil P, the majority of which is in labile organic forms, highlighting the importance of P cycling within the native eucalypt forest. A field experiment was undertaken to evaluate the effect of soil handling during bauxite mining on the distribution of P between the various soil fractions. This study showed that soil stripping and replacement disrupts the P cycle and affects the proportional distribution of P between soil fractions. Horizon mixing during soil handling severely reduces the size of plant-available soil P fractions in surface soils ( 0–5 cm depth) and this can only be partially compensated by the addition of fertiliser. A survey of rehabilitated sites of differing ages showed that restoration of soil organic P fractions is extremely slow, with the overall distribution of P within replaced soils remaining different from that within undisturbed soils 15 years after rehabilitation to native forest or exotic pasture species.

SPATIAL VARIABILITY OF SOIL PHOSPHORUS AS INFLUENCED BY SOIL TEXTURE AND MANAGEMENT

1985 ◽  
Vol 65 (3) ◽  
pp. 475-487 ◽  
Author(s):  
I. P. O’HALLORAN ◽  
R. G. KACHANOSKI ◽  
J. W. B. STEWART
Keyword(s):  
Spatial Variability ◽  
Soil Phosphorus ◽  
Soil Parameters ◽  
Organic P ◽  
P Fractions ◽  
Experimental Site ◽  
Soil P ◽  
Extractable P ◽  
Loam Soil ◽  
Texture Removal

The spatial variability of soil phosphorus (0–15 cm) and its relationship to management and texture was examined on an ongoing (since 1967) crop rotation study located on a Brown Chernozemic loam soil at Swift Current, Saskatchewan. Total soil P was less variable than either the total inorganic (Pi) or organic (Po) phosphorus fractions. The same was found for the sodium bicarbonate extractable P (bicarb-P) fractions, although they were more variable. The spatial variability of the measured P fractions indicated that the site was not uniformly variable. Texture varied significantly within and between treatments and replicates with sand being the most variable. Up to 90% of the variability in P could be accounted for by changes in texture. Considering this, sampling intensity could be significantly reduced in a study of temporal changes in soil P on the experimental site. Organic P (both total and bicarb-Po) and bicarb-Pi were negatively correlated to sand content. The influence of managment on soil phosphorus varied with texture. Removal of treatment effects over the textural ranges encountered and the non-uniform variability of the various soil parameters measured in this study demonstrated the importance of obtaining a complete knowledge of the spatial variability of the experimental site. Key words: Inorganic P, organic P, soil variability, bicarbonate extractable P, soil uniformity

Improved Plant Diversity as a Strategy to Increase Available Soil Phosphorus

2019 ◽  
Vol 103 (1) ◽  
pp. 43-45 ◽  
Author(s):  
Carlos Crusciol ◽  
João Rigon ◽  
Juliano Calonego ◽  
Rogério Soratto
Keyword(s):  
Crop Yields ◽  
Soil Phosphorus ◽  
Cropping System ◽  
P Availability ◽  
P Fractions ◽  
Crop Species ◽  
Soil P ◽  
Residue Decomposition ◽  
Available Soil Phosphorus ◽  
Crop Residue Decomposition

Some crop species could be used inside a cropping system as part of a strategy to increase soil P availability due to their capacity to recycle P and shift the equilibrium between soil P fractions to benefit the main crop. The release of P by crop residue decomposition, and mobilization and uptake of otherwise recalcitrant P are important mechanisms capable of increasing P availability and crop yields.

scholarly journals Estimates of mean residence times of phosphorus in commonly considered inorganic soil phosphorus pools

2020 ◽  
Vol 17 (2) ◽  
pp. 441-454 ◽  
Author(s):  
Julian Helfenstein ◽  
Chiara Pistocchi ◽  
Astrid Oberson ◽  
Federica Tamburini ◽  
Daniel S. Goll ◽  
...  
Keyword(s):  
Land Surface ◽  
Soil Phosphorus ◽  
Land Surface Models ◽  
High Ph ◽  
Soil P ◽  
P Pools ◽  
Extractable P ◽  
Surface Models ◽  
Exchange Kinetic ◽  
Using Data

