pVT-Data and Tait-Equation for 4-trans-(4-alkyl)-Cyclohexyl-Benzonitriles

1981 ◽  
Vol 76 (3-4) ◽  
pp. 199-210 ◽  
Author(s):  
E. Kuss
Keyword(s):  
1976 ◽  
Vol 31 (7) ◽  
pp. 769-776 ◽  
Author(s):  
G. Goldmann ◽  
K. Tödheide

Abstract From the Tait equation an equation of state containing five adjustable parameters was developed which fits experimental density data of molten potassium chloride to 1320 K and 6 kbar with a standard deviation of 0.04%. The thermal expansion coefficient, isothermal compressibility, internal pressure, and molar heat capacities at constant pressure and constant volume were calculated as functions of pressure and temperature from the equation of state and were compared with computer simulation results. A method for an estimate of high-pressure PVT data for molten salts is suggested which yields results superior to the best computed data presently available.


Author(s):  
Alexander Muranov ◽  
Alexey Semenov ◽  
Anatoly Kutsbakh ◽  
Boris Semenov

The article discusses one of the modern areas of powder metallurgy – the technology of manufacturing shaped parts by the powder injection molding (PIM). For the powder-polymer mixture (feedstock) with a wax-polypropylene binder of the solvent-thermal type of removal by isobaric volume dilatometry, the dependence of PVT state parameters was studied. For each component of the polymer binder, the dependence of pressure on the temperature of phase transition was obtained. As a result of mathematical processing and analysis of PVT data for the feedstock of the studied type, a technological window of parameters has been determined that allows injection molding of «green parts» with minimal volume shrinkage. The results of a comparative analysis of the compaction of feedstock with a polymer binder catalytic and solution-thermal type of removal are presented.


Energies ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 930
Author(s):  
Fahimeh Hadavimoghaddam ◽  
Mehdi Ostadhassan ◽  
Ehsan Heidaryan ◽  
Mohammad Ali Sadri ◽  
Inna Chapanova ◽  
...  

Dead oil viscosity is a critical parameter to solve numerous reservoir engineering problems and one of the most unreliable properties to predict with classical black oil correlations. Determination of dead oil viscosity by experiments is expensive and time-consuming, which means developing an accurate and quick prediction model is required. This paper implements six machine learning models: random forest (RF), lightgbm, XGBoost, multilayer perceptron (MLP) neural network, stochastic real-valued (SRV) and SuperLearner to predict dead oil viscosity. More than 2000 pressure–volume–temperature (PVT) data were used for developing and testing these models. A huge range of viscosity data were used, from light intermediate to heavy oil. In this study, we give insight into the performance of different functional forms that have been used in the literature to formulate dead oil viscosity. The results show that the functional form f(γAPI,T), has the best performance, and additional correlating parameters might be unnecessary. Furthermore, SuperLearner outperformed other machine learning (ML) algorithms as well as common correlations that are based on the metric analysis. The SuperLearner model can potentially replace the empirical models for viscosity predictions on a wide range of viscosities (any oil type). Ultimately, the proposed model is capable of simulating the true physical trend of the dead oil viscosity with variations of oil API gravity, temperature and shear rate.


1969 ◽  
Vol 73 (7) ◽  
pp. 2459-2460
Author(s):  
Yun K. Huang
Keyword(s):  

1967 ◽  
Vol 45 (2) ◽  
pp. 123-130 ◽  
Author(s):  
W. A. Adams ◽  
K. J. Laidler

The compressibility of acetone has been redetermined at temperatures of 25 to 55 °C, and at pressures from atmospheric to 1 kbar. The results have been fitted to the Tait equation, and values of (∂P/∂T)V and of the internal pressure have been calculated. The heat capacity at constant volume has also been deduced as a function of pressure and temperature. The variations in these and other derived quantities have been shown to lead to conclusions about structural changes in the liquid.


2021 ◽  
Author(s):  
Thitaree Lertliangchai ◽  
Birol Dindoruk ◽  
Ligang Lu ◽  
Xi Yang

Abstract Dew point pressure (DPP) is a key variable that may be needed to predict the condensate to gas ratio behavior of a reservoir along with some production/completion related issues and calibrate/constrain the EOS models for integrated modeling. However, DPP is a challenging property in terms of its predictability. Recognizing the complexities, we present a state-of-the-art method for DPP prediction using advanced machine learning (ML) techniques. We compare the outcomes of our methodology with that of published empirical correlation-based approaches on two datasets with small sizes and different inputs. Our ML method noticeably outperforms the correlation-based predictors while also showing its flexibility and robustness even with small training datasets provided various classes of fluids are represented within the datasets. We have collected the condensate PVT data from public domain resources and GeoMark RFDBASE containing dew point pressure (the target variable), and the compositional data (mole percentage of each component), temperature, molecular weight (MW), MW and specific gravity (SG) of heptane plus as input variables. Using domain knowledge, before embarking the study, we have extensively checked the measurement quality and the outcomes using statistical techniques. We then apply advanced ML techniques to train predictive models with cross-validation to avoid overfitting the models to the small datasets. We compare our models against the best published DDP predictors with empirical correlation-based techniques. For fair comparisons, the correlation-based predictors are also trained using the underlying datasets. In order to improve the outcomes and using the generalized input data, pseudo-critical properties and artificial proxy features are also employed.


1993 ◽  
Vol 32 (5) ◽  
pp. 970-975 ◽  
Author(s):  
Andre Normandin ◽  
Bernard P. A. Grandjean ◽  
Jules Thibault

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