Theoretical Evaluation of Crosslink Density of Chain Extended Polyurethane Networks Based on Hydroxyl Terminated Polybutadiene and Butanediol and Comparison with Experimental Data

2017 ◽  
Vol 36 (1) ◽  
pp. 38-47 ◽  
Author(s):  
Venkataraman Sekkar ◽  
Ancy Smitha Alex ◽  
Vijendra Kumar ◽  
G. G. Bandyopadhyay
Author(s):  
G Ardizzon ◽  
G Pavesi

A method, based on quasi three-dimensional analysis, of describing pump cavitation behaviour is proposed. Cavitation performance is related to impeller entrance design and the influence of the angle of attack of the leading edges on the flow is studied. Coefficients are derived from the pressure drop due separately to the vanes and shroud. The influence of incident angle on cavitation is shown as a function of the blade geometry and discussed. By comparison with experimental data on centrifugal pumps, it is shown that the present model can simulate the characteristics of inception cavitation at design and off-design conditions.


1962 ◽  
Vol 35 (2) ◽  
pp. 371-378 ◽  
Author(s):  
G. M. Bartenev

Abstract 1. As a result of analysis of the formulas of friction of rubber and of a comparison with experimental data for steady-state friction on smooth solid surfaces it is demonstrated that the friction of vulcanized rubber is determined by three constants of the material, depending upon the type of rubber polymer and the structure of the vulcanizate. 2. The constant α characterizes the constant of the formation of the area of actual contact Sa under loading. This constant does not depend upon the rate of slip and the nature of the solid surface, but it does depend upon the stiffness of the vulcanizate, which is directly proportional to the crosslink density. 3. The tangential stress on the actual area of contact α=F/Sa depends upon the temperature, the rate of slip and the two constants of the material Sk and U. The first of these is the effective area of contact of a chain with the solid surface, depending upon the number of chains in the network of the vulcanizate, the second is the activation energy, depending upon the nature of the frictioning surfaces, in particular upon the structure of the polymer chain of rubber. 4. A method is proposed for calculating the area of actual contact of a vulcanizate from the number of chains per unit volume and from the number of chains which are in contact with the solid surface.


1992 ◽  
Vol 57 (1) ◽  
pp. 33-45
Author(s):  
Vladimír Jakuš

A new approach to theoretical evaluation of the Gibbs free energy of solvation was applied for estimation of retention data in high-performance liquid chromatography on reversed phases (RP-HPLC). Simple and improved models of stationary and mobile phases in RP-HPLC were employed. Statistically significant correlations between the calculated and experimental data were obtained for a heterogeneous series of twelve compounds.


2015 ◽  
Vol 5 (2) ◽  
pp. 135-142 ◽  
Author(s):  
Benzhen Yao ◽  
Zhiqing Wang ◽  
Tiancun Xiao ◽  
Fahai Cao ◽  
Peter P. Edwards ◽  
...  

Author(s):  
Claudio Braccesi ◽  
Filippo Cianetti ◽  
Renzo Scaletta

The present paper illustrates an evaluation method developed by the authors to quantify the index of motion sickness incidence (MSI) in railways motion conditions. This index is formerly defined in literature to quantify diseases coming from low frequency motions (kinetosis). The proposed method, suggested as alternative to the only one existing in reference norm, involves PCT index, well known in railways context, and weighting curves for accelerometric signals, which are also specified in railways regulations. The approach of the method, consistent with the theoretical model, developed by the authors themselves in previous works, allows to obtain MSI index versus time and/or track progressive distance. The model is validated through comparison with experimental data available in literature and with measures recorded and obtained on regular trains during tests performed in Slovenia (EU).


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