Abstract. Quantification of turnover of inorganic soil phosphorus (P) pools is essential to improve our understanding of P cycling in soil–plant systems and improve representations of the P cycle in land surface models. Turnover can be quantified using mean residence time (MRT); however, to date there is little information on MRT of P in soil P pools. We introduce an approach to quantify MRT of P in sequentially extracted inorganic soil P pools using data from isotope exchange kinetic experiments. Our analyses of 53 soil samples from the literature showed that MRT of labile P (resin- and bicarbonate-extractable P) was on the order of minutes to hours for most soils, MRT in NaOH-extractable P (NaOH-P) was in the range of days to months, and MRT in HCl-extractable P (HCl-P) was on the order of years to millennia. Multiple-regression models were able to capture 54 %–63 % of the variability in MRT among samples and showed that land use was the most important predictor of MRT of P in labile and NaOH pools. MRT of P in HCl-P was strongly dependent on pH, as high-pH soils tended to have longer MRTs. This was interpreted to be related to the composition of HCl-P. Under high pH, HCl-P contains mostly apatite, with a low solubility, whereas under low-pH conditions, HCl-P may contain more exchangeable P forms. These results suggest that current land surface models underestimate the dynamics of inorganic soil P pools and could be improved by reducing model MRTs of the labile and NaOH-P pools, considering soil-type-dependent MRTs rather than universal exchange rates and allowing for two-way exchange between HCl-P and the soil solution.

scholarly journals Combining Laser-Induced Breakdown Spectroscopy (LIBS) and Visible Near-Infrared Spectroscopy (Vis-NIRS) for Soil Phosphorus Determination

Sensors ◽  
2020 ◽  
Vol 20 (18) ◽  
pp. 5419 ◽  
Author(s):  
Sara Sánchez-Esteva ◽  
Maria Knadel ◽  
Sergey Kucheryavskiy ◽  
Lis W. de Jonge ◽  
Gitte H. Rubæk ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Variable Selection ◽  
Near Infrared ◽  
Soil Phosphorus ◽  
Laser Induced Breakdown Spectroscopy ◽  
Soil P ◽  
Breakdown Spectroscopy ◽  
Extractable P ◽  
Laser Induced Breakdown ◽  
Wet Chemical

Conventional wet chemical methods for the determination of soil phosphorus (P) pools, relevant for environmental and agronomic purposes, are labor-intensive. Therefore, alternative techniques are needed, and a combination of the spectroscopic techniques—in this case, laser-induced breakdown spectroscopy (LIBS)—and visible near-infrared spectroscopy (vis-NIRS) could be relevant. We aimed at exploring LIBS, vis-NIRS and their combination for soil P estimation. We analyzed 147 Danish agricultural soils with LIBS and vis-NIRS. As reference measurements, we analyzed water-extractable P (Pwater), Olsen P (Polsen), oxalate-extractable P (Pox) and total P (TP) by conventional wet chemical protocols, as proxies for respectively leachable, plant-available, adsorbed inorganic P, and TP in soil. Partial least squares regression (PLSR) models combined with interval partial least squares (iPLS) and competitive adaptive reweighted sampling (CARS) variable selection methods were tested, and the relevant wavelengths for soil P determination were identified. LIBS exhibited better results compared to vis-NIRS for all P models, except for Pwater, for which results were comparable. Model performance for both the LIBS and vis-NIRS techniques as well as the combined LIBS-vis-NIR approach was significantly improved when variable selection was applied. CARS performed better than iPLS in almost all cases. Combined LIBS and vis-NIRS models with variable selection showed the best results for all four P pools, except for Pox where the results were comparable to using the LIBS model with CARS. Merging LIBS and vis-NIRS with variable selection showed potential for improving soil P determinations, but larger and independent validation datasets should be tested in future studies.

scholarly journals Phosphorus Availabilities Differ between Cropland and Forestland in Shelterbelt Systems

Forests ◽  
2019 ◽  
Vol 10 (11) ◽  
pp. 1001
Author(s):  
Scott X. Chang ◽  
Mihiri C.W. Manimel Wadu ◽  
Fengxiang Ma
Keyword(s):  
Land Use ◽  
Chemical Fractionation ◽  
Land Use Type ◽  
Organic P ◽  
P Fractions ◽  
Soil P ◽  
Goods And Services ◽  
P Cycling ◽  
Extractable P ◽  
P Fraction

Shelterbelt systems play pivotal roles in providing goods and services to the rural community and the society at large, but phosphorus (P) cycling in shelterbelt systems is poorly studied, while P cycling and availability would be linked to the ecological function and services of shelterbelt systems. This study was conducted to understand how long-term (>30 years) land-use between cropland and forestland in shelterbelt systems affect soil P status. We investigated modified Kelowna (PKelowna) and Mehlich-3 (PMehlich) extractable P, P fractions (by sequential chemical fractionation), P sorption properties in the 0–10 and 10–30 cm soils and their relationship in six pairs of the cropland areas and adjacent forestland (each pair constitutes a shelterbelt system) in central Alberta. Both PKelowna and PMehlich in the 0–10 cm soil were greater in the cropland than in the forestland. The PKelowna ranged from 10 to 170 and 2 to 57 mg kg−1 within the cropland areas and forestland, respectively. The inorganic P fraction in the 0–30 cm depth was significantly related to PKelowna (R2 = 0.55) and PMehlich (R2 = 0.80) in cropland, but organic P fraction was not significantly related with neither PKelowna nor PMehlich. The iron (Fe) and aluminum (Al) associated P (Fe/Al-P) explained ~50% and ~45% of the variation of PKelowna in the 0–30 cm soil in the cropland and forestland, respectively. The Fe/Al-P and organic P fractions in the 0–10 cm soil were greater in the cropland than in the forestland. The differences in availability and P forms depending on the land use type in shelterbelts suggest that P management needs to be land-use type-specific for shelterbelt systems.

scholarly journals Pronounced surface stratification of soil phosphorus, potassium and sulfur under pastures upstream of a eutrophic wetland and estuarine system

Soil Research ◽  
2017 ◽  
Vol 55 (7) ◽  
pp. 657 ◽  
Author(s):  
Megan H. Ryan ◽  
Mark Tibbett ◽  
Hans Lambers ◽  
David Bicknell ◽  
Phillip Brookes ◽  
...  
Keyword(s):  
Soil Phosphorus ◽  
Dairy Farm ◽  
Soil Surface ◽  
Plant Litter ◽  
Nutrient Concentrations ◽  
Estuarine System ◽  
Soil P ◽  
Extractable P ◽  
High Concentrations ◽  
Extractable Soil

High concentrations of nutrients in surface soil present a risk of nutrient movement into waterways through surface water pathways and leaching. Phosphorus (P) is of particular concern because of its role in aquatic system eutrophication. We measured nutrients under annual pastures on a beef farm and a dairy farm in the Peel–Harvey catchment, Western Australia. Soils were sampled in 10-mm increments to 100mm depth in March, June and September. Plant litter contained approximately 300–550mg kg–1 Colwell-extractable P. Extractable soil P was strongly stratified, being approximately 100–225mg kg–1 (dairy) and 50–110mg kg–1 (beef) in the top 10mm and <40mg kg–1 at 40–50mm depth. Total P and extractable potassium were also highly stratified, whereas sulfur was less strongly stratified. Shoot nutrient concentrations indicated that nitrogen was often limiting and sulfur was sometimes limiting for pasture growth: concentrations of P were often much greater than required for adequate growth (>4mg g–1). We conclude that high P concentrations at the soil surface and in litter and shoots are a source of risk for movement of P from farms into waterways in the Peel–Harvey catchment.

scholarly journals Soil phosphorus dynamics and availability and irrigated coffee yield

2011 ◽  
Vol 35 (2) ◽  
pp. 503-515 ◽  
Author(s):  
Thiago Henrique Pereira Reis ◽  
Paulo Tácito Gontijo Guimarães ◽  
Antônio Eduardo Furtini Neto ◽  
Antônio Fernando Guerra ◽  
Nilton Curi
Keyword(s):  
Soil Phosphorus ◽  
P Fractions ◽  
Soil P ◽  
Coffee Yield ◽  
Phosphate Fertilization ◽  
P Application ◽  
Red Latosol ◽  
Leaf P ◽  
Coffea Arabica L ◽  
Total P

Research data have demonstrated that the P demand of coffee (Coffea arabica L.) is similar to that of short-cycle crops. In this context, the objective of this study was to evaluate the influence of annual P fertilization on the soil P status by the quantification of labile, moderately labile, low-labile, and total P fractions, associating them to coffee yield. The experiment was installed in a typical dystrophic Red Latosol (Oxisol) cultivated with irrigated coffee annually fertilized with triple superphosphate at rates of 0, 50, 100, 200, and 400 kg ha-1 P2O5. Phosphorus fractions were determined in two soil layers: 0-10 and 10-20 cm. The P leaf contents and coffee yield in 2008 were also evaluated. The irrigated coffee responded to phosphate fertilization in the production phase with gains of up to 138 % in coffee yield by the application of 400 kg ha-1 P2O5. Coffee leaf P contents increased with P applications and stabilized around 1.98 g kg-1, at rates of 270 kg ha-1 P2O5 and higher. Soil P application caused, in general, an increase in bioavailable P fractions, which constitute the main soil P reservoir.

Depletion, accumulation and availability of soil phosphorus in the Askov long-term field experiment

Soil Research ◽  
2020 ◽  
Vol 58 (2) ◽  
pp. 117 ◽  
Author(s):  
Musibau O. Azeez ◽  
Gitte Holton Rubæk ◽  
Ingeborg Frøsig Pedersen ◽  
Bent T. Christensen
Keyword(s):  
Rock Phosphate ◽  
Soil Phosphorus ◽  
Available P ◽  
Soil P ◽  
Olsen P ◽  
Extractable P ◽  
P Application ◽  
Plant Available P ◽  
Water Extractable

Soil phosphorus (P) reserves, built up over decades of intensive agriculture, may account for most of the crop P uptake, provided adequate supply of other plant nutrients. Whether crops grown on soils with reduced supply of other nutrients obtain similar use-efficiency of soil P reserves remains unclear. In treatments of the Askov Long-Term Experiment (initiated in 1894 on light sandy loam), we quantified changes in soil total P and in plant-available P (Olsen P, water extractable P and P offtake in wheat grains) when P-depleted soil started receiving P in rock phosphate and when P application to soil with moderate P levels ceased during 1997–2017. Additionally we studied treatments with soil kept unfertilised for &gt;100 years and with soil first being P depleted and then exposed to surplus dressings of P, nitrogen (N) and potassium in cattle manure. For soil kept unfertilised for &gt;100 years, average grain P offtake was 6 kg ha–1 and Olsen P averaged 4.6 mg kg–1, representing the lower asymptotic level of plant-available P. Adding igneous rock phosphate to severely P-depleted soil with no N fertilisation had little effect on Olsen P, water extractable P (Pw), grain yields and P offtake. For soils with moderate levels of available P, withholding P application for 20 years reduced contents of Olsen P by 56% (from 16 to 7 mg P kg–1) and of Pw by 63% (from 4.5 to 1.7 mg P kg–1). However, the level of plant-available P was still above that of unfertilised soil. Application of animal manure to P-depleted soil gradually raised soil P availability, grain yield and P offtake, but it took 20 years to restore levels of plant-available P. Our study suggests symmetry between rates of depletion and accumulation of plant-available P in soil.

scholarly journals Four soil phosphorus (P) tests evaluated by plant P uptake and P balancing in the Ultuna long-term field experiment

2018 ◽  
Vol 64 (No. 9) ◽  
pp. 441-447 ◽  
Author(s):  
Jarosch Klaus A ◽  
Santner Jakob ◽  
Parvage Mohammed Masud ◽  
Gerzabek Martin Hubert ◽  
Zehetner Franz ◽  
...  
Keyword(s):  
Soil Phosphorus ◽  
P Uptake ◽  
P Availability ◽  
Soil P ◽  
Extractable P ◽  
Plant P Uptake ◽  
Soil P Tests ◽  
Water Extractable ◽  
Term Field

Soil phosphorus (P) availability was assessed with four different soil P tests on seven soils of the Ultuna long-term field experiment (Sweden). These four soil P tests were (1) P-H<sub>2</sub>O (water extractable P); (2) P-H<sub>2</sub>O<sub>C10</sub> (water extractable P upon 10 consecutive extractions); (3) P-AL (ammonium lactate extractable P) and (4) P-C<sub>DGT</sub> (P desorbable using diffusive gradients in thin films). The suitability of these soil P tests to predict P availability was assessed by correlation with plant P uptake (mean of preceding 11 years) and soil P balancing (input vs. output on plot level for a period of 54 years). The ability to predict these parameters was in the order P-H<sub>2</sub>O<sub>C10</sub> &gt; P-C<sub>DGT</sub> &gt; P-H<sub>2</sub>O &gt; P-AL. Thus, methods considering the P-resupply from the soil solid phase to soil solution performed clearly better than equilibrium-based extractions. Our findings suggest that the P-AL test, commonly used for P-fertilizer recommendations in Sweden, could not predict plant P uptake and the soil P balance in a satisfying way in the analysed soils.

Long-term crop rotation and fertilizer effects on phosphorus transformations: II. In a Luvisolic soil

1992 ◽  
Vol 72 (4) ◽  
pp. 581-589 ◽  
Author(s):  
R. H. McKenzie ◽  
J. W. B. Stewart ◽  
J. F. Dormaar ◽  
G. B. Schaalje
Keyword(s):  
Sodium Bicarbonate ◽  
Sequential Extraction ◽  
Sodium Hydroxide ◽  
Crop Rotation ◽  
Soil Phosphorus ◽  
Fertilizer Application ◽  
P Fractions ◽  
Soil P ◽  
P Transformations

The effects of different cropping systems, fertilizer, and lime on soil phosphorus (P) dynamics in soils developed under forest vegetation have received little attention. The objective of this study was to develop an understanding of P fractions and transformations in long-term rotation plots on a Luvisolic soil at Breton, Alberta. Results have shown that crop rotation and fertilizer application have affected more inorganic soil phosphorus (Pi) and organic phosphorus (Po) fractions, as determined by a sequential extraction procedure. Continuously cropped treatments, which had not received fertilizer, resulted in P drawdown of resin-extractable Pi (resin-Pi), sodium bicarbonate-extractable Pi (bicarb-Pi), sodium hydroxide-extractable Pi (NaOH-Pi), sodium bicarbonate-extractable Po (bicarb-Po), sodium hydroxide-extractable Po (NaOH-Po) and hydrochloric acid-extractable Pi (HCl-Pi) fractions. Only the residual-P fraction (insoluble Pi and stable Po forms) was unaffected. Addition of fertilizer had an effect on all P fractions except the NaOH-Po fraction. Phosphorus fertilizer treatments positively affected the Pi fractions and N fertilizer positively affected the bicarb-Po fraction. Lime application affected soil pH, which lowered NaOH-Pi levels and increased HCl-Pi levels through formation of more stable calcium phosphate compounds. Addition of lime also resulted in lower bicarb-Po levels. Cropping without using phosphate fertilizer has resulted in a 30–40% decline in total-P in the Breton plots in the Ap horizon. Continuous cropping, with a forage crop in the rotation, coupled with modest N and P fertilizer application, had the most positive effects on P cycling and transformations. Summerfallow had no apparent beneficial effects on P transformations. Key words: Soil P transformations, Luvisolic soil, P bioavailability, sequential extraction

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